酸性介质中Pt-Ir-SnO2/C电催化氧化乙醇

采用改良的B(o)nnemann法合成了一系列新型炭载Pt-Ir-SnO2催化剂.电化学结果表明,在室温下新型电催化剂Pt-Iro.07-SnO2/C可有效断裂乙醇中C-C键,促进乙醇在低电位下完全氧化,其CO2生成量为Pt/C催化剂的2倍.另外,该三元催化剂显著增强乙醇的氧化反应,在室温下其电流密度为Pt/C的3倍.     

离子导体在离子输运状态下的物理特性

1974年杨桢等发现α-LiIO_3单晶在直流电场作用下,中子衍射强度显著增强现象后,引起了中国物理学家们的强烈兴趣。特别是中国科学院物理研究所的物理学家们研究了离子导体在静电场作用下的介电行为,X射线形貌图,光衍射,喇曼散射,超声衰减等等,观察到了许多新现象,并对这些现象的机制作了理论解释,本文将对这些实验和理论结果作一评述。     

一种新型多吡啶钌配合物的合成及其太阳光谱响应特性

以二茂铁和2-吡啶甲酰胺为原料,经偶联、氧化、溴乙酰化及环合反应制备了一种新型的二茂铁噻唑衍生物4-二茂铁-2-(2-吡啶)基噻唑(2-FPT);以2-FPT为第一配体,2,2'-联吡啶-4,4'-二甲酸(dcbpy)为第二配体,与二异苯丙基氯化钌进行配位,合成了一种新型的光敏化染料Ru(dcbpy)2(2-FPT)(...     

Synchronization in multilayer networks through different coupling mechanisms

In recent years, most studies of complex networks have focused on a single network and ignored the interaction of multiple networks, much less the coupling mechanisms between multiplex networks. In this paper we investigate synchronization phenomena in multilayer networks with nonidentical topological structures based on three specific coupling mechanisms:assortative, disassortative, and anti-assortative couplings. We find rich and complex synchronous dynamic phenomena in coupled networks. We also study the behavior of effective frequencies for layers I and II to understand the underlying microscopic dynamics occurring under the three different coupling mechanisms. In particular, the coupling mechanisms proposed here have strong robustness and effectiveness and can produce abundant synchronization phenomena in coupled networks.     

Tunable multi-wavelength microwave photonic filter based on the superposition of transfer functions

A microwave photonic filter （MPF） with reconfigurability and tunability resulting from the superposition of the transfer functions is proposed. Based on the Vernier effect between the optical frequency combs and the periodic optical filters, each comb line can be mapped into a sub-filter in the electronic field. The sub-filters are superposed to obtain the total transfer function of the MPF. By manipulating a few comb lines, we can reconfigure the passband shape, tune the bandwidth, and adjust the center frequency independently. Experiments verify that the bandwidth can be tuned from 224.8 to 674.3 MHz, and that the center frequency ranges from 1 to 4 CHz.     

等截面引射器启动性能数值研究

采用雷诺平均方程和SST k-ω湍流模型,空间离散采用二阶精度的Roe FDS方法,限制器采用Min-Mod方法,时间迭代采用隐式方法,研究了等截面引射器长度、引射器与喷管的间隙对其启动性能的影响。结果表明:等截面引射器存在启动、临界、不启动三种状态;在引射器长度一定的情况下,引射器与喷管之间的间隙越小,引射器的启动压比越小;在引射器与喷管之间间隙一定的情况下,对于本文所计算的工况,当引射器长度小于3m时,引射器所需的启动压比会很大,当引射器长度小于2m,则引射器很难启动;当引射器长度超过7m时,会对引射器的加工、安装、冷却带来诸多不利影响。     

Depolarization and Electrical Response of Porous PZT 95/5 Ferroelectric Ceramics under Shock Wave Compression

The release of bound charges by shock wave loading of poled lead zirconate titanate （PZT 95/5） ferroelectric ceramics can result in a high-power electrical energy output. In this study, a theoretical formulation describing the depolarization and electrical response of porous PZT 95/5 ceramics in the normal mode to shock wave compression loading perpendicular to the polarization direction is developed. The depoling process in porous poled PZT 95/5 ceramics is analyzed by using a parallel circuit consisting of a current source, capacitance, conductance and a circuit load. This modeling takes the effects of porosity on wave velocity and remanent polarization and dielectric constant into account, and the effects of variations in dielectric constant and conductivity in the shocked region are assessed. The output current characteristics of porous PZT 95/5 ceramics under short-circuit and resistive load conditions are analyzed and compared with the experiment, with the results showing that theoretical predictions taking into consideration the porosity of ferroelectric ceramics are in close agreement with the experimentally measured electrical response of porous PZT 95/5 under shock wave compression loading.     

基于三维光谱角统计的光谱图像信息提取方法

提出了一种新的基于三维光谱角统计的光谱图像信息提取方法。通过对影像上横向、竖向和对角方向相邻像元间采用光谱角计算相似度,构成一个三维的信息统计模型。该模型反映了相邻像元间所代表物质的相似度,通过在统计模型中设置不同的阈值和提取不同轴向的切片,可以从影像中提取代表同种物质的均匀区域和边缘信息,用于监督分类中训练样本的采集。该统计方法与直方图、散点图等传统统计工具相比,鲁棒性和可靠性更高,提取的信息更丰富。