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南京关口每年从国外进口铅、锌精矿达几百万吨,随着我国国民经济的发展,作为重要有色金属来源的该矿种的进口量仍将逐年增加。硫化物精矿在运输和储存过程中都有可能发生氧化,由此导致金属品位的波动是常见现象,然而此前在这方面的报导甚少。为此,作者以铅锌硫化物精矿为例对其进行了模拟状态下的氧化实验并采用能谱、光学显微镜、化学物相分析、X射线衍射分析、扫描电镜等手段对氧化前及氧化后的样品进行了鉴定。结果表明,在模拟精矿储运条件下两种精矿的氧化皆甚为明显,铅精矿为1.5%,而锌精矿达到了14.5%,由此引起的品位变化是不可忽视的。鉴于有色金属硫化物精矿在储运过程中呈现了它们的易氧化性并对品位产生影响,所以有关这类矿产品的商贸过程中涉及取样、样品加工和保管、公证等问题,均应在科学实验基础上规范化。 相似文献
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Euhedral crystals of the uncommon low-temperature mineral lansfordite have been obtained by the synthetic method, and the crystal structure analysis has been accomplished correspondingly. The structural parameters and the general view of structure were presented for the first time. The results obtained show that the coordination configuration of two magnesium ions in the unit cell is octahedral arrangement and the coordination number is 6, but in two forms: one in the complex ion Mg(CO_3)_2(H_2O)_4~(2-) and the other in the Mg(H_2O)_6~(2+). There is only a CO_3~(2-) group in the structure, not three distinct groups as reported by Hill et al. previously based on the IR absorption spectrum research data. The authors of this paper believe that the exact chemical formula of lansfordite should be expressed as "Mg(H_2O)_6. Mg(CO_3)_2 (H_2O)_4", and MgCO_3-5H_2O is only a simple chemical expression. 相似文献
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随着我国铜精矿进口量的日益增加及物料性质趋于复杂,有必要采用科学高效的方法对矿产品开展属性鉴别,来规避矿产品进口贸易中潜在的风险。本次对某疑似“掺杂明铜”的进口铜精矿开展物性鉴定,采用矿物自动分析仪(BPMA)、光学显微镜、X-射线衍射仪等综合手段查明了产品中的物质组成和结构特征,并从矿床成因、冶金机理、选矿工艺等多角度对该铜精矿的产出来源和生产工艺进行了深入研究和探讨,论证产品中未掺杂有冶金组分,最终确定其为天然铜精矿。从而协助了海关部门对该货源顺利通关,也保障了贸易双方的权益,实现境外战略资源的有效利用。 相似文献
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