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Raman and mid-infrared spectroscopic study of geometrically frustrated hydroxyl cobalt halides at room temperature 下载免费PDF全文
Mid-infrared absorption and Raman spectra of the geometrically frustrated material series,hydroxyl cobalt halides β-Co 2 (OH) 3 Cl and β-Co 2 (OH) 3 Br,are first,to the best of our knowledge,measured at room temperature,to study the corresponding relationship between their vibrational spectral properties and crystal microstructures.Through the comparative analysis of the four spectra we have categorically assigned the OH-related vibration modes of hydroxyl groups in the trimeric hydrogen bond environment (Co 3 ≡OH) 3… Cl/Br,and tentatively suggested vibration modes of O-Co-O,Co-O and Cl/Br-Co-Cl/Br units.These results can also become the basis for analysing their low-temperature spectral properties,which can help to understand the underlying physics of their exotic geometric frustration phenomena around phase transition temperatures. 相似文献
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针对激光定向干扰系统要求对抗1 m ~3 m和3 m ~5 m 2种类型探测器,需要输出相应2种波段激光,通过高重频调Q技术和种子注入光放大技术,获得高功率高光束质量1.06 m光纤激光输出,外置起偏器获得2束激光输出,分别为泵浦周期极化钽酸锂和周期极化铌酸锂晶体,实现高功率1 m ~3 m 和3 m ~5 m激光输出。在电源输入电流60 A,调Q驱动频率50 kHz的条件下,获得最高功率7.5 W的2 m激光和4.2 W的3.9 m激光,频率转换效率为39.5%。实验结果表明:通过光纤激光器泵浦光参量振荡器,可获得高功率1 m ~3 m和3 m ~5 m双波段激光输出。 相似文献
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Microstructured hydroxyl environments and Raman spectroscopy in selected basic transition-metal halides 下载免费PDF全文
Raman vibrational spectra of the selected basic (hydroxyl OH and deuteroxyl OD) transition-metal halides, geometrically frustrated material series α-, β-, γ-Cu2(OH)3Cl, α-Cu2(OH)3Br, β-Ni2(OH)3Cl, β-Co2(OH)3Cl, β-Co2(OH)3Br, γ-Cu2(OD)3Cl, and β-Co2(OD)3Cl are measured at room temperature and analysed to investigate the relationship between the microstructured OH environments and their respective Raman spectra. Among these selected samples, the last two are used to determine the OH stretching vibration region (3600 cm-1—3300 cm-1) and OH bending vibration region (1000 cm-1—600 cm-1) of OH systems in the spectra. Through the comparative analysis of the distances d(metal—O), d(O—halogen), and d(OH), the strong metal—O interaction and trimeric hydrogen bond (C3v, Cs or C1 symmetry) are found in every material, but both determine simultaneously an ultimate d(OH), and therefore an OH stretching vibration frequency. According to the approximately linear relationship between the OH stretching vibration frequency and d(OH), some unavailable d(OH) are guessed and some doubtful d(OH) are suggested to be corrected. In addition, it is demonstrated in brief that the OH bending vibration frequency is also of importance to check the more detailed crystal microstructure relating to the OH group. 相似文献
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Y and inverted Y-type four-level schemes for optical quantum coherence systems, which may be intuitively considered to be very simple, have not been studied intensively till now. In this paper, we present the multiformity of these two types of schemes by considering that they can be classified into nine possible level styles as the second-order sub-schemes using laser fields. Further we point out the complexity of their more than one hundred realistic configurations as the third-order four-level sub-schemes that may appear in the optical quantum coherence experiments. Throughout this paper we review which configurations have been studied in some research aspects and which ones not, according to our knowledge, in order to be propitious to next steps of theoretical and experimental investigations, especially for applications in the fields of quantum optics, quantum information science, laser spectroscopy, and so on. 相似文献
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