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排序方式: 共有385条查询结果,搜索用时 15 毫秒
91.
92.
Gergely Gyetvai Sören Sundblom Lívia Nagy Ari Ivaska Géza Nagy 《Electroanalysis》2007,19(10):1116-1122
New solid contact ammonium micropipette electrodes (ISE), well applicable in scanning electrochemical microscopy are reported. The solid contact was made of a PEDOT nanowire coated carbon fiber, lowered down close to the orifice, and dipped inside the cocktail being in the pipette tip. This configuration provided low electrical resistance and good potential stability. Submicron tip size, usual in case of micropipette ISE‐s easily can be fabricated in this way. The applicability of the electrode in SECM has been proved in SG/TC mode imaging urease enzyme active spots in urea solutions. 相似文献
93.
Ari S. Nugraha Adama Hilou Nicholas Vandegraaff David I. Rhodes Rachada Haritakun 《Natural product research》2015,29(20):1954-1958
Phytochemical studies of the previously unexplored stem of Boerhavia erecta from Burkina Faso, resulted in the isolation of an unreported glycoside 4, 2,3-dihydroxypropylbenzoate-3-O-β-[4″-methoxy] glucuronide as well as seven known glycosides (1–3, 5–8). The major isolate 5 and 8 indicated a significant inhibition against HIV integrase (IC50 10 and 22 μg/mL, respectively). The extracts and isolates were also tested for anti-malarial activity, but insignificant activity was observed. 相似文献
94.
95.
We consider many-body states of bosonic spinor atoms which, at the mean-field level, can be characterized by a single-particle wave function for the Bose-Einstein condensation and Mott insulating states. We describe and apply a classification scheme that makes explicit the spin symmetries of such states and enables one to naturally analyze their collective modes and topological excitations. Quite generally, the method allows classification of a spin F system as a polyhedron with 2F vertices. We apply the method to the many-body states of bosons with spins two and three. For spin-two atoms we find the ferromagnetic state, a continuum of nematic states, and a state having the symmetry of the point group of the regular tetrahedron. For spin-three atoms we obtain similar ferromagnetic and nematic phases as well as states having symmetries of various types of polyhedra with six vertices. 相似文献
96.
Phenylpropanoid glycosides from Rhodiola rosea 总被引:2,自引:0,他引:2
Rhodiola rosea L. (Golden Root) has been used for a long time as an adaptogen in Chinese traditional medicine and is reported to have many pharmacological properties. Along its known secondary metabolites tyrosol (1), salidroside (rhodioloside) (2), rosin (3), rosarin (4), rosavin (5), sachaliside 1 (6) and 4-methoxy-cinnamyl-O-beta-D-glucopyranoside (7), four compounds were isolated from aqueous methanol extract of the plant and identified as cinnamyl-(6'-O-beta-xylopyranosyl)-O-beta-glucopyranoside (8), 4-methoxy-cinnamyl-(6'-O-alpha-arabinopyranosyl)-O-beta-glucopyranoside (9), picein (10) and benzyl-O-beta-glucopyranoside (11) by UV, MS and NMR methods. Compounds 8 and 9 are new natural compounds whereas compounds 10 and 11 were isolated first time from R. rosea. Also the compounds 6 and 7 are isolated earlier only from the callus cultures of the plant but not from the differentiated plant. 相似文献
97.
Gil Zilber Vladimir Rozenshtein Ari Ayalon Haim Levanon Mordecal Rabinovitz Lawrence T. Scott Hope B. Warren Gaby Persy Jakob Wirz 《Research on Chemical Intermediates》1996,22(9):839-854
Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed. 相似文献
98.
A liquid chromatography/electrospray ionization mass spectrometry (LC/ESI-MS) method based on time-of-flight (TOF) MS with polarity switching and continuous exact mass measurement using a LockSpray ion source was developed for fast evaluation of the total flavonoid content in plants and foodstuffs. No complicated sample preparation was needed, but only a dilution of the extracts. A fast generic gradient elution and wide mass range acquisition was used with good sensitivity. The total analysis time was only 23 min. The ion chromatograms for flavonoid compounds were automatically extracted, and the fragmentation patterns obtained using positive ion mode and exact mass data for both polarities were used for the tentative identification of compounds. Software-based automated searching of molecular ions for flavonoids and their glycosides (xylosides/arabinosides, rhamnosides, glucosides/galactosides) from total ion chromatograms was used. The compounds were quantified using quercetin, quercitrin, rutin and kuromanine as external standards and dextromethorphan as an internal standard. The detection limits ranged from 0.01-0.04 microg/mL, while the quantitation ranges obtained were 0.2-10 microg/mL for anthocyanins and 0.2-4 microg/mL for the other flavonoids. The accuracies within these ranges varied between 80-120% and precision was in the range 0-14% (relative standard deviation). Flavonoid contents of two medicinal plants (Hypericum perforatum and Rhodiola rosea), two grape red wines, two orange juices and two green teas were evaluated using the method, and the results obtained were in good agreement with those published previously. 相似文献
99.
Oxotungsten(VI) complex cis-[WO(LtBu)Me2] (LtBu = methylamino-N,N-bis(2-methylene-4-methyl-6-tert-butylphenolate) dianion) was prepared by the transmetallation reaction of [WO(LtBu)Cl2] (either cis or trans isomer) with methyl magnesium iodide. This unexpectedly stable dialkyl complex can be activated by Et2AlCl to catalyze the ring-opening metathesis polymerization of norbornene. 相似文献
100.
The behaviour of 2-mercaptoethanol at a hanging mercury drop electrode by cathodic stripping voltammetry (c.s.v.) is studied. The stripping curves are recorded by three scanning modes: rapid-scan direct-current, differential-pulse and fundamental harmonic alternating-current polarography. Under the recommended conditions, pre-electrolysis is done at a potential of 0.0 V vs. Ag/AgCl for 3 min in a medium of pH 6.7 or 8 (Britton-Robinson buffer). Then after 1 min, stripping is done at a scan rate of 6.6 mV s?1 preferably in the differential-pulse mode. The stripping peak at about ?0.4 V is used to determine 2-mercaptoethanol within the concentration range 3 × 10?8/2-8 × 10?7 mol l?1. Calibration functions are reported; the standard additions method is preferred near the limit of detection. The interferences of several organic compounds are described. 相似文献