(Co,Ni) Se2/C@FeOOH中空笼状纳米结构的自旋调控加速水氧化催化研究

氢气作为一种清洁无污染的可再生能源,可以有效地解决全球能源危机和环境污染问题.低能耗水裂解制氢是公认的未来清洁制氢的有效途径之一.水裂解反应分为阳极上发生的析氧反应(OER)和阴极上发生的析氢反应,由于阳极半反应涉及四电子过程,反应动力学缓慢,进而导致整个水分解产氢效率低下,成为规模化水裂解制氢应用的瓶颈.贵金属Ir基...     

Dynamic phase transition of ferroelectric nanotube described by a spin-1/2 transverse Ising model

The dynamic phase transition properties for ferroelectric nanotube under a spin-1/2 transverse Ising model are studied under the effective field theory(EFT)with correlations.The temperature effects on the pseudo-spin systems are unveiled in three-dimensional(3-D)and two-dimensional(2-D)phase diagrams.Moreover,the dynamic behaviors of exchange interactions on the 3-D and 2-D phase transitions under high temperature are exhibited.The results present that it is hard to obtain pure ferroelectric phase under high temperature;that is,the vibration of orderly pseudo-spins cannot be eliminated completely.     

Study of Phase Transition Properties in Epitaxial Ferroelectric Film

Based on the transverse Ising model and using decoupling approximation to the Fermi-type Green＇s function, we study the phase transition properties of the epitaxial ferroeleetric film with one substrate. A general recursive equation of the ferroelectric thin film with two n-layer materials is obtained, which enables us to study the phase transition properties for any number layers for epitaxial ferroelectric thin film. With the help of this equation, we analyze the effect of the exchange interaction and the transverse field in the phase diagram, the influence to the polarizations and Curie temperature numerically. The results show that epitaxial ferroelectric film are able to induce a strong increase or decrease of Curie temperature to different exchange interactions and transverse fields within the epitaxial film layers. The theoretical results are in reasonable accordance with experimental data of different ferroelectric thin film.