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利用原位红外光谱技术研究了常压下CO和CH3ONO多相催化合成草酸二甲酯的反应.发现在草酸二甲酯生成的同时还存在副反应,副产物NO继续与CO反应生成CO2和N2O.铜在合金催化剂中起辅助作用,铜分散把,使CO桥式吸附减少,线式吸附增多.主反应与CO桥式吸附无关,而副反应却依赖于CO的桥式吸附.CO线式吸附具有更高的反应活性. 相似文献
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聚合物固载化聚乙二醇季胺盐型相转移催化剂的结构与催化活性 总被引:3,自引:0,他引:3
The gelatinous and macroporous phase transfer catalysts with multiple active centers were synthesized by means of quarterisation of PEG tertiary amine and chloromethylated St DVB copolymer. They were examined as phase transfer catalysts in the reaction of n C 8H 17 Br with solid NaI. The experimental results showed that the reaction rate was first order with respect to the concentration of n C 8H 17 Br. The effects of catalyst structure on the catalytic activity were also investigated. The observed reaction rate constant ( k obsd ) increased as the degree of cross linking of polymer decreased. Macroporous catalysts showed a higher activity (2~2 5 times) than that of microporous catalysts with the same degree of cross linking of polymer, particle size and amount of supported PEG. Molecular weight of PEG also showed much influence on k obsd . As molecular weight of PEG rose properly, the catalysts showed a higher activity. The results were discussed from the aspect of triphase catalysis reaction mechanism. 相似文献
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0聚合物固载的聚乙二醇季铵盐型相转移催化剂的合成,表征及相… 总被引:4,自引:0,他引:4
合成了一系列含有聚乙二聚链和季铵盐两种性中心的离分子相转移催化剂,并考察了它闪在正溴辛烷与固体碘化钠的亲核了以代反应中的相转移催化性能。 相似文献
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