TPR investigations on the reducibility of Cu supported on Al2O3, zeolite Y and SAPO-5

Reducibility of Cu supported on Al₂O₃, zeolite Y and silicoaluminophosphate SAPO-5 has been investigated in dependence on the Cu content using a method combining conventional temperature programmed reduction (TPR) by hydrogen with reoxidation in N₂O followed by a second the so-called surface-TPR (s-TPR). The method enables discrimination and a quantitative estimation of the Cu oxidation states +2, +1 and 0. The quantitative results show that the initial oxidation state of Cu after calcination in air at 400 °C, independent on the nature of the support, is predominantly +2. Cu²⁺ supported on Al₂O₃ is quantitatively reduced by hydrogen to metallic Cu⁰. Comparing the TPR of the samples calcined in air and that of samples additionally pre-treated in argon reveals that in zeolite Y and SAPO-5 Cu²⁺ cations are stabilized as weakly and strongly forms. In both systems, strongly stabilized Cu²⁺ ions are not auto-reduced by pre-treatment in argon at 650 °C, but are reduced in hydrogen to form Cu⁺. The weakly stabilized Cu²⁺ ions, in contrast, may be auto-reduced by pre-treatment in argon at 650 °C forming Cu⁺ but are reduced in hydrogen to metallic Cu⁰.     

双模板法制备具有介孔孔壁的三维有序大孔二氧化铈及其改善的低温还原性能

以聚甲基丙烯酸甲酯(PMMA)为硬模板,三嵌段共聚物F127、十六烷基三甲基溴化铵(CTAB)或聚乙二醇(PEG)为软模板剂(表面活性剂),柠檬酸为络合剂,硝酸铈为金属前驱体,采用双模板法成功地合成出具有介孔孔壁的三维有序大孔(3DOM)结构的立方相CeO2样品CeO2-F127,CeO2-CTAB和CeO2-PEG,...     

The classification problem for von Neumann factors

We prove that it is not possible to classify separable von Neumann factors of types II₁, II_∞ or IIIλ, 0?λ?1, up to isomorphism by a Borel measurable assignment of “countable structures” as invariants. In particular the isomorphism relation of type II₁ factors is not smooth. We also prove that the isomorphism relation for von Neumann II₁ factors is analytic, but is not Borel.     

贵金属助剂对费-托合成用钴基催化剂的促进作用

贵金属助剂促进的费-托合成用钴基催化剂具有高活性和长链烃(C₅⁺)选择性优越等特点,被广泛应用于由合成气制清洁燃料的合成反应中。 本文重点讨论了贵金属助剂对活性钴物种的结构（还原度、分散度、双金属颗粒或合金的构成）, 钴基催化剂稳定性以及其对费-托合成的反应速率和产物选择性的影响规律。     

On the (semi)lattices induced by continuous reducibilities

Continuous reducibilities are a proven tool in Computable Analysis, and have applications in other fields such as Constructive Mathematics or Reverse Mathematics. We study the order‐theoretic properties of several variants of the two most important definitions, and especially introduce suprema for them. The suprema are shown to commutate with several characteristic numbers (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

About Segment Complexity of Turing Reductions

We apply complexity concepts to define a new sort of sub-Turing reducibilities ≤ ?? make the degree hierarchy thinner and to obtain some new specifications of the well known jump inversion theorem of Friedberg. We show that this theorem doesn't hold when ≤ T is replaced with ≤ ??, where ?? is any countable subset of the class ?? of all total increasing functions f : ? → ?.     

On the stable rank and reducibility in algebras of real symmetric functions

Let A_?(??) denote the set of functions belonging to the disc algebra having real Fourier coefficients. We show that A_?(??) has Bass and topological stable ranks equal to 2, which settles the conjecture made by Brett Wick in [18]. We also give a necessary and sufficient condition for reducibility in some real algebras of functions on symmetric domains with holes, which is a generalization of the main theorem in [18]. A sufficient topological condition on the symmetric open set ?? is given for the corresponding real algebra A_?(??) to have Bass stable rank equal to 1 (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

A jump inversion theorem for the enumeration jump

Abstract. We prove a jump inversion theorem for the enumeration jump and a minimal pair type theorem for the enumeration reducibilty. As an application some results of Selman, Case and Ash are obtained. Received: 15 May 1998     

Mechanism of the formation of singularities for quasilinear hyperbolic systems with linearly degenerate characteristic fields

One often believes that there is no shock formation for the Cauchy problem of quasilinear hyperbolic systems (of conservation laws) with linearly degenerate characteristic fields. It has been a conjecture for a long time (see Arch. Rational Mech. Anal. 2004; 172 :65–91; Compressible Fluid Flow and Systems of Conservation Laws in Several Space Variables. Springer: New York, 1984) and it is still an open problem in the general situation up to now. In this paper, a framework to justify this conjecture is proposed, and, by means of the concept such as the strict block hyperbolicity, the part richness and the successively block‐closed system, some general kinds of quasilinear hyperbolic systems, which verify the conjecture, are given. Copyright © 2007 John Wiley & Sons, Ltd.     

制备方法和助剂对贵金属铱催化剂还原性质的影响

通过应用TPR等方法研究了制备方法、焙烧温度和助剂氧化铈含量等对催化剂还原性质、吸附性能的影响 .结果表明分步浸渍法制备的催化剂活性中心比一步共浸渍法制备的催化剂的活性中心数量多 ;助剂氧化铈含量变化的催化剂中Ce含量为 1%时 ,催化剂的活性中心最多 ;共浸渍的催化剂中 ,加入助剂镁以后 ,使金属易于还原 ,加入助剂铈后 ,使贵金属难于还原