首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   366篇
  免费   3篇
  国内免费   32篇
化学   176篇
力学   78篇
数学   7篇
物理学   140篇
  2023年   5篇
  2022年   1篇
  2021年   6篇
  2020年   8篇
  2019年   3篇
  2018年   2篇
  2017年   12篇
  2016年   11篇
  2015年   17篇
  2014年   9篇
  2013年   18篇
  2012年   9篇
  2011年   30篇
  2010年   22篇
  2009年   43篇
  2008年   26篇
  2007年   34篇
  2006年   35篇
  2005年   19篇
  2004年   19篇
  2003年   18篇
  2002年   15篇
  2001年   2篇
  2000年   4篇
  1999年   6篇
  1998年   5篇
  1997年   4篇
  1996年   3篇
  1995年   5篇
  1994年   4篇
  1993年   1篇
  1989年   2篇
  1987年   1篇
  1986年   1篇
  1982年   1篇
排序方式: 共有401条查询结果,搜索用时 15 毫秒
1.
Glass is a promising substitute substrate material being evaluated for electronic packaging technology. Improving the electroless copper plated layer adhesion of the glass is one of the most important considerations for development of the technology. An excimer laser (248 nm) was used for structured texturing of glass surfaces (to improve adhesion) by changing mask dimensions, laser operating parameters and overlapping pitch spacing, and therefore producing a range of micro-scale features. Electroless plated copper adhesion strength was assessed using quantitative scratch testing, demonstrating that micro-patterned structures can significantly improve copper/glass adhesion. New ISO 25178 Part 2 areal surface texture parameters were used to characterise the surface roughness of ablated glass surfaces, and correlated to the scratch testing results. Highly correlated parameters were identified that could be used as predictive surface design tools, directly linking surface topography to adhesion performance, without the need for destructive adhesion quantification via scratch testing.  相似文献   
2.
We examine a mathematical model that describes a quasistatic adhesive contact between a viscoplastic body and deformable foundation. The material’s behaviour is described by the rate-type constitutive law which involves functions with a non-polynomial growth. The contact is modelled by the normal compliance condition with limited penetration and adhesion, a subdifferential friction condition also depending on adhesion, and the evolution of bonding field is governed by an ordinary differential equation. We present the variational formulation of this problem which is a system of an almost history-dependent variational–hemivariational inequality for the displacement field and an ordinary differential equation for the bonding field. The results on existence and uniqueness of solution to an abstract almost history-dependent inclusion and variational–hemivariational inequality in the reflexive Orlicz–Sobolev space are proved and applied to the adhesive contact problem.  相似文献   
3.
对电极在染料敏化太阳能电池(DSCs)中主要起催化氧化还原反应及收集电荷的作用,铂对电极常用的制备方法为磁控溅射法,但其成本较高,制备条件苛刻. 本文通过引入低成本的表面活性剂Span-85,所制得的铂对电极的附着力、透光率和均匀性显著改善,实现了面积可控,与两步浸泡法和旋涂热解法制备的对电极在DSCs中的光电转换效率分别为7.30%,6.96%和7.03%. 紫外-可见吸收光谱、扫描电镜和附着力测试等结果表明,(1)添加表面活性剂有利于增加附着力及改善透光率和均匀性;(2)使用该法制备的Pt/FTO对电极的透光率与两步浸泡法制作的相同,且铂粒子分布更加均匀. 电化学阻抗图谱、塔菲尔极化曲线和循环伏安曲线结果表明,丝网印刷方法制备的Pt/FTO对电极具有更加优异的催化性能,且该法更有利于降低其生产成本和大规模生产.  相似文献   
4.
Raman spectroscopy was evaluated regarding its specific value in terms of detection of interdiffusion in two-component injection molded parts. Two-component injection molded parts made of four material combinations chosen from polypropylene, styrene based thermoplastic elastomer, polycarbonate, polystyrene and polymethyl methacrylate produced by varying melt temperatures of the second component TM2 were investigated.In principle, Raman spectroscopy was found to be a powerful tool to detect interdiffusion. However, some restrictions arise. These include spatial resolution limit and detection limit. Interdiffusion lengths ranging from below 1 μm–3 μm were determined. Either an increase, a decrease or no change of the interdiffusion length for increasing TM2 was detected. The interdiffusion lengths were compared with the stress and elongation at break obtained by tensile tests. No distinct correlation of interdiffusion length and the mechanical properties was found. However, a high TM2 provoked an increase in the stress and elongation at break.  相似文献   
5.
The resistance of fluid infusion inside a thin film that separates an opening gap leads to viscous adhesion. Viscous adhesion can be detrimental for some mechanical devices such as valves or during additive manufacturing processes. On the other hand, it is also a mechanism found in nature for dynamic reversible adhesion. In this article we review analysis and measurements of viscous adhesion. In particular, we give conditions where viscous adhesion dominates over other surface forces. We also describe how characteristics of the solid surfaces such as roughness and elasticity, as well as the compliance of the load cell can be incorporated in the analysis. Finally, we discuss the knowledge gaps and scientific areas where a better understanding of viscous adhesion could be beneficial.  相似文献   
6.
We present an experiment on the morphology and dynamics of a crack front propagating at the interface between an elastomer and a glass slide patterned with a prescribed distribution of defects. Regimes of high and low pinning strength are explored by changing the fracture energy contrast of the defects. We first analyze the roughness of crack fronts by measuring their typical amplitude in real and Fourier space. Irrespective of the pinning regime, no well defined self-affine behavior is found which may be explained by the emergence of an intermediate lengthscale between the defect size and the sample size. Then, we show that the dynamics at high fracture energy contrast results in rapid jumps alternating with periods of arrest. The distributions of speeds, displacements and waiting times are found to have an exponential decay which is directly related to the distribution of distances between defects along the direction of propagation.  相似文献   
7.
A cohesive zone model for two-dimensional adhesive contact between elastic cylinders is developed by extending the double-Hertz model of Greenwood and Johnson (1998). In this model, the adhesive force within the cohesive zone is described by the difference between two Hertzian pressure distributions of different contact widths. Closed-form analytical solutions are obtained for the interfacial traction, deformation field and the equilibrium relation among applied load, contact half-width and the size of cohesive zone. Based on these results, a complete transition between the JKR and the Hertz type contact models is captured by defining a dimensionless transition parameter μ, which governs the range of applicability of different models. The proposed model and the corresponding analytical results can serve as an alternative cohesive zone solution to the two-dimensional adhesive cylindrical contact.  相似文献   
8.
Elastocapillary phenomena involving elastic deformation of solid structures coupled with capillary effects of liquid droplets/films can be observed in a diversity of fields,e.g.,biology and microelectromechanical systems(MEMS).Understanding the physical mechanisms underlying these phenomena is of great interest for the design of new materials and devices by utilizing the effects of surface tension at micro and nano scales.In this paper,some recent developments in the investigations on elastocapillary phenomena are briefly reviewed.Especially,we consider the deformation,adhesion,self-assembly,buckling and wrinkling of materials and devices induced by surface tensions or capillary forces.The main attention is paid to the experimental results of these phenomena and the theoretical analysis methods based on continuum mechanics.Additionally,the applications of these studies in the fields of MEMS,micro/nanometrology,and biomimetic design of advanced materials and devices are discussed.  相似文献   
9.
For accurately predicted adhesion laws of fibrillar structures contribute to the rational design of high-performance biomimetic adhesives, an adhesion model is proposed to study the directional adhesion behavior of an extensible elastic fiber that contacts a rigid smooth surface with its side surface under the coupling effect of normal and shear forces, based on the extensible Euler Bernoulli beam theory and the surface energy concept. The deformed configuration of the fiber is obtained analytically, and on the basis of this result, the detachment mode and the normal pull-off force of the fiber for a given shear force are predicted directly. It is also found that, due to the extensibility of the fiber, there exists a maximum normal pull-off force (MNPF) when an optimal shear force is applied. The MNPF will be enhanced by increasing the axial stiffness, and reduced by increasing the bending stiffness. In addition, generating an optimal pre-tension in the adhered part of the fiber will maximize the MNPF. The derived adhesion law is expected to contribute to the optimal design and applications of single-level fibrillar adhesives.  相似文献   
10.
Ce mémoire décrit la synthèse de phosphonates comportant une chaîne perfluorée. Ces composés sont obtenus par la télomérisation d'allylphosphonates de dialkyle en présence d'un agent de transfert fluoré de type mercaptan. Ensuite, nous employons deux méthodes de déalkylation menant sélectivement soit au monoacide soit au diacide phosphonique. Tous ces produits comprenant une extrémité de chaîne phosphonée, sous forme acide ou ester, ont été caractérisés et leur adhésion respective sur des plaques d'acier est étudiée. Ces tests montrent que le monoacide phosphonique est un excellent promoteur d'adhésion et qu'il est aussi efficace que le diacide. This article describes the synthesis of phosphonic derivatives bearing a perfluorinated chain. These compounds have been synthetized by telomerization of dialkyl allylphosphonate with a fluorinated transfer agent type mercaptan. Then two methods of dealkylation leading selectively were used to mono or to diacid phosphonic moieties. All the products bearing phosphonic end-groups, more or less acidic, have been characterized and their own adhesion on steel plates is studied. These tests show that phosphonic monoacid is an excellent adhesion promoter on steel, as efficient as the diacid compound.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号