STUDY ON THE SEQUENCE STRUCTURE OF SBR BY 13C—NMR METHOD Ⅰ. ASSIGNMENT FOR UNSATURAT CARBONS SPECTRA*

The sequence structures of emulsion-processed SBR and solution-processed (by lithium catalyst) SBR were investigated by ~(13)C-NMR spectroscopy. Seventeen peaks within unsaturated carbon region were recorded under the adopted experimental conditions. Assignments for these peaks were made by empirical-parameter-evaluation method.     

聚丙烯成核剂研究进展

聚丙烯材料被越来越多的应用于汽车领域、工程塑料等,聚丙烯性能的优化也成为工业界和学术界研究的热点问题。聚丙烯因其良好的机械性能、加工性能、价格低廉而备受关注,但其低温脆性大、热变形温度低、易收缩等缺点也制约了该类材料的发展和在某些领域的应用。对聚丙烯的改性关键是对其分子链规整度、球晶尺寸的调控,成核剂改性是聚丙烯改性中相对简单易行的方法。聚丙烯成核剂种类繁多,各俱特色,本文在综述了聚丙烯成核剂的基础上提出了新型聚丙烯改性成核剂,即大分子成核剂,并展望了大分子成核剂的发展前景。     

Poly(N-isopropylacrylamide)-grafted dual stimuli-responsive filter paper for protein separation

Thermal and salt dual stimuli-responsive filter-paper-based membranes were prepared by UV-induced grafting of NIPAM-based polymers on paper surface. The grafting ratio could be controlled by monomer concentration during grafting polymerization. The results from pressure drop measurement of the mobile phase flowed cross the membrane demonstrate that an appropriate grafting ratio would be 8%-10%. Protein adsorption on the membrane through hydrophobic interaction could be promoted by increasing temperature and lyotropic salt concentration. The effect of grafted polymer structure on protein binding performance was studied. Filter paper grafted with NIPAM-based branched copolymer consisting of hydrophobic monomer moieties shows ten times higher protein binding capacity than that of the original filter paper. The separation of plasma proteins using the dual stimuli-responsive membrane was examined to demonstrate feasible application for hydrophobic interaction chromatographic separation of proteins.     

含疏水链节的聚N-异丙基丙烯酰胺共聚物的温敏性

采用溶液聚合法合成了一系列N-异丙基丙烯酰胺(NIPAM)与甲基丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯或甲基丙烯酸丁酯的无规共聚物,用浊度观测法和光散射法测定了不同共聚物水溶液的温敏相转变行为.结果表明:所得共聚物的低临界溶解温度(LCST)均低于均聚物PNIPAM的,酯类单体的结构和含量对共聚物的LCST有显著影响,其中酯基上的烷基对共聚物LCST的影响能力大于丙烯酸酯α位上的烷基,前者对增大共聚物的疏水性有更大贡献.通过NIPAM与特定丙烯酸酯单体进行无规共聚可以合成转变温度低于PNIPAM均聚物且具有预设LCST数值的水溶性温敏聚合物.     

热可逆共价交联反应及其研究进展

梗概评述了环戊二烯（ＣＰＤ）与双环戊二烯（ＤＣＰＤ）之间Ｄｉｅｌｓ－Ａｌｄｅｒ反应的特点,以及将其引作大分子间交联键的思路;以此为基础详细讨论了热可逆共价交联聚合物的分析方法。制备路线,以及利用这一反应目前所达到的研究水平和成就 。     

氯化聚乙烯的热可逆共价交联

采用新型热可逆共价交联剂 ,以溶液反应法使氯化聚乙烯 (CPE)交联制得了凝胶量在 80 %左右的共价交联CPE ,研究了不同牌号CPE、催化剂及其用量、反应温度、反应时间及交联剂用量对CPE交联程度的影响 ,并测定了共价交联CPE的热可逆转化特性     

STUDY ON THE SEQUENCE STRUCTURE OF BUTADIENE-STYRENE RUBBER BY ~(13)C-NMR METHOD V.CALCULATION METHOD OF DIAD COMPOSITION

The calculating equations which could be used to obtain diad composition from the peakintensities of carbon spectra were derived. The result of the microstructure calculated from thediad compositions was in good agreement with that obtained through IR or ~1H-NMR measurement.     

温敏支化聚合物的合成及其双重相转变行为

将N-异丙基丙烯酰胺(NIPAm)与具有温敏性的大分子单体进行共聚,制得了主链与支链在水溶液中具有不同相转变温度的温敏支化聚合物。经过双重相转变过程后,通过扫描电子显微镜(SEM)可以观察到聚合物链形成的具有较大比表面积的"葡萄串"结构,光散射实验中聚合物粒径大小随着温度升高发生两次突变进一步解释了双重相转变过程中聚合物微观形态的变化。在温敏支化聚合物溶液样品的差示扫描量热法(DSC)曲线中可以观察到35℃与21℃出现两组相对独立的吸热峰,从热力学的角度描述了双重相转变行为。通过使用二维红外相关光谱技术分析了温敏支化聚合物各基团对温度扰动的响应顺序,其结果说明仅存在于支链中的丙烯酸丁酯(BA)结构单元要先于NIPAm结构单元发生变化,对双重相转变行为的机理有了更进一步的说明。"葡萄串"结构的形成有效地提高了温敏聚合物的疏水比表面积,有望应用于生化分离领域。