Equidistribution of negative statistics and quotients of Coxeter groups of type B and D

We generalize some identities and q-identities previously known for the symmetric group to Coxeter groups of type B and D. The extended results include theorems of Foata and Schützenberger, Gessel, and Roselle on various distributions of statistics, like inversion number, major index, and descent number. In order to show our results we provide explicit characterizations of the systems of minimal coset representatives of Coxeter groups of type B and D.     

Colored-descent representations of complex reflection groups <Emphasis Type="Italic">G</Emphasis>(<Emphasis Type="Italic">r,p, n</Emphasis>)

We study the complex reflection groups G(r, p, n). By considering these groups as subgroups of the wreath products , and by using Clifford theory, we define combinatorial parameters and descent representations of G(r, p, n), previously known for classical Weyl groups. One of these parameters is the flag major index, which also has an important role in the decomposition of these representations into irreducibles. A Carlitz type identity relating the combinatorial parameters with the degrees of the group, is presented.     

Investigation of the Dynamic Response of Swirling Flows Based on LES and Experiments

The dynamic response of a swirling flow undergoing vortex breakdown is investigated via Large Eddy Simulation (LES) and experiments in a water flow facility. The investigation is carried out following previous work on the link between thermoacoustic combustion instabilities and coherent structures in lean premixed gas turbine combustors. The velocity field transfer function is obtained in LES from the Unit Impulse Response determined via application of a low intensity broadband noise perturbation of the inflow mass flow rate and the Wiener-Hopf filtering method. In the experiments, harmonic fluctuations in the water flow rate through the swirler are generated via a piston mounted on the side wall of the test facility and activated with a low frequency linear motor. The velocity field transfer function is then obtained via phase averaging applied to Particle Image Velocimetry snapshots which are collected at prescribed values of the harmonic phase. The analysis, which is carried out in terms of coherent structures identified via Proper Orthogonal Decomposition, gives numerical transfer functions with amplitude and phase consistent with the experimental ones.     

Solid phase extraction of penicillins from milk by using sacrificial silica beads as a support for a molecular imprint

We have prepared molecularly imprinted beads with molecular recognition capability for target molecules containing the penicillanic acid substructure. They were prepared by (a) grafting mesoporous silica beads with 6-aminopenicillanic acid as the mimic template, (b) filling the pores with a polymerized mixture of methacrylic acid and trimethylolpropane trimethacrylate, and (c) removing the silica support with ammonium fluoride. The resulting imprinted beads showed good molecular recognition capability for various penicillanic species, while antibiotics such as cephalosporins or chloramphenicol were poorly recognized. The imprinted beads were used to extract penicillin V, nafcillin, oxacillin, cloxacillin and dicloxacillin from skimmed and deproteinized milk in the concentration range of 5–100 μg·L⁻¹. The extracts were then analyzed by micellar electrokinetic chromatography by applying reverse polarity staking as an in-capillary preconcentration step, and this resulted in a fast and affordable method within the MRL levels, characterized by minimal pretreatment steps and recoveries of 64–90 %.

Penicillanic acid-imprinted beads prepared in preformed porous silica by an imprinting &; etching approach show selectivity towards β-lactams antibiotics. Molecularly imprinted solid phase extraction/micellar electrokinetic chromatography coupled with in-capillary preconcentration resulted in a fast and affordable method for penicillins in milk at MRL levels.

     

Solid phase extraction of penicillins from milk by using sacrificial silica beads as a support for a molecular imprint

We have prepared molecularly imprinted beads with molecular recognition capability for target molecules containing the penicillanic acid substructure. They were prepared by (a) grafting mesoporous silica beads with 6-aminopenicillanic acid as the mimic template, (b) filling the pores with a polymerized mixture of methacrylic acid and trimethylolpropane trimethacrylate, and (c) removing the silica support with ammonium fluoride. The resulting imprinted beads showed good molecular recognition capability for various penicillanic species, while antibiotics such as cephalosporins or chloramphenicol were poorly recognized. The imprinted beads were used to extract penicillin V, nafcillin, oxacillin, cloxacillin and dicloxacillin from skimmed and deproteinized milk in the concentration range of 5–100 μg·L^?1. The extracts were then analyzed by micellar electrokinetic chromatography by applying reverse polarity staking as an in-capillary preconcentration step, and this resulted in a fast and affordable method within the MRL levels, characterized by minimal pretreatment steps and recoveries of 64–90 %.

Effect of fuel mixture fraction and velocity perturbations on the flame transfer function of swirl stabilized flames

A novel methodology is developed to decompose the classic Flame Transfer Function (FTF) used in the thermo-acoustic stability analysis of lean premix combustors into contributions of different types. The approach is applied, in the context of Large Eddy Simulation (LES), to partially-premixed and fully-premixed flames, which are stabilized via a central recirculation zone as a result of the vortex breakdown phenomenon. The first type of decomposition is into contributions driven by fuel mixture fraction and dynamic velocity fluctuations. Each of these two contributions is further split into the components of turbulent flame speed and flame surface area. The flame surface area component, driven by the pure dynamic velocity fluctuation, which is shown to be a dominant contribution to the overall FTF, is also additionally decomposed over the coherent flow structures using proper orthogonal decomposition. Using a simplified model for the dynamic response of premixed flames, it is shown that the distribution of the FTF, as obtained from LES, is closely related to the characteristics of the velocity field frequency response to the inlet perturbation. Initially, the proposed method is tested and validated with a well characterized laboratory burner geometry. Subsequently, the method is applied to an industrial gas turbine burner.     

Acoustic forcing on swirling flow: experiments and simulation

We investigated the effect of sound irradiated from loudspeakers on the flow of preheated air in the combustion chamber of a swirl burner. The temporally periodic pattern of the flow generated by the sound was detected by fast particle image velocimetry (PIV), with a repetition rate that was adapted to the observation of 12 phase angles of the irradiated monochromatic sound. The strong observed movement of the air is related to the movement by the sound itself, as determined by the pressure measurements with microphones. The PIV measurements reveal also a nonlinear interaction between the irradiated sound and the precession of the vortex core. The accuracy of the sound measurements was tested by determining in quiescent air the acoustic velocity by microphones and as well by PIV; good agreement was obtained thereby. Numerical calculations, using large eddy simulation and accounting for the sound forcing by variation in the mass flow at the inlet of the computational domain, approximately reproduce some of the experimental results.