Electrochemiluminescence from tris(2,2′-bipyridyl) ruthenium (Ⅱ) in the presence of aminocarboxylic acid co-reactants

Due to the highly sensitive electrochemiluminescence (ECL), tris(2,2′-bipyridyl) ruthenium(II) (Ru(bpy)32+) is often used in the field of bioarrays with the help of co-reactants. However, the generally used co-reactant, tripropylamine (TPA), is toxic, corrosive and volatile. Therefore, the search for safe, sensitive and economical co-reactants is critical. Herein, three aminocarboxylic acids, ethylenediamine-tetraacetic acid (EDTA), nitrilotriacetic acid (NTA), and 2-hydroxyethylethylene diaminetriacetic ac...     

Separation/enrichment of the low-content high molecular weight natural protein using protein-imprinted polymers with ARPCs

We introduce a new method for separation/enrichment of the low-content cellular protein in high mo-lecular weight on the basis of molecular imprinting. The template protein, bacterial cloned immu-noglobulin binding protein (BiP), was selectively assembled with assistant recognition polymer chains (ARPCs) from their library, which consists of numerous limited length polymer chains with randomly distributed recognition and immobilizing sites. The assemblies of proteins and ARPCs were adsorbed by porous polyme...     

The cage effect on assembly of cyclic-bis-(zinc porphyrin) with 5,15-dipyridylporphyrin

An inclusion complex of cyclic bis(zinc porphyrin) 1 with 5,15-dipyridylporphyrin derivative 3 has been designed and constructed. The complex formation is induced by Zn-N coordination, and is robust (Kassoc ~ 106 L/mol) due to the presence of the cage effect of cyclic bis(zinc porphyrin). The cage-like complex as an entity is stable enough, and also convenient to achieve relative movement between the bis(zinc porphyrin) host and the dipyridylporphyrin guest connected by Zn-N coordination. The characteristic...     

羧甲基葡聚糖磁性纳米微球的制备及表征

采用超声预处理技术,在羧甲基葡聚糖-水分散体系中,通过化学共沉淀法制备羧甲基葡聚糖磁性复合微球．采用IR,TEM,AFM,XRD和振动样品磁强计方法对产物进行了表征．实验结果表明：超声预处理方法能明显提高复合微球的分散性．制得的复合微球呈球形,分散均匀,平均粒径为100nm．它们具有超顺磁性,室温下磁性饱和磁化强度为35emu·g^-1．     

3D Multiphase Piecewise Constant Level Set Method Based on Graph Cut Minimization

Segmentation of three-dimensional (3D) complicated structures is of great importance for many real applications. In this work we combine graph cut minimization method with a variant of the level set idea for 3D segmentation based on the Mumford-Shah model. Compared with the traditional approach for solving the Euler-Lagrange equation we do not need to solve any partial differential equations. Instead, the minimum cut on a special designed graph need to be computed. The method is tested on data with complicated structures. It is rather stable with respect to initial value and the algorithm is nearly parameter free. Experiments show that it can solve large problems much faster than traditional approaches.     

Abel分部求和法与基本超几何级数变换

利用修正的Abel分部求和引理,系统研究基本超几何级数的部分和,建立一些关于列平衡、二次、三次以及四次基本超几何级数的变换公式和求和公式．     

模糊值二人零和对策的Nash均衡策略

我们将在Ramik定义的模糊最大序关系基础上研究模糊环境中的二人零和对策。在非对称模糊数基础上,引入模糊环境中的几种Nash均衡策略,讨论各种均衡策略存在的充要条件。并引入含参变量确定性矩阵对策及其均衡策略的概念,讨论含参变量确定性矩阵对策的Nash均衡策略和模糊值矩阵对策的均衡策略的关系。     

LIMIT CYCLES OF SOME Z_3-EQUIVARIANT NEAR-HAMILTONIAN SYSTEMS OF DEGREES 3 AND 4

This paper studies the number of limit cycles of some Z3-equivariant near-Hamiltonian systems of degrees 3 and 4,which are a perturbation of a cubic Hamiltonian system. By the Melnikov function method,we obtain 5 and 6 limit cycles respectively.     

求解不等式命题的另类方法

关于由两个不等号连接的不等式求解、证明以及与不等式有关的这类命题,都有一个共同的特征,那就是要思考和分析连接不等号的三个式子的大小关系．如果三个式子的大小关系形如a≤f（x）≤6,那么三个式子a、f（x）、b所对应的值就可看作数轴上的三个点,其中有两个定点（对应a、b）和一个动点（对应f（x））,当我们把这两个定点作为线段的端点,把这个动点作为线段的分点时     

农民收入增长波动关系预测分析:基于小波变换

新农村建设背景下,保持农民收入快速、稳定增长对于构建社会主义和谐社会、不断缩小城乡差距具有重要的战略意义。本文运用小波变换(WT)对1976-2006年间农民收入的波动关系进行预测分析,实证检验结果显示:全国农民人均纯收入增长具有7年和40年左右的特征时间尺度,与农民人均纯收入变化存在着7年和40年两个主要周期振荡保持一致。两个特征时间尺度叠加,可以预见在未来的数年内,全国农民人均纯收入将呈现绝对值快速增长、增长率在波动中有所放缓的特征。最后,文章就如何保持农民收入稳定增长提出了点简短的对策建议。