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1.
Yongxing Tang Yajun Yu Xinyu Wei Jin Yang Yeting Zhu Yun-Hui Zhao Zilong Tang Zhihua Zhou Xiaofang Li Xianyong Yu 《Tetrahedron letters》2019,60(43):151187
A novel 6-endo-dig cyclization followed by oxidation/elimination of o-alkynylarylaldimines with 4-hydroxybenzylamine was developed for preparation of isoquinolines. The intermediates of this tandem reaction were monitored by mass spectroscopy (MS) to confirm the reaction pathway. This methodology was further applied to the design and synthesis of a novel ratiometric chemosensor for determination of fluoride. 相似文献
2.
Herein we summarized some clean preparation examples to emphasize the concept of dual roles design (or named as “two birds one stone strategy”) in green and sustainable chemistry. In those examples, the reactants and/or solvent play dual roles rendering a cleaner organic preparation process. Consequently, both the chemical waste and manufacturing cost could be reduced. 相似文献
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The present work describes the development of a novel robotic vane shear test tool for characterization of soil parameters with high precision and accuracy. The tool automates industrial standards for testing procedures. The proposed system is capable of performing high resolution torque measurements, which are then used to estimate the shear strength of the soil. The design of the instrument and its advantages over traditional manual instruments are discussed, after which error sources, calibration, and test procedures are described. The developed tool was successfully validated against high-end commercial equipment. The built unit was employed for characterizing mine waste in a laboratory setting and also deployed in the field on board an Unmanned Ground Vehicle for remote soil characterization. 相似文献
5.
The working performance of agricultural machinery is largely determined by the walking performance of the wheel when driving in complex unstructured soil. However, the driving performance of existing wheels is not satisfactory for paddy field with muddy soil. The purpose of the current study is therefore to propose a novel rigid wheel for agricultural machinery which is applicable to paddy field with muddy soil. Firstly, a novel arc edge shaped wheel was designed based on the principles of mechanics on the ground. Then the driving performance of this arc edge shaped wheel was evaluated using FE modeling of interaction between rigid wheel and soil. Finally, the structure originally designed arc edge shaped wheel was improved according to FE modeling results, and this improved design was further evaluated by both FE simulation and prototype experiments. Both FE modeling and experimental results indicate that the improved arc edge shaped wheel proposed in this study has a good driving performance with regarding to wheel sinkage and soil reaction force. The proposed arc edge shaped wheel could be used as an effective component of rice harvester for paddy field with muddy soil. 相似文献
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《中国化学快报》2020,31(7):1855-1858
By virtue of electrochemistry, a series of α,α-dihaloacetophenones were easily obtained with good to excellent yields. This electrochemical procedure was taken in a divided cell with constant current in aqueous media. The reaction can be carried out smoothly at room temperature under metal and oxidant free condition, which provides an eco-friendly synthesis for the α,α-dihaloacetophenone derivatives. 相似文献
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A novel Ni/Na – containing inorganic-organic hybrid supramolecule {(PW12O40)·[Na2(NiH2EDTA·H2O)(H4EDTA)·2H2O]·2H2O·H3O}n (short for NiEDTA-PW12) has been successfully synthesized by solution method, and investigated by thermogravimetric-differential thermal analysis (TG-DTA), ultraviolet visible (UV-Vis) spectroscopy, cyclic voltammetry (CV), photoluminescence (PL), ultraviolet visible diffuse reflectance spectrum (UV-vis DRS) and single-crystal X-ray diffraction (XRD). NiEDTA-PW12 exhibits intriguing infinite supramolecular structure with Na+ ions as linker. Furthermore, NiEDTA-PW12 displays a fast-responsive reversible photochromism under ultraviolet or visible light. The photochromic property of NiEDTA-PW12 has been investigated by techniques of UV-vis DRS and PL, and the impact of the O2 on fading of the colored NiEDTA-PW12 has been investigated. 相似文献
9.
Dr. Qiuhua Liu Wanjie Ren Siwei Zhang Dr. Yang Huang Dilong Chen Dr. Wennan Zeng Prof. Dr. Zaichun Zhou Prof. Dr. Lin He Prof. Dr. Wenping Guo Prof. Dr. Jianfeng Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(8):e202103892
Both geometric architecture and electronic configurations of heme proteins contribute to its activity. In this work we designed and synthesized a series of four copper(II) porphyrin complexes ( 4 -, 3 -, 2 - and 1 -Cu) where the molecular conformations are modulated by a pair of stepwise shortened straps on the same porphyrin side (cis-ortho) to give double bow-shaped skeletons. Single crystal structures demonstrate that the straps gradually increase the saddle deformation and the deviation of the metal centers, which is in accordance with two, unusual d-orbital reconstructions of two different ground states, as revealed by 4 K EPR and DFT calculations. In the study of the electrocatalytic hydrogen evolution reaction (HER), 1 -Cu, with the shortest straps, showed the most apparent improvement of activity. Second coordination sphere (SCS) effects created by the double bow-shaped architecture and the strong saddle porphyrin core in 1 -Cu are found to play key roles in proton trapping during the catalytic process. The work contributes a novel strategy to improve the catalytic performance of heme analogs through ligand geometric modulation. 相似文献
10.
以单纤维十字型横向拉伸试验为研究对象,对纤维/基体界面采用弹性-软化双线性内聚力模型,建立了纤维复合材料在横向拉伸作用下界面法向失效过程的解析模型。得到了沿纤维/基体圆周界面的法向应力分布,纤维/基体界面的状态与界面承载力和单纤维复合材料承载力的关系,以及内聚力参数和试件几何尺寸对它们的影响。结果表明:纤维/基体圆周界面在脱粘前经历全部弹性及弹性+软化两种状态;当界面为弹性状态时,界面法向应力随界面强度线性增加;当界面为弹性+软化状态时,界面软化范围随界面裂纹萌生位移的增加而增大;界面初始脱粘位置与拉伸荷载方向重合;界面初始脱粘时的界面承载力随界面强度及界面裂纹萌生位移的增加而增加,随界面裂纹生成位移的增加而降低;单纤维复合材料的脱粘荷载受基体截面尺寸的影响,当纤维体积含量相同时,沿荷载方向截面尺寸的增大对提高脱粘荷载更显著。 相似文献