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1.
A zinc coordination polymer derived from pyridine-2,6-dicarboxylate (PDC), {[Zn2(PDC)2]}n, was successfully prepared via conventional, sonication and microwave-irradiation methods. The composition and characteristics of the obtained coordination polymers (CPs) were investigated by elemental analysis, TGA/DTA, X-ray diffraction and spectroscopic techniques. The so obtained CPs were heat-treated in the air at 600 °C for 2 h to produce ZnO of nanosized particles (NPs). It is of interest to note that the synthesis approach of the precursor greatly affects both the nanoparticle size and the structure of the resulting ZnO NPs. Moreover, the smallest particle size was associated with the sample derived from the ultrasonically prepared precursor. TEM analysis revealed that all samples have sphere-like morphologies. Structural analysis of the prepared ZnO samples was conducted and compared using Rietveld analysis of their PXRD patterns. Optical band gap calculations based on analysis of the UV–vis spectra of ZnO samples using Tauc's power law were achieved. The highest band gap of 3.63 eV was observed for ZnO sample obtained from the ultrasonically prepared precursor. Furthermore, the photocatalytic activity of ZnO NPs for the removal of Eosin Y color was monitored. The highest removal efficiency was recorded for ZnO originated from the ultrasonically synthesized precursor. Enhancement of removal efficiency that reached 98% was attained in only a period of 8 min. Its recycling test showed that it can be reused without structural changes over four cycling experiments. 相似文献
2.
Asia Al-jabiry Dr. Martin Palmer Dr. James Langridge Dr. Jeddidiah Bellamy-Carter Dr. David Robinson Prof. Neil J. Oldham 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(55):13783-13792
Native mass spectrometry is now an important tool in structural biology. Thus, the nature of higher protein structure in the vacuum of the mass spectrometer is an area of significant interest. One of the major goals in the study of gas-phase protein structure is to elucidate the stabilising role of interactions at the level of individual amino acid residues. A strategy combining protein chemical modification together with collision induced unfolding (CIU) was developed and employed to probe the structure of compact protein ions produced by native electrospray ionisation. Tractable chemical modification was used to alter the properties of amino acid residues, and ion mobility-mass spectrometry (IM-MS) utilised to monitor the extent of unfolding as a function of modification. From these data the importance of specific intramolecular interactions for the stability of compact gas-phase protein structure can be inferred. Using this approach, and aided by molecular dynamics simulations, an important stabilising interaction between K6 and H68 in the protein ubiquitin was identified, as was a contact between the N-terminus and E22 in a ubiquitin binding protein UBA2. 相似文献
3.
We report on a new (to our knowledge) configuration incorporating both birefringence and quasi-phase-matching, enabling efficient phase-matched nonlinear diffraction in one-dimensional periodically poled nonlinear crystals. We demonstrate the method experimentally, showing an efficient nonlinear diffraction to the first few orders in two types of crystals, MgO doped congruent lithium niobate and congruent lithium niobate, and characterize its efficiency dependence on the fundamental power, the propagation angle, and the crystal temperature. This configuration can increase efficiencies observed in nonlinear diffraction experiments, enables ferroelectric domain characterization by nonlinear microscopy, and can be used to determine the duty cycles of periodically poled nonlinear crystals. 相似文献
4.
M. Khan Asia Anjum C. Fetecau 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2011,62(4):749-759
In this study, the exact solutions of the Stokes second problem for a Burgers?? fluid are presented when the relaxation time satisfies the conditions ?? =???2/4 and ?? >???2/4. The velocity field and the associated tangential stress, when only one initial condition is necessary for velocity, are determined by means of the Laplace transform. The physical interpretation for the emerging parameters is discussed with the help of graphical illustrations. The similar solutions for the Stokes?? first problem are obtained as the limiting cases of our solutions. 相似文献
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6.
M. Khan Asia Anjum Haitao Qi C. Fetecau 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2010,45(2):133-145
This paper deals with exact solutions for some oscillating motions of a generalized Oldroyd-B fluid. The fractional calculus
approach is used in the constitutive relationship of fluid model. Analytical expressions for the velocity field and the corresponding
shear stress for flows due to oscillations of an infinite flat plate as well as those induced by an oscillating pressure gradient
are determined using Fourier sine and Laplace transforms. The obtained solutions are presented under integral and series forms
in terms of the Mittag–Leffler functions. For α = β = 1, our solutions tend to the similar solutions for ordinary Oldroyd-B fluid. A comparison between generalized and ordinary
Oldroyd-B fluids is shown by means of graphical illustrations. 相似文献
7.
M. Khan Asia Anjum Haitao Qi C. Fetecau 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2010,61(1):133-145
This paper deals with exact solutions for some oscillating motions of a generalized Oldroyd-B fluid. The fractional calculus approach is used in the constitutive relationship of fluid model. Analytical expressions for the velocity field and the corresponding shear stress for flows due to oscillations of an infinite flat plate as well as those induced by an oscillating pressure gradient are determined using Fourier sine and Laplace transforms. The obtained solutions are presented under integral and series forms in terms of the Mittag–Leffler functions. For α = β = 1, our solutions tend to the similar solutions for ordinary Oldroyd-B fluid. A comparison between generalized and ordinary Oldroyd-B fluids is shown by means of graphical illustrations. 相似文献
8.
S. A. Agamy M. Y. Khalil M. Y. Hamza W. A. Abou-Taleb 《Isotopes in environmental and health studies》2013,49(6):287-291
Microstructure defects play a very important role in the swelling of irradiated stainless steel. This work is a parametric study of the effects of microstructural defects on the swelling of ion-irradiated steel. For simplicity, vacancy loop effects were neglected. Cold working was found to play a complicated role in the swelling behavior. On one hand, it increase the bias to interstitial absorption due to the increase in dislocation density. On the other hand, it decreases the total flux of point defects to voids by the decrease of the point defect concentrations. Grain size has also a strong effect on swelling. It was found that large gain sizes produces higher swelling and vise versa, i.e. the larger the surface of grain boundaries the less the irradiation-produced swelling. Similar effects were found for precipitates. 相似文献
9.
The associated prime ideals of powers of polymatroidal ideals are studied, including the stable set of associated prime ideals of this class of ideals. It is shown that polymatroidal ideals have the persistence property and for transversal polymatroids and polymatroidal ideals of Veronese type the index of stability and the stable set of associated ideals is determined explicitly. 相似文献
10.
Maria Elisa Fernandes Dimitri Leemans Asia Ivić Weiss 《Aequationes Mathematicae》2016,90(5):1045-1067
We study incidence geometries that are thin and residually connected. These geometries generalise abstract polytopes. In this generalised setting, guided by the ideas from the polytope theory, we introduce the concept of chirality, a property of orderly asymmetry occurring frequently in nature as a natural phenomenon. The main result in this paper is that automorphism groups of regular and chiral thin residually connected geometries need to be C-groups in the regular case and \({C^+}\)-groups in the chiral case. 相似文献