Synthesis, Crystal Structure and Photoluminescent Property of a Three-dimensional Zinc（Ⅱ） Coordination Polymer: [Zn1.5（PDB）（bix）0.5（μ2-OH）]2n

A new metal-organic coordination polymer [Zn1.5(PDB)(bix)0.5(μ2-OH)]2n 1 (H2PDB = pyridine-3,4-dicarboxylic acid, bix = 1,4-bis(imidazol-1-ylmethyl)-benzene) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P2/c with a = 7.411(2), b = 7.848(3), c = 25.048(8), V = 1451.8(8)3, C28H22N6O10Zn3, Mr = 798.63, Dc = 1.827 g/cm3, μ(MoKα) = 2.529 mm-1, F(000) = 804, Z = 2, the final R = 0.0440 and wR = 0.1035 for 1952 observed reflections (I > 2σ(I)). It exhibits a three-dimensional framework structure. Moreover, its luminescent property has been investigated in the solid state.     

大型液体火箭姿控与跷振大回路耦合动力学建模与分析

大型液体火箭结构模态的空间化分布特征导致结构振动、姿态运动和推进系统液路脉动存在相互耦合,进而影响传统姿控回路的稳定性. 针对大型液体火箭, 充分考虑姿态控制系统对箭体姿态动力学和弹性振动的影响, 以及箭体结构弹性振动与推进系统的耦合作用(跷振(POGO)), 建立了姿控与跷振大回路耦合模型. 该模型包含了推进系统、结构系统与姿控系统之间的耦合因素, 可进行姿控-结构-推进大回路耦合机理研究. 该模型具有非奇异的优点, 可以直接用于频域分析和时域仿真. 基于该模型研究了我国某型号液体捆绑火箭推进系统参数——泵增益和蓄压器能量值对姿态运动与结构振动稳定性的影响. 研究得出, 泵增益和蓄压器能量值的变化不仅导致了结构振动的不稳定, 而且也导致了姿态运动的发散. 因此, 对于大型液体捆绑火箭, 推进系统与姿控系统之间存在不可忽略的耦合作用, 在设计姿控系统时, 有必要考虑推进系统对姿控系统稳定性的影响.      

凝胶电解质的研究进展

本文评述了凝胶电解质－一种新型功能高人子材料的研究进展,讨论了电解质的特性,类型,关于其结构性能的研究方法,以及其在电双层电容器和锂离子二次电池方面的应用研究状况,并简要探讨了发展前景。     

Numerical investigation of effect of rolling manipulation of traditional Chinese medical massage on blood flow

The hemodynamic mechanism of rolling manipulation (RM) of traditional Chinese medical massage (TCMM) is investigated. An axisymmetrical nonlinear model and an arbitrary Lagrangian-Eulerian finite element method (ALE-FEM) with rezoning algorithm were introduced to study the viscous flow through an axisymmetrical rigid tube with axially moving stenosis to simulate the rolling manipulation. Flow rate and wall shear stress were obtained by solving complete Navier-Stokes equations numerically. The numerical results show that the stenosis moving frequency, namely the frequency of rolling manipulation, has great effect on the disturbance of flow and the wall shear stress. The stenosis coefficient, which characterizes the severity of the stenosis, another adjustable parameter in rolling manipulation, also shows the significant effect on flow rate and wall shear stress. These numerical results may provide some data that can be taken into consideration when massage is used in clinic.     

高信噪比集成化共振光电探测器

在理论分析的基础上，利用光电二极管的固有结电容和可变电感构成共振电路实现光电探测。通过精简电路并对电路板进行精密布板设计，降低由原内部混频电路带来的杂散寄生电容的影响；利用选定低噪声芯片、低转换损耗混频器及滤波器隔离噪声，构建高信噪比的集成化共振型光电探测器（RPD），并实现了对特定调制信号的高效探测。实验结果表明：在相同条件下，RPD增益在共振频率下比商用宽带探测器（BPD）高大约30 dB。利用RPD获得的锁腔误差信号的峰峰值是BPD的16倍，其误差信号的信噪比比现有BPD高18 dB左右。可见，此RPD能够为高性能压缩态光场制备提供器件支持。