13-cis-异维A酸衍生物的合成、表征及抗癌活性研究

以六甲基磷酰胺为溶剂,在室温条件下将异维A酸合成为尚未见文献报道的异维A酸衍生物(4a～4g),其结构经^1H NMR,^13C NMR和MS表征。着重考察了4g的生物活性,结果表明该4g对肝癌细胞,舌癌细胞等具有抗癌活性。     

k-means-RBF集成神经网络在工业尾气检测中的应用

神经网络是工业尾气检测系统的一个重要组成部分. 为提高神经网络的预测精度和收敛速度, 建立k-means-RBF集成神经网络模型. 首先, 通过选取不同的径向基函数神经网络参数, 得到一组RBF神经网络; 然后, 利用k-means算法对生成的RBF神经网络进行聚类, 并筛选出各类中精度较高的神经网络; 最后, 通过简单平均法对筛选出的神经网络进行集成, 得到高性能的k-means-RBF集成神经网络模型. 为验证模型有效性, 搭建基于k-means-RBF集成神经网络模型的工业尾气检测系统进行验证. 结果表明, 与粒子群算法优化后的Back Propagation (PSO-BP)神经网络模型相比, k-means-RBF集成神经网络模型的平均预测精度提高78.27%, 收敛时间节省99.65%     

高稳定性低噪声的561 nm黄光激光器

鉴于目前561 nm激光器噪声较大,影响其实用性,提出一种高稳定性低噪声的561 nm黄光激光器。利用Nd:YAG晶体得到1 123 nm基频光,通过LBO晶体腔内倍频得到561 nm输出。理论分析了1 112 nm、1 116 nm与1 123 nm波长的阈值泵浦功率,提出1 123 nm的单波长振荡条件,确定谐振腔镀膜要求。根据理论计算,设计了合理的谐振腔膜系,通过抑制1 112 nm与1 116 nm谱线在谐振腔内的振荡实现1 123 nm谱线的单波长振荡。在泵浦功率为5 W时,实现了561 nm激光单波长输出,输出功率达到107 mW,功率不稳定性达到0.7%,噪声为1.2%。     

氧化石墨烯功能化后含水甲基蓝中隐藏的驰豫通道

The mixture of graphene oxide (GO) and dye molecules may provide some new applications due to unique electronic, optical, and structural properties. Methylene blue (MB), a typical anionic dye, can attach on GO via π-π stacking and electrostatic interaction, and the molecule removal process on GO has been observed. However, it remains unclear about the ultrafast carrier dynamics and the internal energy transfer pathways of the system which is composed of GO and MB. We have employed ultrafast optical pump-probe spectroscopy to investigate the excited dynamics of the GO-MB system dispersed in water by exciting the samples at 400 nm pump pulse. The pristine MB and GO dynamics are also analyzed in t_andem for a direct comparison. Utilizing the global analysis to fit the measured signal via a sequential model, five lifetimes are acquired:(0.61±0.01) ps, (3.52±0.04) ps, (14.1±0.3) ps, (84±2) ps, and (3.66±0.08) ns. The ultrafast dynamics corresponding to these lifetimes was analyzed and the new relaxation processes were found in the GO-MB system, compared with the pristine MB. The results reveal that the functionalization of GO can alter the known decay pathways of MB via the energy transfer from GO to MB in system, the increased intermediate state, and the promoted energy transfer from triplet state MB to ground state oxygen molecules dissolved in aqueous sample.     

Proof of the insecurity of quantum secret sharing based on the Smolin bound entangled states

This paper reconsiders carefully the possibility of using the Smolin bound entangled states as the carrier for sharing quantum secret. It finds that the process of quantum secret sharing based on Smolin states has insecurity though the Smolin state was reported to violate maximally the two-setting Bell-inequality. The general proof is given.     

基于斜面的摩擦力显微镜探针扭转系数标定改进方法

基于标准样品的已知斜面,对摩擦力显微镜探针扭转系数标定方法进行改进.根据探针在斜面上滑动时的受力特点,测试不同载荷下斜面上摩擦力环电压信号的半高量和偏移量,求解摩擦系数并最后得出探针扭转系数.结果表明:斜面摩擦力信号的半高量和偏移量随着载荷的增大而增加,且在较高载荷下呈线性增长;在此前提下黏着力不影响摩擦系数和扭转系数的求解;平面验证试验所得摩擦系数与上述求解值基本一致.相关结果有望简化纳米尺度摩擦力的标定和测试.     

Delay Effect on Coherent Transfer of Optical Frequency Based on a Triple-Pass Scheme

We demonstrate a triple-pass scheme for coherent transfer of optical frequency and the delay effect on the fiber phase noise compensation. It is theoretically proved that the delay effect consists of both fiber delay and servo delay. The delay effect confines the servo bandwidth within 1/8 and induces a residual fiber phase noise after noise compensation. For a 25-km-long fiber, the servo bandwidth is found to be around 1 k Hz, and the fiber phase noise is suppressed approaching to the theoretical limitation. The triple-pass scheme enables the simultaneous transfer of optical frequency to multiple remote users. The performance of noise compensator in the triple-pass scheme can achieve a similar level result compared with that in the double-pass scheme.     

高性能反谐振空芯光纤导光机理与实验制作研究进展

传统实芯光纤无法克服材料本身固有的非线性、色散、瑞利散射、光照损伤等缺陷,微结构空芯光纤有望解决这些本征性问题,可以为高功率激光、非线性光学、生物光子学、量子光学、光纤传感、光通信等应用提供一个理想而方便的媒介.在技术实现的道路上存在着光子禁带空芯光纤和反谐振空芯光纤两种选项.后者具有宽带导光和高激光损伤阈值等优点,但是一直受困于较高的传输损耗.这一情况随着最近几年人们对反谐振导光机理和光纤制作技术研究的快速推进正在逐渐发生转变.本文回顾了我们团队五年来开展的系统性的理论和实验工作,介绍了一套直观的可定量计算的反谐振导光机制理论,展示了最新研制的高性能光纤.通过合理利用光纤结构中的局域性和全局性特征,突破了半解析计算反谐振空芯光纤限制损耗的难题;通过对光纤拉制条件的精密控制,制作出了紫外到中红外波段的各型光纤;并对进一步提高光纤性能和在此基础上的更丰富的光学应用研究进行了展望.     

U型加劲板稳定极限承载力影响因素分析

为研究U型加劲板稳定极限承载能力受初始几何缺陷、焊接残余应力以及荷载偏心距等因素的影响, 采用考虑几何与材料双重非线性的有限元模拟方法, 对各影响因素进行参数分析. 结果表明, U型加劲板的稳定极限承载能力受初始几何缺陷的影响明显, 而焊接残余应力对其影响较初始几何缺陷更为显著; 荷载偏心距对加劲板极限承载力影响明显, 极限承载力随偏心距的增加逐渐降低, 且偏向U肋一侧时的降低幅度更大.     

热滚压成型工艺参数对微流道回复率的影响

为研究热滚压成型工艺参数对微流道成型弹性回复的影响, 基于Maxwell模型建立了微流道截面弹性回复率与各工艺参数之间函数关系的分析模型, 并利用非线性有限元仿真软件ABAQUS对PMMA、PVC、PC非结晶材料的热成型进行有限元模拟, 系统分析了温度、预压紧量及滚动速度对弹性回复率的影响. 结果显示, 当增加温度和减小预压紧量、滚动速度时, 可以有效地减小微流道截面弹性回复率.