Phenomena Affecting the Equilibrium of Al(III) and Zn(II) Extraction with Winsor II Microemulsions

The extraction of Al(III) and Zn(II) from an aqueous solution with two water-in-oil microemulsions, one containing di(2-ethylhexyl)phosphoric acid (DEHPA), was investigated to aid the understanding of the role of the extractant and the metal specific characteristics in the mechanism of microemulsion extraction. The extraction of Al with the DEHPA microemulsion increased by a factor of about 10 with respect to that in the conventional DEHPA system, whereas the extraction of Zn was lower than that in the single DEHPA system. Extraction with the DEHPA-free microemulsion was very low, showing that metal ion solubilization was not important in the mechanism of microemulsion extraction. It is proposed that the effect of the mixed microemulsion on the metal distribution coefficient is the result of the balance between a decrease in the complexation reaction yield due to the interaction between butanol and DEHPA, and the adsorption of the metal complex at the macro- and microinterfaces. The former leads to a decrease in Zn(II) extraction and the latter to Al(III) extraction synergism. Copyright 2000 Academic Press.     

Structure of V(2)O(5)*nH(2)O xerogel solved by the atomic pair distribution function technique

A long-standing issue regarding the local and long-range structure of V(2)O(5)*nH(2)O xerogel has been successfully addressed. The full three-dimensional structure of the lamellar turbostratic V(2)O(5)*nH(2)O xerogel was determined by the atomic pair distribution function technique. We show that on the atomic scale the slabs of the xerogel can be described well as almost perfect pairs (i.e., bilayers) of single V(2)O(5) layers made of square pyramidal VO(5) units. These slabs are separated by water molecules and stack along the z-axis of a monoclinic unit cell (space group C2/m) with parameters a = 11.722(3) A, b = 3.570(3) A, c = 11.520(3) A, and beta = 88.65 degrees. The stacking sequence shows signatures of turbostratic disorder and a structural coherence limited to 50 A.     

Neutron diffraction evidence of microscopic charge inhomogeneities in the CuO2 plane of superconducting La2-xSrxCuO4 (0<or=x<or=0. 30)

High-resolution atomic pair distribution functions have been obtained using neutron powder diffraction data from La2-xSrxCuO4 over the range of doping 0相似文献   

Study of temperature dependent atomic correlations in MgB2

We have studied temperature evolution of the local as well as the average crystal structure of MgB₂ using real-space atomic pair distribution function (PDF) measured by high resolution neutron powder diffraction in a wide temperature range of T=10–600 K. We find small positive correlation factors for the B–B and B–Mg pairs, determined by mean-square displacements (MSD) and the mean-square relative displacements (MSRD). We analyze the PDF using both Einstein and force constant models finding a good agreement between the experimental data and the two models. This indicates that B and Mg atomic correlations are not sensitive to the details of phonon dispersion.     

Light charged particles and clusters in coincidence with heavy fragments in the40Ar(1100 MeV)+13C incomplete fusion reaction. Simulated statistical decay analysis

Protons, deuterons, tritons,α-particles and Li have been studied in coincidence with evaporation residues produced at low impact parameter for the⁴⁰Ar(1100 MeV)+¹³C reaction. Experimental characteristics of the light particle — heavy residue correlations, and among them an effect of left-right asymmetry, are analyzed and discussed in some detail on the basis of Monte Carlo simulations. This reaction appears to be governed by an incomplete fusion process. Due to transverse emission of preequilibrium particles, the compound nuclei associated with light-particle-evaporation-residue coincidence events recoil at a non-zero degree lab. angle with some dispersion around this direction. When these effects are introduced into statistical decay calculations, it is then possible to reproduce various experimental results and to understand features like the asymmetry effect. Discrimination of light particles of preequilibrium and of evaporative origin appears possible.     

机械泵驱动两相回路的实时动态模型分析

在航空航天领域,为了加速系统设计及测试进度,通常需要进行半实物实时仿真,即控制器用实物,受控对象采用数学模型。本文开发出了基于Matlab/Simulink的两相传热模块,并用其搭建了某机械泵驱动两相回路的实时动态模型。通过与实验的对比,验证了模型的可靠性,表明该模型满足实时要求,可以在下一步用于半实物仿真。     

Phenolic compounds in field horsetail (Equisetum arvense L.) as natural antioxidants

In this paper, the study of antioxidant activity and phenolic composition of three different extracts (EtOAc, n-BuOH and H(2)O) of field horsetail (Equisetum arvense L.) is presented. The antioxidant activity has been evaluated measuring the total reducing power (expressed by Ascorbate Equivalent Antioxidant Capacity - AEAC), inhibition of lipid peroxidation, and free radical scavenging capacity (RSC) towards 2,2-diphenyl-1-picrylhydrazyl (DPPH radical) and nitric oxide (NO), respectively. In addition, the total flavonoid content (TFC) and phenolic constituents of each extract have been determined. The results obtained show that the highest RSC regarding both DPPH and NO radicals is expressed by EtOAc extract (EC(50)=2.37 microg/mL and EC(50)=90.07 microg/mL, respectively), and the lowest by H(2)O extract (EC(50)=37.2 microg/mL and EC(50)>333.33 microg/mL, respectively). n-BuOH extract showed the highest total reducing power (AEAC=13.40 microg/mL). Differences in the phenolic composition of examined extracts are found comparing the HPLC chemical profiles. Although, isoquercitrin is the main flavonoid in both EtOAc and n-BuOH extracts, a considerable amount of di-E-caffeoyl-meso-tartaric acid was presented in the n-BuOH extract. In H(2)O extract high content of phenolic acids and low percentage of flavonoids were detected.     

Chemical composition, antioxidant and antibacterial properties of Achillea collina Becker ex Heimerl s.l. and A. pannonica Scheele essential oils

The in vitro antioxidant and antimicrobial activities of two Achillea millefolium (Adanson) Koch s.l species essential oils (A. collina Becker ex Heimerl s.l. and A. pannonica Scheele, Asteraceae) originating from the Golija and Radan mountains (Serbia) were investigated. The chemical profiles of the essential oils were evaluated by GC-MS. Antioxidant activity was assessed as free radical scavenging capacity (RSC) towards 2,2-diphenyl-1-picrylhydrazil (DPPH) radicals, together with effects on lipid peroxidation (LP). Antibacterial activity was examined on 21 bacterial strains. Based on the chemical composition of the essential oil, A. collina s.l. from Mount Golija was classified as a chamazulene chemotype (tetraploid). The high percentage of oxygenated monoterpenes and absence of azulene in the essential oil obtained from A. pannonica from Radan pointing that this population is octaploid. Essential oil of A. pannonica expressed stronger antimicrobial activity on almost all tested bacteria. Furthermore, this essential oil expressed higher scavenging effects on DPPH radical (IC(50) = 0.52 comparing to 0.62 mug/mL). Only in the LP evaluation, essential oil of A. collina s.l. from Golija exhibited stronger antioxidant activity (IC(50) = 0.75 comparing to 2.12 mug/mL).     

Phase diagram of K(x)Fe(2-y)Se(2-z)S(z) and the suppression of its superconducting state by an Fe2-Se/S tetrahedron distortion

We report structurally tuned superconductivity in a K(x)Fe(2-y)Se(2-z)S(z) (0 ≤ z ≤ 2) phase diagram. Superconducting T(c) is suppressed as S is incorporated into the lattice, eventually vanishing at 80% of S. The magnetic and conductivity properties can be related to stoichiometry on a poorly occupied Fe1 site and the local environment of a nearly fully occupied Fe2 site. The decreasing T(c) coincides with the increasing Fe1 occupancy and the overall increase in Fe stoichiometry from z = 0 to z = 2. Our results indicate that the irregularity of the Fe2-Se/S tetrahedron is an important controlling parameter that can be used to tune the ground state in the new superconductor family.     

Quadrupolar ordering in LaMnO3 revealed from scattering data and geometric modeling

Many strongly correlated materials display quadrupolar (Jahn-Teller) distortion of the local octahedral structural units. It is common for these distortions to be observed by probes of local structure but absent in the crystallographic average structure. The ordering of these quadrupoles is important in determining the properties of manganites and cuprates, and the nature of the disorder in these structures has been an unsolved problem. We combine high resolution scattering data and novel geometrical modeling techniques to obtain a detailed picture of the local atomic structure, and also to extract the quadrupolar order parameter associated with the distorted octahedra. We show that in LaMnO3, quadrupoles undergo a strong first-order phase transition at 730 K, but with nonzero order parameter remaining in the high-temperature phase.