仿生合成中的单核铜蛋白及其含铜金属模拟酶的研究

仿生化学的研究重点之一是对各类天然金属酶的氧化模拟。文章主要综述了近年来国内外对含金属铜的单核蛋白质体蓝素结构、半乳糖氧化酶、含铜的胺氧化酶和铜锌超氧歧化酶等的结构特点和催化功能的研究进展。质体蓝素结构为畸变的四面体,参与光合作用过程中电子传递;半乳糖氧化酶活性中心结构是平面四边形,能将伯醇氧化成相应的醛;铜锌超氧歧化...     

一维链状配位聚合物[Ag(bix)(NO3)(H2O)]n的合成和晶体结构

A one-dimensional (1D) Z conformation coordination polymer, [Ag(bix)(NO₃)(H₂O)]_n was obtained by the reaction between AgNO₃ and flexible ligand of 1,4-bis(imidazol-1-ylmethyl)-benzene under hydrothermal conditions. It crystallizes in triclinic with space group P1. The crystallographic data of the compound are: a=0.777 1(2) nm, b=1.043 4(3) nm, c=1.082 7(3) nm, α=71.403(4)°, β=80.946(5)°, γ=88.794(4)°. The 1D chainlike structure was connected by π-π interaction between phenyl rings, leading to a 2D layered network. The lattice water and the NO₃^- anions were involved between the layers, therefore the 2D layered structure further extended to an intricate 3D framework. CCDC: 257100.