首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   591篇
  免费   83篇
  国内免费   126篇
化学   584篇
力学   28篇
综合类   6篇
数学   25篇
物理学   157篇
  2023年   1篇
  2022年   12篇
  2021年   2篇
  2020年   8篇
  2019年   9篇
  2018年   7篇
  2017年   11篇
  2016年   5篇
  2015年   4篇
  2014年   42篇
  2013年   56篇
  2012年   51篇
  2011年   23篇
  2010年   11篇
  2009年   17篇
  2008年   26篇
  2007年   22篇
  2006年   21篇
  2005年   22篇
  2004年   31篇
  2003年   39篇
  2002年   89篇
  2001年   196篇
  2000年   31篇
  1999年   20篇
  1998年   10篇
  1997年   10篇
  1996年   5篇
  1995年   4篇
  1994年   1篇
  1993年   4篇
  1992年   2篇
  1991年   3篇
  1988年   1篇
  1987年   1篇
  1984年   2篇
  1983年   1篇
排序方式: 共有800条查询结果,搜索用时 15 毫秒
1.
常晓明  王兵 《实验力学》1993,8(3):278-280
本试验采用“冻结”刚度这一新测试方法,测试了 SMC 15MN 液压机上横梁的刚度分布,并抽样验证了此种方法的可靠性。试验结果表明 SMC 压机结构在刚度分布上比较合理,刚性较好,同以往箱型焊接结构相比有较大优越性。  相似文献   
2.
一堂物理课     
 我是一位中学教师,我深爱《现代物理知识》,在讲授《卢瑟福核式结构》一课时,我向同学们言简意赅地介绍了那上面的一篇文章:《原子核壳模型发现前后》.当我讲述卢瑟福提出有效模型是怎样成功地解释盖革与马斯顿的实验结果时,同学们顿时活跃起来,纷纷想一展身手,体验一次科学发明的过程.然而,物理上的每一个发现,都是科学家凭借坚实的理论基础和实验事实而获得的.在教师的指导下,同学们通过阅读教材,得出了如下结论:“如果是枣糕式模型,α粒子穿过原子内部时,它受到原子内两侧的斥力相互抵消,使α粒子偏转不会很大”.  相似文献   
3.
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl…  相似文献   
4.
It is becoming a focus to synthesize and assemble organic-inorganic materials, especially, to synthesize charge-transfer complexes formed by polyoxometalate and organic donors. They have attracted much attention because such complexes are active in their electric, magnetic and optic properties1-4, many investigations about them have been done and some crystal structures of them were reported5-6. But, the disadvantage of these crystals is instability at room temperature. According to the view…  相似文献   
5.
The natural product, hainanolide 1, also under the name harringtonolide2 demonstrated antitumor and antiviral activities in preliminary test. Its structure was determined by X-ray diffraction. The total synthesis of 1 was reported recently by Mander3. A different scheme of its synthesis has been studied in our laboratory4. Here the determination of the stereochemical structure of the key intermediate 2 in the synthesis was reported. HMBC and HMQC spectra identified the skeleton and H,…  相似文献   
6.
It is well known that the study on biomimetic oxygen carriers not only has important theoretic significance to discover the mechanism of reversible bonding, activating oxygen as well as the oxidation reaction in organism, but also has potential application in separating oxygen from air and realizing the high efficiency and selectivity of catalytic oxidation reaction under a mild condition1. Metal- porphyrin and metal- phthalol- gaunine have been extensively used as biomimetic oxygen carriers u…  相似文献   
7.
The use of supercritical fluids (SCFs) as solvents has been attracting widespread interest in the research and commercial applications. The study of partial molar volumes of solutes at infinite dilution in the near-critical region is of considerable fundamental importance, as these data reflects the interactions occurring between the solute and the solvent. Experimental measurements of partial molar volumes may be divided into two categories: direct and indirect methods. The direct methods…  相似文献   
8.
Much effort has been dedicated to the molecular design and synthesis of model proteins to define protein folding interactions and to develop protein-based materials. Among them, the ring-opening polymerization of -amino acid-N-carboxyanhy- drides (NCAs) has drawn much attention because the resulting artificial polypeptides have wide applications in biotechnology, biomineralization and diagnostics1, 2. It is well known that dendrimers are hyperbranched macromolecules possessing a very high co…  相似文献   
9.
A highly efficient catalyst indium (III) tribromide is used to synthesize 5-alkoxy- carbonyl-4-hydrocarbyl-3,4-dihydropyrimidin-2(1H)-ones by a three-component coupling of β-keto ester, aldehydes and urea through improved Biginelli reaction.  相似文献   
10.
The increasing demand to produce enantio-pure pharmaceuticals, flavors, and other fine chemicals has advanced the field of asymmetry catalytic technologies. Among all asymmetry catalytic methods, catalytic enantioselective hydrogenation of unsaturated bonds such as olefins, ketones, and imines, which employs dihydrogen and small amounts of transition-metal complexes modified intrinsically by chiral ligands, is now recognized as being the most promising strategy for the synthesis of large amount…  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号