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Combined effect of modified zeolite 13X and β-nucleating agent on improving β-crystal content and toughening polypropylene random copolymer 总被引:1,自引:0,他引:1
Although addition of β-NUCLEATING agent directly into homo-polypropylene(PPH) is a useful method to improve β-CRYSTAL content and toughen PPH, polypropylene random copolymer(PPR) makes this method powerless due to its random structure and low crystallinity. In this study, the-nucleated PPR with high β-CRYSTAL content was prepared by a novel high effective β-NUCLEATING system which consists of-nucleation agent(TMB-5) and modified zeolite 13X(M13X). It was found that M13X and TMB-5 had a synergistic influence on improving β-CRYSTAL content and toughening PPR. The content of β-CRYSTAL in PPR/M13X/TMB-5 was significantly larger than the sum of that in PPR/M13X and PPR/TMB-5. Besides,fracture behavior, phase morphology and relaxation of matrix chain segments were also investigated. The results showed that M13X and TMB-5 improved the mobility of amorphous chain segments at low temperature and contributed to much energy dissipation. This work provides a powerful method to modify PPR. 相似文献
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水溶性低分子壳聚糖的制备 总被引:21,自引:0,他引:21
Oxidative degradation of chitosan by H2O2-NaClO mixed oxidant is studied in acidic condition.The effects of concentration of H2O2,reactive temperature and reaction time on oxidative degradation reaction are studied.The results show that the method of oxidative degradation of chitosan with H2O2-NaClO mixed oxidant is effective for preparation of water-soluble chitooligosaccharides. 相似文献
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