Multiple Scattering Effects of Ag Particles in Random Ag-SiN Film

A layer of 40nm-thick Ag-SiN film with Ag nano-particles embedded and distributed randomly in the SiN thin film were deposited by the method of radiant-frequency magnetron sputtering. Specimens orderly comprising a random Ag-SiN film and an optical phase change recording layer were exposed to a focused laser beam with wavelength of 69Ohm. It is shown that, with a random Ag-SiN layer deposited above the recording layer. Calculation by the finite difference time domain method of a 4Ohm-thick SiN film under a Gaussian beam irradiation has been carried out to simulate the near-field distribution in the film, which showed a huge local near-field intensity enhancement of about 200 times if small Ag particles with diameter of 6 nm were modelled inthe SiN film in the central region of the in cident laser spot.     

基于Delaunay三角法的电压门控钾离子通道的分类和拓扑结构识别

本文构建了一个Delaunay模型对电压门控钾离子(Kv)通道进行预测。该方法通过建立一系列带有隐含变量的单纯形来分类电压门控钾离子通道,然后通过未知序列在主成分空间里面的投影来预测结构。结果表明该模型无论是在分类和结构预测上均可以得到很好的结果。     

Experimental and Theoretical Evidence for the Existence of Broad Forbidden Gaps in the Three—Component Composite

The influence of localized resonance on the properties of band-gaps of the two-dimensional periodic composite are analysed numerically and experimentally by comparing the two-component phononic crystal with the three-component one. The three-component composite which exhibits localized resonance in the elastically soft coating ring is composed of a square array of coated cylinders embedded in an epoxy resin. The coated cylinders consist of a steel inner core and a rubber coating, which has much smaller wave velocity and mass density than the matrixand tile inner material. Tile measured transmission power of tile three-component composite drops to the noise level in a broad ultrasonic frequency interval in contrast to the binary composite, which is in good agreement with the calculation using the finite element method.     

在配位体络合体系中合成窄分布聚苯乙烯

本文报道了在RLi-配位体络合体系中阴离子聚合方法合成窄分布聚苯乙烯的研究结果.在己烷、庚烷、甲苯等溶液中合成分子量范围为10~2～10~3。的窄分布聚苯乙烯(MWD<1.10)时,以鹰爪豆矸、N,N,N’,N’-四甲基乙二胺为配位体的络合体系,聚合操作简便,效果非常好.在非极性溶剂中加一定比例的THF以后,该体系也能合成分子量范围为10~4～10~5的窄分布聚苯乙烯.     

对高一化学“氯化氫、鹽酸”教材及教学的研討

(一)氯化氫 氯化氫这節教材,根据北京市教育局編的授課計劃綱要規定为一课時。照新的高中化学课本把它排在鹵素一章講完氯以後。这新的編排順序較为恰当,因为講过氯的化学性質——     

对高三化学“铝和它的化合物”一章教材及教学的商讨

“鋁和它的化合物”这一章是在碱金屬、碱土金屬之後提出來的。鋁在週期表中位於第三週期,学生們对本週期的其他元素已有了初步的知識。尤其在鈉、鈣等元素学習了以後,有必要通过鋁的学習使他們形成元素週期性遞变的完整概念。此外,在高中化学裹,只提出鉀、钠、鈣、鋁,鈇等金屬來个別的研究,鉀、鈉是作     

碱性介质中二过碲酸合铜(III)氧化乙二醇的反应动力学及机理

本文采用分光光度法研究了碱性介质中二过碲酸合铜(III)(DTC)氧化乙二醇(Glgcol)在291.2-303.2K的反应动力学机理。结果表明, 反应对氧化剂(DTC)是一级, 对乙二醇也是一级, 准一级([Glycol]0>>[DTC]0)速率常数Kobs随着[OH^-]增加而增加, 随着[TeO4^2^-]增加而降低, 并且有负盐效应, 提出了一种含有前期平衡的反应机理。据此导出了一个能够解释全部实验事实的速率方程, 求出平衡常数、速控步骤的速率常数及298.2K时的活化参数。     

初中化学“碳、燃烧”的教学法(上)

本章教材在讲授时,应多与学生日常生活知识加以联系。本章教材分为两大部分:一为碳及含碳化合物的性质、生成与用途的部分,一为燃烧及火焰与燃料之研究。根据教学大纲,本章教材可分十课时进行。讲授次序,与课本的节目不同,除已精简者之外,讲授程序如后:第一课Ⅰ.碳第七节自然界里的碳第八节碳的用途第二课第四节二氧化碳和碳酸第三课第五节碳酸盐第六节一氧化碳第四课Ⅱ.燃烧第一节什么是燃烧第二节燃烧的条件第五课第二节燃烧的条件(续)     

Stereoselective Synthesis of （E）-α-Aryltellurenylvinyl-stannanes and Their Application in the Synthesis of Stereodefined Trisubstituted Alkenes

(E)-α-Aryltellurenylvinylstannanes have been synthesized stereoselectively via the hydrozirconation of alkynylstannanes, followed by the reactions with aryltellurenyl iodides. (E)-α-Aryltellurenylvinylstannanes can undergo sequential cross coupling reactions with both electrophiles and nucleophiles in the presence of transition metal complexes to form two carbon-carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereoselectively.