全文获取类型
收费全文 | 96710篇 |
免费 | 11606篇 |
国内免费 | 13955篇 |
专业分类
化学 | 70557篇 |
晶体学 | 775篇 |
力学 | 5050篇 |
综合类 | 1208篇 |
数学 | 12128篇 |
物理学 | 32553篇 |
出版年
2023年 | 1334篇 |
2022年 | 1872篇 |
2021年 | 3221篇 |
2020年 | 3577篇 |
2019年 | 3159篇 |
2018年 | 2923篇 |
2017年 | 3164篇 |
2016年 | 3712篇 |
2015年 | 3454篇 |
2014年 | 4822篇 |
2013年 | 7782篇 |
2012年 | 5625篇 |
2011年 | 6004篇 |
2010年 | 5120篇 |
2009年 | 6245篇 |
2008年 | 6510篇 |
2007年 | 6736篇 |
2006年 | 6060篇 |
2005年 | 4740篇 |
2004年 | 4518篇 |
2003年 | 3847篇 |
2002年 | 3090篇 |
2001年 | 2752篇 |
2000年 | 2281篇 |
1999年 | 1916篇 |
1998年 | 1790篇 |
1997年 | 1511篇 |
1996年 | 1421篇 |
1995年 | 1356篇 |
1994年 | 1240篇 |
1993年 | 1151篇 |
1992年 | 1051篇 |
1991年 | 829篇 |
1990年 | 683篇 |
1989年 | 580篇 |
1988年 | 533篇 |
1987年 | 417篇 |
1986年 | 386篇 |
1985年 | 477篇 |
1984年 | 392篇 |
1983年 | 221篇 |
1982年 | 400篇 |
1981年 | 582篇 |
1980年 | 511篇 |
1979年 | 533篇 |
1978年 | 425篇 |
1977年 | 339篇 |
1976年 | 289篇 |
1974年 | 127篇 |
1973年 | 198篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
利用hirota双线性法,得到(3+1)维孤子方程、(3+1)维KP-Boussinesq方程、(2+1)维修正Caudrey-Dodd-Gibbon-Kotera-S awada方程、Hirota-Satsuma浅水波方程的精确解,并做出一部分解的图形,进一步研究解的结构和性质. 相似文献
2.
Dariusz Marek Adam Domaski Joanna Domaska Jakub Szygua Tadeusz Czachrski Jerzy Klamka 《Entropy (Basel, Switzerland)》2021,23(5)
In this article, a way to employ the diffusion approximation to model interplay between TCP and UDP flows is presented. In order to control traffic congestion, an environment of IP routers applying AQM (Active Queue Management) algorithms has been introduced. Furthermore, the impact of the fractional controller and its parameters on the transport protocols is investigated. The controller has been elaborated in accordance with the control theory. The TCP and UDP flows are transmitted simultaneously and are mutually independent. Only the TCP is controlled by the AQM algorithm. Our diffusion model allows a single TCP or UDP flow to start or end at any time, which distinguishes it from those previously described in the literature. 相似文献
3.
水热合成法制备了不同磁性纳米洋葱碳(MCNOs)负载量(0%、1%、3%、5%)的MCNOs/CdS光催化剂。并通过X射线衍射分析(XRD)、扫描电子显微镜(SEM)、傅里叶红外光谱(FT-IR)、X射线光电子能谱(XPS)、紫外可见光光谱(UV-Vis)、磁滞回线测定仪(VSM)对其进行表征,探究了MCNOs负载比例对催化剂在可见光下降解RhB性能及机理的影响。结果表明,MCNOs能有效提高CdS的光催化效果,复合3%MCNOs后降解率为96%,与纯CdS相比降解率提高了30%,磁性分析表明,其具有良好的顺磁性并能实现催化剂的有效回收。MCNOs/CdS在可见光下催化降解RhB的一级反应动力学直线有较好的拟合度,表明制备的催化剂有较好的催化活性。 相似文献
4.
Ioulia Chikina Sawako Nakamae Valeriy Shikin Andrey Varlamov 《Entropy (Basel, Switzerland)》2021,23(2)
We discuss the peculiarities of the Seebeck effect in stabilized electrolytes containing the colloidal particles. Its unusual feature is the two stage character, with the linear increase of differential thermopower as the function of colloidal particles concentration during the first stage (“initial state”) and dramatic drop of it at small during the second one (“steady state”). We show that the properties of the initial state are governed by the thermo-diffusion flows of the mobile ions of the stabilizing electrolyte medium itself and how the colloidal particles participate in the formation of the electric field in the bulk of the suspension. In its turn, we attribute the specifics of the steady state thermoelectric effect the massive colloidal particles undergoing slow thermal diffusion and the break down of their electro-neutrality in the vicinity of electrodes. 相似文献
5.
We investigate the possibility of phantom crossing in the dark energy sector and the solution for the Hubble tension between early and late universe observations. We use robust combinations of different cosmological observations, namely the Cosmic Microwave Background (CMB), local measurement of Hubble constant (), Baryon Acoustic Oscillation (BAO) and SnIa for this purpose. For a combination of CMB+BAO data that is related to early universe physics, phantom crossing in the dark energy sector was confirmed at a 95% confidence level and we obtained the constraint km/s/Mpc at a 68% confidence level, which is in perfect agreement with the local measurement by Riess et al. We show that constraints from different combinations of data are consistent with each other and all of them are consistent with phantom crossing in the dark energy sector. For the combination of all data considered, we obtained the constraint km/s/Mpc at a 68% confidence level and the phantom crossing happening at the scale factor at a 68% confidence level. 相似文献
6.
7.
In this study, we investigated an alternative method for the chemical CO2 reduction reaction in which power ultrasound (488 kHz ultrasonic plate transducer) was applied to CO2-saturated (up to 3%) pure water, NaCl and synthetic seawater solutions. Under ultrasonic conditions, the converted CO2 products were found to be mainly CH4, C2H4 and C2H6 including large amount of CO which was subsequently converted into CH4. We have found that introducing molecular H2 plays a crucial role in the CO2 conversion process and that increasing hydrogen concentration increased the yields of hydrocarbons. However, it was observed that at higher hydrogen concentrations, the overall conversion decreased since hydrogen, a diatomic gas, is known to decrease cavitational activity in liquids. It was also found that 1.0 M NaCl solutions saturated with 2% CO2 + 98% H2 led to maximum hydrocarbon yields (close to 5%) and increasing the salt concentrations further decreased the yield of hydrocarbons due to the combined physical and chemical effects of ultrasound. It was shown that CO2 present in a synthetic industrial flue gas (86.74% N2, 13% CO2, 0.2% O2 and 600 ppm of CO) could be converted into hydrocarbons through this method by diluting the flue gas with hydrogen. Moreover, it was observed that in addition to pure water, synthetic seawater can also be used as an ultrasonicating media for the sonochemical process where the presence of NaCl improves the yields of hydrocarbons by ca. 40%. We have also shown that by using low frequency high-power ultrasound in the absence of catalysts, it is possible to carry out the conversion process at ambient conditions i.e., at room temperature and pressure. We are postulating that each cavitation bubble formed during ultrasonication act as a “micro-reactor” where the so-called Sabatier reaction - - takes place upon collapse of the bubble. We are naming this novel approach as the “Islam-Pollet-Hihn process”. 相似文献
8.
《中国物理 B》2021,30(5):56501-056501
Thermal expansion control is always an obstructive factor and challenging in high precision engineering field. Here,the negative thermal expansion of Nb F_3 and Nb OF_2 was predicted by first-principles calculation with density functional theory and the quasi-harmonic approximation(QHA). We studied the total charge density, thermal vibration, and lattice dynamic to investigate the thermal expansion mechanism. We found that the presence of O induced the relatively strong covalent bond in Nb OF_2, thus weakening the transverse vibration of F and O in Nb OF_2, compared with the case of Nb F_3.In this study, we proposed a way to tailor negative thermal expansion of metal fluorides by introducing the oxygen atoms.The present work not only predicts two NTE compounds, but also provides an insight on thermal expansion control by designing chemical bond type. 相似文献
9.
Orientation dependence in high harmonics of ZnO with polarization corrections to counteract the birefringent effect 下载免费PDF全文
《中国物理 B》2021,30(7):74204-074204
We investigate the influence of the birefringence on the high-order harmonics in an a-cut Zn O crystal with midinfrared laser pulses. The high harmonics exhibit strong dependence on the alignment of the crystal with respect to the laser polarization. We introduce the Jones calculus to counteract the birefringent effect and obtain the harmonics with polarization corrections in Zn O. We show that the birefringent effect plays an important role in the orientation dependence of HHG. 相似文献
10.
We propose a conjecture on the relative twist formula of l-adic sheaves, which can be viewed as a generalization of Kato—Saito's conjecture. We verify this conjecture under some transversal assumptions. We also define a relative cohomological characteristic class and prove that its formation is compatible with proper push-forward. A conjectural relation is also given between the relative twist formula and the relative cohomological characteristic class. 相似文献