Self-assembly behaviour of amphiphilic diblock copolymer in selective solvents studied by synchrotron small-angle x-ray scattering

The aggregation behaviour of styrene-vinyl benzoic acid (PSm-b-PVBAn) amphiphilic diblock copolymers in selective solvents with different m and n was investigated by synchrotron small-angle x-ray scattering (SAXS). We have carried out a detailed analysis of scattering intensity, dimension, shape and microstructure of the diblock copolymers of narrow distribution in water, methanol, ethanol and isopropanol selective solvents, respectively. We have found that the aggregation behaviour of the copolymer depends on the nature of the solvent and the micelle forms fiat disc objects with the ratio of radius ω=0.4. The average radius gyration Rg of the copolymer decreases as solvents change from isopropanol to ethanol and to methanol, and increases with increasing pH in aqueous solution, but decreases with the addition of COCl2 in ethanol solvent. The scattering intensity of diblock copolymer micelle follows I(h) ∝ h^-α in different selective solutions, suggesting that the PSm-b-PVBAn coils have self-similar structure behaviour or a fractal structure in the selective solvents. All of these revealed that the aggregation behaviour of the diblock copolymer changes dramatically with experimental condition in the selective solvent. The increase of mass fractal dimension (Dm) from 2.12 to 2.47 indicates that the copolymer chain changes from a swollen coil to a rather compact disc in the course of changing solvents, decreasing surface fractal dimension (Ds) from 2.98 to 2.58 indicates that the copolymer micelle change from a rather rough surface to a smooth form in the course of increasing pH in aqueous solutions, and increasing Dm and Ds from 2.29 to 2.35 and 2.70 to 2.90, respectively, indicates the shrinkage of copolymer micelle to a rather compact and rough disc form by adding COCl2 in ethanol solvents.     

基于TMS320VC5416的计算装置设计

TMS320VC5416是TI公司生产的一款低功耗高性能：定点16位数字信号处理器，工作频率可达150MHz，具有很强的数字信号处理能力。采用基于TMS320VC5416的数字处理装置能够完成较复杂的数据采集、传输、处理和仿真通信功能。经过不断调试并改进，该计算装置在下面两方面取得初步成效。     

铜氧化物超导体的电子结构

本文主要很据光电子能谱和电子能量损失谱的实验结果，综述目前对铜氧化物超导体的铜原子的价态、强电子相关作用、反铁磁性、空穴导电及其对称性和费米面的性质等电子结构问题的认识．     

弱概周期微分方程的弱概周期解

本文利用微分方程的指数型三分性给出了弱概周期微分方程的弱概周期解的存在性定理,并讨论了弱概周期微分方程的一些性质,从而改进了文献[2—7]中的一些结果.     

用有限元法分析多波导耦合系统本征模的模式特性

本文应用有限元法(FEM),计算和分析了多波导耦合系统的本征模(超模)的模式特性及其变化规律,得到了强度均匀分布的基超模,克服了微扰理论计算这类问题的局限性.     

斜波导喇曼振荡器

 采用斜波导的喇曼氢气池, 使泵浦激光束在波导内部传播, 增大了受激喇曼散射的作用区域。在传播过程中光束截面逐渐被压缩, 补偿因波导内壁的反射损耗而引起的功率密度下降。在一定气压范围内提高了喇曼转换的效率, 并利用波导对激光束的均匀作用, 使输出的一阶斯托克斯光光强的均匀性获得改善。     

恶性肿瘤患者血清锌与淋巴细胞转化率及自然杀伤细胞活性变化…

观察了８６例恶性肿瘤患者血清锌与淋巴细胞转化及自然伤细胞活性间的变化。结果表明，肿瘤患者的血清锌较正常对照组明显降低，同时伴有淋巴细胞转化率ＮＫ细胞活性下降。表明缺锌是肿瘤患者免疫功能下降的原因之一。     

线阵CCD光积分时间的智能控制技术及其应用

本文提出了一种新型线阵ＣＣＤ驱动电路的设计方法，可以在不改变系统工作主频的情况下，连续地改变ＣＣＤ的光积分时间，并且可通过计算机接口实现智能调整，此项技术已成功应用于热扎线材外径的线检测仪中，控制效果极其理想。     

有损耗波导中非线性TE波的数值模拟

本文发展了一种以有限元技术为基础的数值方法,用它分析有损耗波导中的非线性TE模。在这种方法中,非线性有损耗波导中TE波与功率有关的复传播常数和局城电场分布,可从这种波导直接得到,没有任何近似。作为这种方法的应用,计算了非线性有损耗波导系统中TE0模的功率色散关系和电场分布。