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1.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
2.
结构静动力屈曲问题研究进展 总被引:19,自引:0,他引:19
近几十年来,结构的静动力屈曲问题一直是力学工作者极为关注的一个前沿课题.本文总结和综述了这一研究领域的几个基本问题:屈曲问题的分类、动态屈曲问题的特点及其特征量;介绍了屈曲问题的处理方法和目前已取得的成果;总结评述了人们关心的热点问题;屈曲问题的模型分析和实验技术、动态屈曲判别准则. 相似文献
3.
ZHAO JinYu LI JiaHuang ZHANG Zheng ZHANG ShuYi QU Min FANG JianWen HUA ZiChun 《中国科学:物理学 力学 天文学(英文版)》2013,(7):1301-1309
The enthalpy and conformational volume changes in the photolyses of carboxy-hemoglobin (HbCO) of human, bovine, pig, horse and rabbit are investigated by photoacoustic calorimetry. Considering the time scales of the exciting laser pulse and the receiving ultrasound transducers (PVDF films and PZT ceramics), as well as the reaction lifetimes in the photolysis processes of HbCO, the measured results are related to the geminate recombination and tertiary relaxation in photolyses of HbCO. Moreover, the quantum yields of the five mammals are also measured by laser pump-probe technique. The results show that the dynamic parameters, such as enthalpy and conformational volume changes, differ between the processes of the geminate recombination and tertiary relaxation. Also, the dynamic parameters differ among the five mammals although some of them may be consistent with each other. 相似文献
4.
We create a GaN photocathode based on graded Alx Ga1-x N buffer layers to overcome the influence of buffer-emission layer interface on the photoemission of transmission-mode GaN photocathodes.A gateshaped spectral response with a 260-nm starting wavelength and a 375-nm cut-off wavelength is obtained.Average quantum efficiency is 15% and short wavelength responses are almost equivalent to long wavelength ones.The fitted interface recombination velocity is 5×104 cm/s,with negligible magnitude,proving that the design of the graded buffer layers is efficient in obtaining good interface quality between the buffer and the emission layer. 相似文献
5.
吴斌 《数学物理学报(B辑英文版)》2011,31(3):960-968
In this paper, we consider a degenerate steady-state drift-diffusion model for semiconductors. The pressure function used in this paper is ()(s) = s~α(α > 1). We present existence results for general nonlinear diffhsivities for the degenerate Dirichlet-Neumann mixed boundary value problem. 相似文献
6.
7.
In the framework of the relativistic mean field theory, the effects of the δ meson on the direct Urca (DURCA) processes are investigated. In a neutron star, the DURCA processes involving nucleons, Λ and Ξ- can take place while the process involving the Ξ0 can not. With the inclusion of the δ meson, the threshold densities for the DURCA processes become lower. With the δ included, the threshold neutron star mass for the DURCA process among nucleons and electrons becomes smaller while the threshold masses for the processes involving hyperons become larger. When the δ meson is included, the total neutrino emissivity remarkably increases in the density range of 0.32--0.41 fm-3. The total neutrino luminosity increases with the neutron star mass first and then decreases. The neutrino luminosity gets larger with the inclusion of the δ meson. The cooling of the EXO0748-676 is sensitive to the isovector scalar interaction. 相似文献
8.
Ruifang Yang Nanjing Zhao Xue Xiao Shaohui Yu Jianguo Liu Wenqing Liu 《Journal of Chemometrics》2015,29(8):442-447
Sparse non‐negative matrix factorization on right side factor (SNMF/R) has better performance in feature extraction than non‐negative matrix factorization. In this work, SNMF/R was first used to separate the overlapped three‐dimensional fluorescence spectra of polycyclic aromatic hydrocarbons mixtures in pure water, lake water, and river water, respectively. It is found that the similarity coefficients between the acquired three‐dimensional spectra and the corresponding reference spectra with random initials are all above 0.80; the recognition rate of SNMF/R is higher than that of PARAFAC and non‐negative matrix factorization algorithms, especially in the case of lake water and river water samples. In addition, SNMF/R does not need any initialization scheme designing during spectra separation. These results demonstrate that SNMF/R is an appropriate algorithm to separate the overlapped fluorescence spectra of polycyclic aromatic hydrocarbons in aquatic environment accurately and effectively. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
9.
Hafnium(Ⅳ) bis(perfluorooctanesulfonyl)imide complex is found to be an efficient catalyst for the multicomponent condensation ofβ-naphthol,aromatic aldehydes and urea or amides in perfluorodecalin to afford the corresponding substituted amidomethyl naphthols in good yields.The remarkable features of this new procedure are high yields,shorter reaction times, reusability of catalyst and simple work-up procedures. 相似文献
10.
Yu Ming Dong Guang Li Wang Ping Ping Jiang Ai Min Zhang Lin Yue Xiao Ming Zhang 《中国化学快报》2011,22(2):209-212
ZnO particles about 200 nm were prepared through a facile hydrothermal method.Compared with single ozonation,the degradation efficiency of phenol increased about 23.7%and the degradation efficiency of intermediates improved about four times in the presence of ZnO at 298 K.In addition,the catalyst had good stability in the ozonation process.The influence of temperature was investigated and it was found that the better catalysis efficiency could be obtained at lower temperature. 相似文献