光纤荧光法对吸附于红树叶片表面上荧蒽的测定

利用光纤荧光法实现了吸附于白骨壤(Am)、海漆(Ea)、秋茄(Kc)、桐花树(Ac)和老鼠簕(Ai)叶片表面上荧蒽(Fla)的定量测定.所建方法测定吸附于Am、Ea、Kc、Ac和Ai叶片表面上Fla的线性范围分别为2.5 ～500、2.0 ～600、4.5 ～1 100、15 ～600、3.5 ～450 ng/spot,相应的检出限分别为0.91、0.63、1.12、3.52、1.40 ng/spot,方法的相对标准偏差小于7.8%(n=15),加标回收率分别为97% ～108%、78% ～95%、77% ～90%、84% ～108%和78% ～102%.利用所建方法考察了5种红树叶片正反面吸附不同量Fla的信号强度随时间的变化情况.结果表明:在200 min内,叶片正反面上Fla的信号均发生不同程度的衰减,且反面的信号衰减率大于正面;5种红树叶片正反面对Fla的吸附特性均不同;吸附于叶片正面的Fla多残留在叶片表面,而吸附于叶片反面的Fla易向叶片内部迁移.     

Symmetry energy from neutron-rich fragments in heavy-ion collisions, and its dependence on incident energy, and impact parameters

The yields of fragments produced in the 60Ni+ 12C reactions at 80 A and 140 A MeV, and with maximum impact parameters of 1.5, 2 and 7.3 fm at 80 A MeV are calculated by the statistical abrasion-ablation model. The yields of fragments are analyzed by the isobaric yield ratio (IYR) method to extract the coefficient of symmetry energy to temperature (asym/T ). The incident energy is found to influence asym/T very little. It’s found that asym/T of fragments with the same neutron-excess I = N-Z increases when A increases, while asym/T of isobars decreases when A increases. The asym/T of prefragments is rather smaller than that of the final fragments, and the asym/T of fragments in small impact parameters is smaller than that of the larger impact parameters, which both indicate that asym/T decreases when the temperature increases. The choice of the reference IYRs is found to have influence on the extracted a sym /T of fragments, especially on the results of the more neutron-rich fragments. The surface-symmetry energy coefficient (bs/T ) and the volume-symmetry energy coefficient (bv/T) are also extracted, and the bs/bv is found to coincide with the theoretical results.     

荧光粉CaWO4：Eu3+中WO42-与Eu3+间的能量转递

通过高温固相法分别制备了CaWO₄和CaWO₄:1%Eu³⁺ 样品. 测量了样品不同温度(10–300 K)的荧光光谱、荧光衰减曲线和 时间分辨荧光光谱. 样品的荧光光谱表明: 在240 nm紫外光激发下, 两个样品在430 nm处都展现出来源于WO₄^2-的蓝色发射; 样品CaWO₄:Eu³⁺的Eu³⁺(⁵D₀→⁷F_{1, 2, 3,4})的特征发射则归属于WO₄^2-到Eu³⁺ 间的能量传递.由样品室温(300K)荧光衰减曲线发现: 纯CaWO₄的荧光寿命为8.85μs,Eu³⁺掺杂之后WO₄^2-的荧光寿命缩短至6.27μs,这从另一方面证明了WO₄^2-与Eu³⁺间能量传递的存在. 由荧光寿命得到T=300K时, CaWO₄: 1%Eu³⁺中WO₄^2-与Eu³⁺间的能量传递效率(η_ET)为29.2%, 能量传递速率(ω_ET)为4.65×10⁴ s^-1.通过时间分辨荧光光谱, 获得了从WO₄^2-到Eu³⁺之间的能量传递的时间演变过程,当温度由10 K增加到300 K时, 能量传递出现的时间单调变小. 测试了不同温度(10–300 K)对CaWO₄:Eu³⁺的荧光寿命的影响, 发现在10–50K时,Eu³⁺的荧光寿命增加, 但温度超过50K时发生猝灭, 荧光寿命开始下降; WO₄^2-的荧光寿命则是随着温度的升高逐渐缩短. 关键词： 能量传递 红色荧光粉 温度依赖 4：Eu³⁺')" href="#">CaWO₄：Eu³⁺     

求标准正交基的初等变换法

用初等变换法可求Euclid空间的标准正交基,且只需要进行较少次数的第三种类型的初等变换就能实现这一结果.     

单层正三角锯齿型石墨烯量子点的电子结构和磁性

采用基于密度泛函理论的广义梯度近似(GGA),对不同尺寸(N=2—11)的单层正三角锯齿型石墨烯量子点(Z_N -GNDs)的结构进行优化,得到与实验数据较好符合的晶格常数,进一步计算得到不同尺寸下体系的自旋多重度、磁矩、电子态密度以及自旋电子密度.结果表明:所有体系都呈现金属性,在尺寸较小的体系中量子尺寸效应对电子结构的影响比较明显;与单层石墨烯片一样,sp²杂化作用和非键态电子在量子点中仍起到非常重要的作用;费米能级上有自旋向上的电子分布,体系的 关键词： 石墨烯 量子点 电子结构 磁性     

迭代函数方程$G(x,f(x),\ldots,f^n(x))=F(x)$的$C^1$解

In this paper we consider the iterative equation G(x,f(x),...,f n(x)) = F(x) on R,and give the existence of C 1 solutions near the fixed point of F,which generalize some results on the leading coefficient problem from the form of the polynomial-like iterative equations to the general form.     

传导电子虚声子交换对热电势的影响

本文基于Anderson Hamiltonian，考虑电子——声子耦合效应，研究了传导电子之间虚声子交换所引起的电子间有效相互作用对杂质系统温热电势的影响。     

Some Remarks on One Type of Parabolic Monge-Ampère Equation

Inthepresentpaper,weinvestigatethefollowinginitial--boundaryvalueproblemforatypeofparabolicMonge-AmpereequationwhereQ=ax(0,TI,nisaboundedconvexdomaininR",aamistheHessianofthefunctionu,ovQdenotestheparabolicboundaryofQ.Recently,IvochkinaandLadyzhenskaya[1]consideredtheaboveproblem,andundersomestructureconditions,theyobtainedtheuniquesolvabilityofitinclassicalsense.Afterthat,WangRouhuaiandWangGuanglieimprovedtheresultsof[ifundersomeweakerconditionsandgetthatproblem(1),(2)hasauniquesolution…     

Time-bin-encoding-based remote states generation of nitrogen-vacancy centers through noisy channels

We design proposals to generate a remote Greenberger-Horne-Zeilinger(GHZ) state and a W state of nitrogenvacancy(NV) centers coupled to microtoroidal resonators(MTRs) through noisy channels by utilizing time-bin encoding processes and fast-optical-switch-based polarization rotation operations.The polarization and phase noise induced by noisy channels generally affect the time of state generation but not its success probability and fidelity.Besides,the above proposals can be generalized to n-qubit between two or among n remote nodes with success probability unity under ideal conditions.Furthennore,the proposals are robust for regular noise-changeable channels for the n-node case.This method is also useful in other remote quantum information processing tasks through noisy channels.     

基于二次电子发射的中性束剖面诊断系统设计

阐述了NBI系统长脉冲束中二次电子的发射原理,分析了束能量与靶表面温度对二次电子发射系数的影响,通过有限元分析模拟建立实际靶板模型进行初步模拟验证,并提出了基于二次电子数据反演的束功率密度剖面的处理方法,给出了束诊断系统的设计流程图,分析了系统各组成部分和系统整体运行方式,确定了基于二次电子发射束剖面诊断探针设计。