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Reactions of Zn(NO3)2·6H2O and MNO3(M = Na, K and Rb) with H2mip(H2mip = 5-methylisophthalic acid) in DMF(DMF = N,N′-dimethylformamide) resulted in the formation of novel heterometallic metal-organic frameworks(Me2NH2)[ZnM(mip)2](1: M = Na; 2: M = K; 3: M = Rb, mip = 5-methylisophthalate dianion for 1~3). These complexes belong to the monoclinic system, space group P2/c and have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveal that 1~3 are 3D isomorphic structures based on a trinuclear unit {ZnM2(?2-COO)2(?3-COO)2} and exhibit pcu topological net and blue fluorescence. 相似文献
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Solvothermal reactions of Zn(NO3)2·6H2O with isophthalic acid in the presence of potassium nitrate lead to an acentric three-dimensional(3D) hetero-metallic inorganic-organic hybrid framework [ZnK2(m-BDC)2(H2O)2]n(1, m-H2 BDC = benzene-1,3-dicarboxylic acid). The crystal was characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction analysis. Complex 1 is of orthogonal crystal system, acentric space group Cmc21 with a = 19.764(6), b = 19.948(6), c = 12.039(4) , V = 4746(3) 3, Z = 4, C32H20O19K4Zn2, Mr = 995.66, Dc = 1.393 g/cm3, F(000) = 2000 and μ = 1.426 mm-1. The final R = 0.0761 and wR = 0.1841. The crystal exhibits remarkable blue luminescence emissions with high quantum yield of 56.02% and displays modest powder SHG efficiency of about 0.7 times that produced by a potassium dihydrogen phosphate(KDP) powder. In addition, it also exhibits potential ferroelectric property. 相似文献
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铁-抗坏血酸-3,3′,5,5′-四溴联苯-双-(重氮氨基偶氮苯)催化褪色光度法测定痕量铁 总被引:4,自引:0,他引:4
研究了在硫酸介质中 ,铁 催化抗坏血酸还原 3 ,3′,5 ,5′ 四溴联苯 双 (重氮氨基偶氮苯 )(TBDPBDAA)而褪色的反应及其动力学条件 ,测定了反应级数和表观活化能 ,建立了催化动力学光度法测定痕量铁的新方法。方法的测定范围为 0~ 0 .0 80mg L;测定下限为 4.3× 1 0 - 1 0 g mL。用于测定发样、茶叶、面粉中的痕量铁 ,与电感耦合等离子体原子发射光谱法 (ICP AES)对照 ,结果满意。 相似文献
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2-磺酸基-4-甲氧基苯基重氮氨基偶氮苯(MOSDAA)和Cu(II)反应生成疏水性络合物后,被萃取到Triton X-114非离子表面活性剂胶束相中,火焰原子吸收光谱法测定其中的铜,建立了浊点萃取预富集-火焰原子吸收光谱法测定铜的方法。反应体系的pH、MOSDAA和Triton X-114的浓度、平衡温度及时间等实验条件被优化。在选择的实验条件下,方法的检出限为1.1 ng/mL(3σ),对浓度为0.1μg/mL的Cu(II)溶液平行测定6次,相对标准偏差为1.9%。方法已用于小米和水样中痕量铜的测定。 相似文献
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