Tl-1223高温超导薄膜在蓝宝石单晶基片上的生长和性能研究

本文报道了采用射频磁控溅射法和快速升温烧结法在R面取向的蓝宝石单晶基片上生长CeO₂缓冲层和Tl-1223超导薄膜，研究了缓冲层生长情况和先驱膜后退火条件对超导薄膜结晶情况和超导特性的影响。AFM和XRD表征结果显示，蓝宝石基片经过退火后其表面形成具有光滑平台的台阶结构，同时基片的晶体质量得到了改善；本文所制备的CeO₂缓冲层和Tl-1223超导薄膜具有较好的c轴生长取向，而且两者呈现良好的ab面内织构。SEM表征结果显示，生长良好的Tl-1223超导薄膜呈层状结构，表面光滑平整、结构致密。在液氮环境下，测得所制备Tl-1223超导薄膜的临界转变温度T_c约为111 K,临界电流密度J_c(77 K,0 T)约为1.3 MA/cm²。     

双冠醚钾离子选择电极的研究 Ⅰ.一些双冠醚钾电极的响应特性

测定了十九种双冠醚制成的PVC膜钾电极的响应性能.以4′ ,4″-(邻-或间-亚苯基二氧亚甲基)双(苯并-15-冠-5)(10,11)和4′,4″-(邻-或间-亚苯基二氧亚甲基)[(苯并-15-冠-5)(苯并-18-冠-6)](7,8)等性能较好.25℃时,电极10和7的线性响应范围为5×10~(-2)～10~(-5)mol·dm~(-3)(KCl),K_(K+,Na+)~(pot)为3×10~(-4),K_(K+,Cs+)~(pot)<10~(-2);低温时,响应性能显著变差,斜率降低(0℃,～40mV/pK~+). 实验表明,带酯键桥联的双冠醚制成的钾电极的性能不稳定,使用寿命不长,一些Schiff硷型双冠醚或其还原产物仲胺型双冠醚钾电极,响应线性范围较窄,斜率偏低,K_(K+,Na+)~(pot)～10~(-3).     

HT-7装置逆磁测量

通过在HT 7装置的内真空室安装一对同心圆逆磁线圈 ,并运用软件补偿的方法 ,对HT 7装置的逆磁通量进行了测量。在杂散场测量与软件补偿实验中 ,发现同心圆逆磁线圈感应的杂散信号主要来自垂直场、涡流电流、等离子体电流和纵场电流的变化。逆磁测量结果表明 ,在等离子体线平均密度 ne 很低时 ( ne <2 .2 ×10 1 3cm- 3) ,HT 7等离子体的总体能量约束时间τE 随 ne 线性变化 ;在 ne 很高时 ( ne >2 .2 × 10 1 3cm- 3) ,τE 则趋于饱和 ,其饱和值约为 2 1ms。并运用计算机统计分析的方法给出了欧姆加热的τE 定标律为τE =1.5 7 ne0 .72±0 .0 4 ×Ip0 .35± 0 .0 2 B0 .31 ± 0 .0 3T 。     

Water and Ion Permeation through Electrically Charged Nanopore

The behaviour of water and small solutes in confined geometries is important to a variety of chemical and nanofluidic applications. Here we investigate the permeation and distribution of water and ions in electrically charged carbon cylindrical nanopore during the osmotic process using molecular dynamics simulations. In the simulations, charges are distributed uniformly on the pores with diameter of 0.9 nm. For nanopores with no charge or a low charge, ions are difficult to enter. With the increasing of charge densities on the pores, ions will appear inside the nanopores because of the large electronic forces between the ions and the charged pores. Different ion entries induce varying effects on osmotic water flow. Our simulations reveal that the osmotic water can flow through the negatively charged pore occupied by K^＋ ions, while water flux through the positively charged pores will be disrupted by Cl^- ions inside the pores. This may be explained by the different radial distributions of K^＋ ions and Cl^- ions inside the charged nanopores.     

一款基于多物理场调控的超宽带线-圆极化转换器

为了在微波波段实现可调谐的线-圆极化转换器的设计,结合固态等离子体与二氧化钒设计了一种基于多物理场调控的超宽带线-圆极化转换器,通过改变固态等离子体谐振单元激励状态和人为改变外部温度(T)来实现对该线-圆极化转换器工作频段的调控.采用了全波仿真的方法对该极化转换器的极化转换率曲线、反射相位曲线、轴比曲线、表面电流图进行了计算,并讨论了参数r_1与r_3对轴比的影响.仿真结果表明,当固态等离子体区域均未激励且T68℃时,3 dB轴比频带为14.3—29.7 GHz,相对带宽为70%;当固态等离子体区域均被激励且T68℃时,3 dB轴比频带为14.4—23.4 GHz与28.6—35.9 GHz,相对带宽分别为47.61%和22.64%;当固态等离子体区域未激励且T≥68℃时,3 dB轴比频带为8.4—11.2 GHz与18.7—29.5 GHz,相对带宽分别为28.57%与44.81%.通过改变固态等离子体的激励状态和外部温度,实现了该超宽带线-圆极化转换器工作带宽向高频和低频区域的移动.     

电位滴定法测定定心藤中总有机酸的含量

为研究定心藤中总有机酸的最佳提取工艺,建立其测定方法,采用正交实验法考察了乙醇含量、固液比、提取时间及提取次数4个因素对该工艺的影响,利用电位滴定法对其进行了测定。结果表明,定心藤中总有机酸提取的最佳提取工艺为:乙醇含量75%,固液比1∶10,提取时间2.5 h,提取次数3次;电位滴定法对其测定简单可行,精密度高,重现性好,为定心藤进一步研究和资源开发利用提供一定的科学依据。     

Water Transport through Multinanopores Membranes

We investigate the influence of correlation between water molecules transport through the neighbouring nanopores, whose centres are at a distance of only 6.2A, using the molecular dynamics simulations. Water molecule distribution in nanopore and average water flow are obtained. It is found that the average water molecule number and water flow are slightly different between a system made of the neighbouring nanopores and a system of a single pore. This indicates that transport of water chains in neighbouring pores do no show significant influence each other. These findings should be helpful in designing efficient artificial membrane made of nanopores and providing an insight into effects of the biological channel structure on the water permeation.     

补骨脂及其混伪品蛋白质电泳鉴别

为鉴别补骨脂与其混伪品,对两种种子的可溶性蛋白质进行了聚丙烯酞胺凝胶电泳分析.结果表明,补骨脂及其混伪品的电泳图谱存在显著差异,电泳图谱可作为补骨脂及其混伪品的鉴别依据.     

Observation of intermittency in edge plasma of SUNIST tokamak

The temporal intermittency of the fluctuation-driven particle transport fluxes is analysed by using data obtained from Langmuir probe array in the edge of the Sino-United Spherical Tokamak (SUNIST). The conditional statistics analysis indicates that the intermittent structures have a characteristic time width of about 30μs, which is the typical fluctuation time scaling. It is also found that the transport fluxes have a multifractal character over the fluctuation time scales, and exhibit a long-time-range correlation character with self-similar parameter H>0.5 in the plasma confinement time scales. Furthermore, the analyses show that the level of the intermittency and the long-range correlation of the fluxes vary with increasing plasma density. These observations are consistent with the prediction of the avalanche-like model.