全文获取类型
收费全文 | 2180篇 |
免费 | 266篇 |
国内免费 | 227篇 |
专业分类
化学 | 401篇 |
晶体学 | 8篇 |
力学 | 227篇 |
综合类 | 48篇 |
数学 | 1584篇 |
物理学 | 405篇 |
出版年
2023年 | 17篇 |
2022年 | 36篇 |
2021年 | 44篇 |
2020年 | 59篇 |
2019年 | 52篇 |
2018年 | 56篇 |
2017年 | 70篇 |
2016年 | 79篇 |
2015年 | 45篇 |
2014年 | 97篇 |
2013年 | 194篇 |
2012年 | 98篇 |
2011年 | 96篇 |
2010年 | 97篇 |
2009年 | 144篇 |
2008年 | 150篇 |
2007年 | 131篇 |
2006年 | 138篇 |
2005年 | 143篇 |
2004年 | 90篇 |
2003年 | 93篇 |
2002年 | 75篇 |
2001年 | 88篇 |
2000年 | 83篇 |
1999年 | 75篇 |
1998年 | 66篇 |
1997年 | 68篇 |
1996年 | 44篇 |
1995年 | 38篇 |
1994年 | 27篇 |
1993年 | 13篇 |
1992年 | 11篇 |
1991年 | 18篇 |
1990年 | 6篇 |
1989年 | 10篇 |
1988年 | 15篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 14篇 |
1984年 | 17篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 14篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 7篇 |
1976年 | 3篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有2673条查询结果,搜索用时 62 毫秒
1.
We introduce a new flexible mesh adaptation approach to efficiently compute a quantity of interest by the finite element method. Efficiently, we mean that the method provides an evaluation of that quantity up to a predetermined accuracy at a lower computational cost than other classical methods. The central pillar of the method is our scalar error estimator based on sensitivities of the quantity of interest to the residuals. These sensitivities result from the computation of a continuous adjoint problem. The mesh adaptation strategy can drive anisotropic mesh adaptation from a general scalar error contribution of each element. The full potential of our error estimator is then reached. The proposed method is validated by evaluating the lift, the drag, and the hydraulic losses on a 2D benchmark case: the flow around a cylinder at a Reynolds number of 20. 相似文献
2.
Juan Luis García Guirao Jaume Llibre Wei Gao 《Journal of Difference Equations and Applications》2020,26(2):203-208
The objective of this work is to present sufficient conditions for having positive topological entropy for continuous self-maps defined on a closed surface by using the action of this map on the homological groups of the closed surface. 相似文献
3.
4.
基于Hilbert空间标架理论,借助算子工具,用己有连续广义标架构造了新连续广义标架,并给出了有限个连续广义标架和构成新连续广义标架的充要条件,为构造连续广义标架提供了新方法。 相似文献
5.
对于一般任意支撑的连续梁结构动力稳定性问题,已有的计算方法求解过程都很复杂,给工程设计带来极大的不便.本文提出了一个简化的分析方法,利用现有的商业软件,只需求得连续梁的自然频率及静力屈曲(失稳)荷载,就可容易得到结构的动力失稳区域,当考虑结构阻尼对不稳定区域的影响时,可将阻尼矩阵表达为Rayleigh阻尼的形式.研究结果表明:采用本文计算方法与已有的理论计算方法得到的连续梁主参数共振的不稳定边界非常吻合,而本文计算方法更为简单,计算结果可靠,计算精度高,可满足工程设计的需要. 相似文献
6.
Dr. Antoine Nitelet Dr. Damien Thevenet Dr. Bruno Schiavi Dr. Christophe Hardouin Dr. Jean Fournier Dr. Rodolphe Tamion Prof. Dr. Xavier Pannecoucke Prof. Dr. Philippe Jubault Prof. Dr. Thomas Poisson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(13):3262-3266
The copper-photocatalyzed borylation of aryl, heteroaryl, vinyl and alkyl halides (I and Br) was reported. The reaction proceeded using a new heteroleptic Cu complex under irradiation with blue LEDs, giving the corresponding boronic-acid esters in good to excellent yields. The reaction was extended to continuous-flow conditions to allow an easy scale-up. The mechanism of the reaction was studied and a mechanism based on a reductive quenching (CuI/CuI*/Cu0) was suggested. 相似文献
7.
In this article, we study for the ‐realization of the vector‐valued Schrödinger operator . Using a noncommutative version of the Dore–Venni theorem due to Monniaux and Prüss, we prove that the ‐realization of , defined on the intersection of the natural domains of the differential and multiplication operators which form , generates a strongly continuous contraction semigroup on . We also study additional properties of the semigroup such as extension to L1, positivity, ultracontractivity and prove that the generator has compact resolvent. 相似文献
8.
9.
Ryoichi Doi 《Analytical letters》2019,52(10):1519-1538
Test strips and similar products are highly feasible tools for the rapid and approximate determination of chemical characteristics. Although the application of both the quantitative observation of coloration and regression modeling has recently enabled these products to become quantitative tools, their precision and accuracy may be further improved. In this study, the pseudocolor imaging of the coloration image, derivative spectrophotometry-like differentiation of the coloration values, and logarithmic conversion of the raw and derivative values were compared in terms of the precision and accuracy of the quantitative determination of corrosiveness, glucose, nitrate, and pH using the products. The best regression models for the determination were provided by the combination of pseudocolor imaging and differentiation (nitrate and pH); pseudocolor imaging, differentiation, and square-conversion (corrosiveness); or all of the techniques (glucose). When compared to the use of the original 10 raw coloration variables of red-green-blue, cyan-magenta-yellow-key black, and L*a*b* color models only, the above combinations improved the normalized mean absolute error from 14.8% to 3.09% (corrosiveness), 6.33% to 3.15% (glucose), 7.46% to 4.56% (nitrate), and 3.22% to 0.94% (pH). These achievements were largely attributed to the combination of multiple variables that have non-linear and nonmonotonic relationships with the chemical characteristics. 相似文献
10.
Continuous‐Flow Microwave Synthesis of Metal–Organic Frameworks: A Highly Efficient Method for Large‐Scale Production 下载免费PDF全文
Dr. Marco Taddei Daniel Antti Steitz Prof. Dr. Jeroen Anton van Bokhoven Dr. Marco Ranocchiari 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(10):3245-3249
Metal–organic frameworks are having a tremendous impact on novel strategic applications, with prospective employment in industrially relevant processes. The development of such processes is strictly dependent on the ability to generate materials with high yield efficiency and production rate. We report a versatile and highly efficient method for synthesis of metal–organic frameworks in large quantities using continuous flow processing under microwave irradiation. Benchmark materials such as UiO‐66, MIL‐53(Al), and HKUST‐1 were obtained with remarkable mass, space–time yields, and often using stoichiometric amounts of reactants. In the case of UiO‐66 and MIL‐53(Al), we attained unprecedented space–time yields far greater than those reported previously. All of the syntheses were successfully extended to multi‐gram high quality products in a matter of minutes, proving the effectiveness of continuous flow microwave technology for the large scale production of metal–organic frameworks. 相似文献