A Tin(IV) Porphyrin with Two Axial Organometallic NCN‐Pincer Platinum Units

A tin(IV) porphyrin was combined with two axial NCN‐pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN‐pincer platinum derived benzoic acid. The solid‐state structure determined by X‐ray crystallography revealed some close contacts between the pincer complexes and the meso‐p‐tolyl subsitutents of the porphyrin. It was shown by ¹H NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures.     

Constructing orthogonal pandiagonal Latin squares and panmagic squares from modular n‐queens solutions

In this article, we show how to construct pairs of orthogonal pandiagonal Latin squares and panmagic squares from certain types of modular n‐queens solutions. We prove that when these modular n‐queens solutions are symmetric, the panmagic squares thus constructed will be associative, where for an n × n associative magic square A = (a_ij), for all i and j it holds that a_ij + an?i?1,n?j?1 = c for a fixed c. We further show how to construct orthogonal Latin squares whose modular difference diagonals are Latin from any modular n‐queens solution. As well, we analyze constructing orthogonal pandiagonal Latin squares from particular classes of non‐linear modular n‐queens solutions. These pandiagonal Latin squares are not row cyclic, giving a partial solution to a problem of Hedayat. © 2007 Wiley Periodicals, Inc. J Combin Designs 15: 221–234, 2007     

The completion of the classification of the regular near octagons with thick quads

Brouwer and Wilbrink [3] showed the nonexistence of regular near octagons whose parameters s, t₂, t₃ and t satisfy s ≥ 2, t₂ ≥ 2 and t₃ ≠ t₂(t₂+1). Later an arithmetical error was discovered in the proof. Because of this error, the existence problem was still open for the near octagons corresponding with certain values of s, t₂ and t₃. In the present paper, we will also show the nonexistence of these remaining regular near octagons. MSC2000 05B25, 05E30, 51E12 Postdoctoral Fellow of the Research Foundation - Flanders     

The valuations of the near hexagons related to the Witt designs S(5,6,12) and S(5,8,24)

Valuations of dense near polygons were introduced in 16 . In the present paper, we classify all valuations of the near hexagons ??₁ and ??₂, which are related to the respective Witt designs S(5,6,12) and S(5,8,24). Using these classifications, we prove that if a dense near polygon S contains a hex H isomorphic to ??₁ or ??₂, then H is classical in S. We will use this result to determine all dense near octagons that contain a hex isomorphic to ??₁ or ??₂. As a by‐product, we obtain a purely geometrical proof for the nonexistence of regular near 2d‐gons, d ≥ 4, whose parameters s, t, t_i (0 ≤ i ≤ d) satisfy (s, t₂, t₃) = (2, 1, 11) or (2, 2, 14). The nonexistence of these regular near polygons can also be shown with the aid of eigenvalue techniques. © 2005 Wiley Periodicals, Inc. J Combin Designs 14: 214–228, 2006     

A preemptive repeat priority queue with resampling: Performance analysis

In this paper, we analyze a discrete-time preemptive repeat priority queue with resampling. High-priority packets have preemptive repeat priority, and interrupted low-priority packets are subjected to independent retransmission attempts. Both classes contain packets with generally distributed transmission times. We show that the use of generating functions is beneficial for analyzing the system contents and packet delay of both classes. The influence of the priority scheduling on the performance measures is illustrated by some numerical examples. This work has been supported by the Interuniversity Attraction Poles Programme–Belgian Science Policy.     

Polyethene with pendant fullerene moieties

Polyethene with fullerene moieties pendant on short-chain branches was prepared by the catalytic copolymerization of ethene and a fullerene-containing vinylic comonomer, yielding polyethene copolymers containing up to 25 wt% of C60.