两个三维柔性功能化双苯并咪唑金属N-杂环卡宾的合成和结构

由1,1'-双苄基-3,3'-氧双(亚乙基-2,1)-二苯并咪唑六氟磷酸盐(L1)和1,1'-双(吡啶-2-甲基)-3,3'-氧双(亚乙基-2,1)-二苯并咪唑六氟磷酸盐(L2)为配体合成了[Hg(C₃₂H₂₈N₄O)](CH₃COO)(PF₆)₂(1)和[NiCl(C₃₀H₂₈N₆O)](PF₆)₂(2),并对其进行了结构表征。配合物1是一个罕见的三价态Hg配合物,为单斜晶系P2₁/c空间群,配合物2为单斜晶系P2₁/n的配合物。1和2中存在O-H…F,C-H…F,C-H…Cl,C-H…π,P-F…π氢键作用和π-π堆积作用,并以此分别形成了3D超分子结构。     

开拓创新 精益求精

<正>中国船舶重工集团公司第十二所标准物质研究室是国家冶金标准样品定点研制单位(证书号为:BKRK25-2009)和国家有色标准样品会员单位,拥有独特的金属材料标准物质均匀化制备技术优势,主要研制开发铸造金属材料光谱分析用标准物质和成分分析标准物质,广泛应用于兵器、航空、航天、船舶、冶金、机械等行业。北京、上海、沈阳、武汉、济南等全国各大城市均有代理销售单位。发展目标:成为中国金属材料标准物质制备基地及国防特种合金标准物质研究试验中心。     

A quasi-flow constitutive model with strain-rate dependence

In this paper, the proposed is a quasi-flow constitutive model with strain-rate sensitivity for elastic plastic large deformation. The model is based on the Quasi-flow Corner theory, and is suitable for the sheet metal forming process simulation with a variable punch machine velocity. Uniaxial tensile tests and deep-drawing tests of a circular blank with square punch are carried out and numerically simulated. The consistency between the experimental and the numerically simulated results shows the validity of the present new constitutive model. The project supported by the Scientific Foundation of National Outstanding Youth of China (10125208), the National Natural Science Foundation of China (19832020), and the National Education Committee of China     

无机类富勒烯过渡金属硫化物纳米材料的合成及其摩擦学应用研究进展

评述了无机类富勒烯（IF）与过渡金属硫化物（WS2和MoS2等）纳米材料的合成技术及其摩擦学应用研究的最新进展，外型为球形或近似于球形并具有嵌套中空结构的IF－WS2和IF－MoS2纳米果粒具有潜在的摩擦学应用前景；对含有IF－WS2纳米颗粒的复合材料和Ni-P复合镀层的研究表明，其比含有石墨和层状2H－WS2粉末的固体润滑剂具有更优异的摩擦学性能。     

The effects of relative density of metal foams on the stresses and deformation of beam under bending

The exact analytic solution of the pure bending beam of metallic foams is given. The effects of relative density of the material on stresses and deformation are revealed with the Triantafillou and Gibson constitutive law (TG model) taken as the analysis basis. Several examples for individual foams are discussed, showing the importance of compressibility of the cellular materials. One of the objects of this study is to generalize Hill’s solution for incompressible plasticity to the case of compressible plasticity, and a kinematics parameter is brought into the analysis so that the velocity field can be determined. The English text was polished by Yunming Chen.     

金属橡胶材料阻尼测试的一个新方法

金属橡胶材料是一种新型减振缓冲材料。本文提出了一个金属橡胶材料阻尼性能的测试方法。基于粘弹性阻尼耗能的基本原理,在给定应变激励函数的条件下,构造了一个等效应力响应函数,由滞环面积相等建立了一组包含实测应力响应和等效应力响应的等效耗能方程,将应变激励函数离散得到了损耗因子的计算表达式,由此可以通过实测应力方便地计算出损耗因子。该方法不仅便于对大阻尼材料的阻尼进行测试,而且具有精度高的优点。依据这一方法对金属橡胶材料进行了测试,测试结果表明我们开发的金属橡胶材料有很好的阻尼减振性能。     

Oblique Perforation of Thick Metallic Plates by Rigid Projectiles

Oblique perforation of thick metallic plates by rigid projectiles with various nose shapes is studied in this paper. Two perforation mechanisms, i.e., the hole enlargement for a sharp projectile nose and the plugging formation for a blunt projectile nose, are considered in the proposed analytical model. It is shown that the perforation of a thick plate is dominated by several non-dimensional numbers, i.e., the impact function, the geometry function of projectile, the non-dimensional thickness of target and the impact obliquity. Explicit formulae are obtained to predict the ballistic limit, residual velocity and directional change for the oblique perforation of thick metallic plates. The proposed model is able to predict the critical condition for the occurrence of ricochet. The proposed model is validated by comparing the predictions with other existing models and independent experimental data.The English text was polished by Keren Wang     

激光散斑干涉法测量金属复合引线热膨胀系数的实验研究

本文采用激光散斑干涉法测量微电子金属封装用金属复合引线的热膨胀系数。该方法有很高的测量精度和灵敏度,并对试件形状、尺寸和表面无特殊要求。同时利用光学方法全场测量的优点,使用已知热膨胀系数的金属材料作为标准试件,可减少温度场不均匀分布及微小变化对测试精度的影响,消除了测量光路几何参数导致的系统误差。在相对简单的实验设备下,得到较高精度金属复合引线的热膨胀系数值。该方法可广泛用于各种新材料的热膨胀系数的测定。     

从国际深空探测大赛看理论力学教学及力学竞赛

1 国际深空探测轨迹设计大赛简介 太阳系中存在很多小行星,它们有着丰富的稀有金属资源,同时,一些近地小行星对地球的安全存在潜在的威胁.     

尖头弹丸撞击下金属靶板弹道极限的两种工程模型

研究了圆锥形头和卵形头刚性弹垂直撞击塑性金属靶板扩孔冲塞型和延性扩孔型穿孔模式,考虑靶板背面自由边界的影响,提出两种两阶段工程分析模型,得到最小穿透能量的解析解。由球形空腔膨胀理论和两阶段总耗能最小确定第一阶段的侵彻深度,由功能原理和圆柱形空腔膨胀理论计算第一阶段侵彻扩孔耗能,延性扩孔型第二阶段耗能近似按Taylor扩孔理论计算,扩孔冲塞型第二阶段耗能考虑了加速塞块和剪断塞块所损耗的能量。与铝合金和装甲钢靶板弹道试验数据比较表明,本文两阶段模型的计算结果与试验结果吻合较好。