碱土金属对锆基钙钛矿材料负载钌催化剂氨合成性能的影响

采用柠檬酸络合法制备了含Ca,Sr和Ba的锆基钙钛矿材料,负载Ru后用于催化氨合成反应;研究了碱土金属对催化剂织构性能和载体材料表面碱性的影响,并与催化剂活性相关联.同时,采用程序升温脱附技术对催化剂表面H2脱附性能进行了表征.结果显示,碱土金属对催化剂活性的促进顺序为Ba>Sr>Ca.研究发现,不同锆基碱土金属钙钛矿材料表面均具有较强的碱性位,碱土金属的加入影响了载体碱性强度以及金属-载体的相互作用,其中BaZrO3可有效抑制H2的吸附.因此,Ru/BaZrO3催化剂表现出优异的氨合成活性.     

具有重叠多非线性项的一般Lurie系统的绝对稳定性

本文研究了具有重叠多非线性项的一般Lurie直接系统的绝对稳定问题. 利用关于某个变元绝对稳定的概念, 获得了绝对稳定的充要条件和一些充分条件, 推广了现有的一些研究结果.     

基于矩阵环上求根问题的数字签名算法

考虑定义在模数N的剩余类环上的矩阵所构成的矩阵环上的求根问题的困难性,本文设计了一个数字签名算法,证明了攻击者能够成功伪造一个签名当且仅当攻击者能够求解矩阵环上的求根问题.对矩阵环上的求根问题的困难性进行了分析,在一种特殊情况下,证明了矩阵环上的求根问题与整数分解问题是等价的.分析表明,该数字签名算法是一个高效安全的签名算法.     

弹性地基梁理论在锚索抗滑桩计算中的应用


针对目前锚索抗滑桩的内力计算通常未考虑滑面以上桩身与岩土体的相互作用关系,而将滑面以上桩身按一般静力结构或有限次超静定结构计算的现状。本文根据弹性地基梁理论,考虑锚索与桩的变形协调,将初参数法运用到锚索抗滑桩的计算中,通过选取合理的初参数作为未知量,得到了锚索拉力以及桩身内力的计算过程。并结合皖南地区某处产生滑移弯曲变形的顺层滑坡治理工程进行了分析,与传统方法计算结果相比,本方法所得内力值较大,偏于安全,桩身内力分布规律与传统方法所得结果较吻合。

)     

动态超高压微射流对卵清蛋白微观结构的影响

采用圆二色谱(CD)、X射线衍射(XRD)、ANS荧光探针和紫外(UV)光谱研究了动态超高压微射流对卵清蛋白微观结构的影响。结果表明：卵清蛋白的微观结构的变化与处理压力有关,CD显示不同压力处理的卵清蛋白二级结构中的α-螺旋,β-折叠,β-转角和无规卷曲之间发生相互转化,二级结构的有序性提高;X射线衍射图谱直观显示不同压力处理的卵清蛋白晶体结构增加,160 MPa处理下结晶区最大,说明蛋白结构的有序性提高,与CD分析结果相似;ANS荧光探针光谱显示卵清蛋白的表面疏水性随着处理压力的增大而提高,120 MPa处理下达到最大;紫外光谱显示随着处理压力的增大,卵清蛋白最大紫外吸光值下降,卵清蛋白分子表面的具有紫外吸收的芳香氨基酸残基被包埋于分子内部,卵清蛋白的三维结构发生改变。     

Perturbation solution to unsteady flow in a porous channel with expanding or contracting walls in the presence of a transverse magnetic field

An incompressible flow in a porous channel with expanding or contacting walls in the presence of a transverse magnetic field is considered. Using similarity transformations, the governing equations are reduced to the nonlinear ordinary differential equations. The exact similar solutions for the different cases of the expansion ratio and the Hartmann number are obtained with a singular perturbation method, and the associated behavior is discussed in detail.     

Evolutionary prisoner’s dilemma on Newman-Watts social networks with an asymmetric payoff distribution mechanism

In this paper, we introduce an asymmetric payoff distribution mechanism into the evolutionary prisoner's dilemma game (PDG) on Newman--Watts social networks, and study its effects on the evolution of cooperation. The asymmetric payoff distribution mechanism can be adjusted by the parameter α: if α>0, the rich will exploit the poor to get richer; if α<0, the rich are forced to offer part of their income to the poor. Numerical results show that the cooperator frequency monotonously increases with α and is remarkably promoted when α>0. The effects of updating order and self-interaction are also investigated. The co-action of random updating and self-interaction can induce the highest cooperation level. Moreover, we employ the Gini coefficient to investigate the effect of asymmetric payoff distribution on the the system's wealth distribution. This work may be helpful for understanding cooperative behaviour and wealth inequality in society.     

基于非偏振光照明的水下偏振成像目标增强技术

分析水中粒子对光的吸收及后向散射造成的图像退化的物理模型,提出一种基于非偏振光照明的水下偏振成像目标增强技术。该技术的优势在于非偏振光照明确保了目标反射光与杂散光始终存在偏振态差异;采用偏振角特征参量确保了杂散光光强估算的精确性。与基于线偏振光照明的水下偏振成像技术相比,其适用范围更广,图像恢复精度更高。实验结果表明,该方法能够提高水下图像的能见度与对比度,对比度至少提升100%,适用于不同材质目标、不同成像距离以及不同杂质、不同浑浊程度的水体环境,在水下成像领域具有潜在应用价值。     

Energetics of He and H Atoms in W–Ta Alloys: First-Principle Calculations

Properties of various defects of He and H atoms in W-Ta alloys are investigated based on density functional theory. The tetrahedral interstitial site is the most configured site for self-interstitial He and H in W and W-Ta alloys. Only a single He atom favors a substitutional site in the presence of a nearby vacancy. However, in the coexistence of He and H atoms in the presence of the vacancy, the single H atom favors the tetrahedral interstitial site(TIS) closest to the vacancy, and the He atom takes the vacancy center. The addition of Ta can reduce the formation energy of TIS He or H defects. The substituted Ta affects the charge density distribution in the vicinity of the He atom and decreases the valence electron density of the H atoms. A strong hybridization of the H s states and the nearest W d state s exists in W_(53)He_1 H_1 structure. The sequence of the He p projected DOS at the Fermi energy level is in agreement with the order of the formation energy of the He-H pair in the systems.     

波前编码显微物镜景深扩展的研究

为了解决传统显微物镜景深与分辨率的矛盾,采用波前编码的方法,设计研究了波前编码的10倍显微物镜,结合传统光学设计软件,采用基于MTF一致性的相位板参数的优化方法,实现了在像面附近一定范围内系统的点扩散函数一致性;此外,还设计了扩展三次相位编码板的10倍显微物镜,比较了采用两种不同相位板系统的焦深扩展的效果,结果显示三次相位板的焦深扩展效果较好,可以将传统10倍显微物镜的焦深扩展15倍。成像模拟仿真结果显示滤波后的编码像在±15倍焦深范围内成像清晰,从而扩大了系统的景深。