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以4, 5-二氰基咪唑(HIMDN)配体, 用常温扩散法合成了2个新颖的金属-有机配合物{[Zn2(IMDN)4(H2O)3]·(H2O)3}n(1)和[Co(IMDN)2(H2O)2]n(2), 并通过元素分析、红外分析、热重分析和X-射线单晶衍射对其进行了表征。结果表明配合物1中2个中心Zn(Ⅱ)离子的配位环境不同, 一个是四配位, 另一个是六配位。配合物2的中心钴(Ⅱ)离子为六配位。2个配合物都为一维链状结构, 并且均通过氢键作用显示出三维结构。此外还研究了配合物1的荧光性质。 相似文献
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采用浸渍法制备了Ni/MgO与Ni/O-D(氧化金刚石)催化剂,分别研究了反应温度和空速对甲烷催化裂解转化率的影响,并利用XPS、SEM、EDS等测试技术对催化剂进行了表征. 结果表明,33Ni/O-D和41Ni/MgO分别在500与650 ℃能长时间维持其催化活性,前者在150 min内的甲烷转化率>8%,后者则在120 min内的甲烷转化率>25%;甲烷初始转化率随裂解反应温度升高而增大,但温度过高导致催化剂迅速失活;降低空速有利于提高甲烷的转化率,但却会降低氢气产量;甲烷裂解生成的碳产物形貌取决于载体和催化反应条件,较低温度(500和550 ℃)下,Ni/O-D表面的裂解碳呈现出纤维状,在650 ℃以上则表现为板结颗粒堆积并将Ni完全覆盖,但该温度下的Ni/MgO表面仍能形成碳纤维,并随空速降低存在直径增加的趋势. 相似文献
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A novel laser-electro magnetic acoustic transducer (EMAT) system for nondestructive testing NDT surface crack of continuous casting billet (CCB) is provided. Rayleigh wave generated by line laser source is used to detect the surface crack of CCB. According to the principle of mode conversion from Rayleigh wave to shear wave, the defect signal is received using the shear wave EMAT sensor in a non-contact way. Experiments are carried out on the steel sample with size 30 × 0.2 ×0.2 (mm) of crack. Further, the influences of life off value and distance between EMAT sensor and laser beam on the testing sensitivity are discussed, respectively. It is found that the life off value is the main factor that effects sensitivity of the proposed method. There is a clear prospect of the method applied to test continuously cast bloom at high temperature. 相似文献
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