用计算机模拟平抛物体运动的实验规律

用计算机辅助课堂教学,具有形象、直观的效果,它能准确地模拟物理现象,弥补有些物理实验不易观察的缺陷,帮助学生理解有关概念,达到提高教学质量的目的。 用计算机程序设计的语言种类较多,本人在教学实践中,找到了一种方便、易学的编程方法,即在FOXBASE 关系数据库系统中调     

抗体催化的氨酰化反应

酰基转移反应在许多生物学或化学过程中都起着十分重要的作用。氨酰tRNA合成酶在蛋白质生物合成中起关键作用。它催化tRNA的终端腺苷上2′,3′-二醇的酯化反应。伯克利化学系的Schultz小组最近提出这样一个问题,能否产生催化这类反应的抗体。这样的抗体也许会加速tRNA与新氨基酸的氨酰化,可用于蛋白质的生物合成研究。他们发现,针对磷酸二酯过渡态类似物产生的一种     

石墨炉原子吸收法测定掺质钆镓石榴石中钴、铬、镍

用石墨炉原子吸收法测定掺质钆镓石榴石单晶中钴、铬、镍的含量,晶体中的钆不影响测定,但镓呈现背景干扰,文中对此进行了讨论。用氘灯扣除背景。钴、铬、镍含量为0.015%、0.037%、0.0057%时,变动系数分别为1.4%、1.9%、2.7%,检出限分别为2.5μg/g、0.87μg/g、2.0μg/g。     

用LCAC—SW法计算H＋H2（0）→H2＋H一维共线反应几率

用排列通道线性组合散射波方法计算了一维共线反应Ｈ＋Ｈ２（０）→Ｈ２＋ＪＨ的反应几率。在采用较小基组的情况下，得到了与精确量子计算数值相吻合的结果。     

Application of transcutaneous diffuse reflectance spectroscopy in the measurement of blood glucose concentration

In this paper, the propagation characteristics of near-infrared (NIR) light in the palm tissue are analyzed, and the principle and feasibility of using transcutaneous diffuse reflectance spectroscopy for non-invasive blood glucose detection are presented. An optical probe suitable for measuring the diffuse reflectance spectrum of human palm and a non-invasive blood glucose detection system using NIR spectroscopy are designed. Based on this system, oral glucose tolerance tests are performed to measure the blood glucose concentrations of two young healthy volunteers. The partial least square calibration model is then constructed by all individual experimental data. The final result shows that correlation coefficients of the two experiments between the predicted blood glucose concentrations and the reference blood glucose concentrations are 0.9870 and 0.9854, respectively. The root mean square errors of prediction of full cross validation are 0.54 and 0.52 mmol/1, respectively.     

从月桂烯出发合成新铃兰醛

综述了从月桂烯出发合成新铃兰醛的不同合成方法。     

L-丙氨酰-L-谷氨酰胺的合成反应研究

以L-乳酸乙酯和L-谷氨酰胺为原料,通过L-乳酸乙酯氯化、水解、酰化得到D-2-氯-丙酰基氯,再将D-2-氯-丙酰基氯与4-谷氨酰胺缩合后氨解,得到目标化合物,总收率43%,纯度(HPLC)大于98%。缩合反应的溶剂甲苯不需要脱水处理。重点讨论了中间体D-2-氯-丙酸的合成。     

Different Kinds of Discrete Breathers in Three Types of One-Dimensional Models

The dynamics of different kinds of discrete breathers in three types of one-dimensionai monatomic chains with on-site and inter-site potentiais are investigated. The existence and evolution of symmetric breather, antisymmetric breather, and multibreather in one-dimensionai models are proved by using rotating wave approximation, local anharmonic approximation, and the numerical method. The linear stability of these breathers is investigated by using Lyapunov stable anaiysis. The localization and stability of breathers in three types of models correlate closely to the system nonlinear parameter β.     

钠蒸气中受激电子喇曼散射

本文报道了钠原子3S-4S跃迁的受激电子喇曼散射的首次观测。获得了2.38μm～2.65μm的可调谐红外输出;计算了受激电子喇曼散射的功率增益系数并测量了红外输出随染料激光频率调谐的变化,其结果符合较好;给出了泵浦功率阈值随钠蒸气压变化的实验曲线;测得光子转换效率约为30％。在此同时,观测到了钠原子4S-3P跃迁的放大自发辐射。     

方波极谱同时测定血清中的微量元素铜、铅、镉、锌(一) `

血清及血浆中铜、铅、镉和锌的分别测定用极谱方法的报道颇多.同时测定两种以上元素的有Copeland,R.etc.在1.7M HOAC+1.25M KOAC中用脉冲极谱测定全血和血浆中的铅、镉;Sinko,I.及Gomiscek,S.在0.2M NaOAC(pH6.4)中用阳极溶出法同时测定了铜、铅、镉、锌、铊、铋六种元素,每毫升血清中金属离子的检出限量为0.01微克,分析时间为6小时;Copeland,T.R.及Shogerboe,R.K.也用阳极溶出法测定血中的痕量元素,铜、铅、镉、锌的灵敏度可达10~(-11)克/毫升.至今用方波极谱同时测定血清中四种离子尚未见报道.我们研究了不经过富集用方波极谱同时测定血清中的铜、铅、镉、锌,提供一种测定血清中痕量元素的方法.