Regulation of Zn/Sn ratio in kesterite absorbers to boost 10% efficiency of Cu_2ZnSn(S,Se)_4 solar cells

The Zn/Sn ratio in Cu_2ZnSn(S,Se)_4(CZTSSe)films has been regulated to control the composition-related phase,defect,and photoelectric properties for high performance kesterite solar cells.It is found that the increase in the Zn/Sn ratio can slightly narrow the energy band gap to extend the light absorption range and improve the photocurrent.Optimal Zn/Sn ratio of 1.39 in CZTSSe film is obtained with the least secondary phase,the lowest defect density,and the longest charge recombination lifetime.Up to 10.1%photoelectric conversion efficiency has been achieved by this composition regulation.     

藏药柳茶叶乙醇水提取物中化学成分的鉴定

采用多种色谱分离技术对藏药柳茶叶80%乙醇提取物进行分离纯化,得到了9个化合物。 根据其理化性质与NMR谱数据对化合物进行了结构鉴定,分别为金丝桃苷（hyperoside,Ⅰ）、槲皮素（quercetin,Ⅱ）、芸香苷（rutin,Ⅲ）、槲皮素3-O-β-D-吡喃葡萄糖苷（quercetin-3-O-β-D-glucopyranoside,Ⅳ）、儿茶素（catechin,Ⅴ）、香草酸（vanillic acid,Ⅵ）、熊果苷（arbutin,Ⅶ）、异阿魏酸（isoferulic acid,Ⅷ）和胡萝卜苷（daucosterol,Ⅸ）。 化合物中除Ⅳ、Ⅷ和Ⅸ外,其余6个化合物为首次从该属植物中分离鉴别。     

PDMAEMA多重环境响应行为的NMR研究

利用原子转移自由基聚合（Atom Transfer Radical Polymerization, ATRP）合成了分子量分布较窄的聚甲基丙烯酸N, N-二甲氨基乙酯{Poly\[2 (diethylamino)ethylmethacry-late], PDMAEMA}并通过对液体核磁共振氢谱（¹H NMR）化学位移以及弛豫时间（T₁、T₂）的测量,研究了聚合物PDMAEMA的温度敏感、pH敏感以及离子敏感3种环境敏感行为. 发现聚合物链段的运动性,以及温度和离子强度诱导的相变行为,都与体系的pH值具有强依赖关系. 室温下,聚合物链段的运动性随pH值的增大而降低. 酸性条件下,聚合物表现出离子敏感性,而不表现出温度敏感性. 碱性条件下,聚合物表现出温度敏感性,不表现出离子敏感性.     

QuEChERS-在线凝胶色谱-气相色谱-质谱法测定大米、黍子和小麦中34种农药残留

采用QuEChERS方法结合在线凝胶色谱-气相色谱-质谱（GPC-GC-MS）系统,建立了大米、黍子和小麦中34种中高毒农药的快速筛查方法。研究了称样量、萃取剂、净化吸附剂种类对大米样品提取净化效果的影响并考察了基质效应和分析保护剂的使用效果,采用选择离子监测（SIM）模式,外标法定量。结果表明,34种农药在大米、黍子和小麦中的检出限分别为0.0281~5.30、0.0282~4.82、0.0273~5.13 μg/kg;在0.05 μg/g添加水平的平均回收率分别为94.5%~117.1%、83.1%~121.7%、93.1%~120.2%;相对标准偏差（RSD,n=6）分别为2.6%~14.5%、3.4%~15.1%、3.5%~15.2%。该方法消耗试剂少,分析成本低,符合绿色化学的理念,具有操作便捷、快速、通用性强等特点,适用于大米、黍子和小麦中34种农药残留的快速筛查与检测。     

Effect of passive plates on vertical instability in the EAST tokamak

The effect of passive plates on vertical displacement control in the EAST tokamak is investigated by open loop experiments and numerical simulations based on a rigid displacement model.The experiments and simulations indicate that the vertical instability growth rate is reduced by a factor of about 2 in the presence of the passive plates,where the adjacent segments are not connected to each other.The simulations also show that the vertical instability growth rate is reduced by a factor of about 10 if all adjacent segments on each passive plate loop are connected to each other.The operational window is greatly enlarged with the passive plates.     

氨分子逐级键解离能降低的解释

采用理论计算方法解释了氨逐级解离能降低的现象。计算结果表明,随着N与H原子结合数目的减少,键解离能降低、键长增长;随着N与H原子结合数目的增多,N的2s电子跃迁到N的2p轨道上的几率增大,减小了屏蔽作用;更多电子从H的1s轨道迁移到N的2p轨道,增大了N和H之间的静电作用;单电子或孤对电子与N-H键夹角的增大减小了排斥作用。这3个因素造成NH3的逐级键解离能有降低的趋势。     

Switching the direction of spin accumulation in the spin Hall effect of light by adjusting the optical axis of an uniaxial crystal

We theoretically and experimentally investigate a switchable spin Hall effect (SHE) of light in reflection near the Brewster angle at an air-uniaxial crystal interface. We find a large transverse spin splitting near the Brewster angle, whose sign can be altered by rotating the optical axis. As an analogy of the SHE in an electronic system, a switchable spin accumulation in the SHE of light is detected. We are able to switch the direction of the spin accumulation by adjusting the optical axis angle of the uniaxial crystal. These findings may give opportunities for photon spin manipulating and developing a new generation of nano-photonic devices.     

6 mm~60 mm百万像素变焦安防镜头设计

设计一种可用于监控系统的大口径百万像素变焦距光学成像镜头,采用0.85 cm(1/3英寸)CCD接收,像元大小为3.75 m。镜头在短焦、中焦、长焦的位置时F数分别为1.6、2.1和2.4。变焦系统采用四组元组合形式,与传统的变焦系统相比,该系统采用第4组元作为补偿组。通过高斯法分析与求解得到初始结构,使用Zemax软件对其优化,系统均采用球面透镜进行设计。镜头轴上视场在133 lp/mm处大于0.3,轴外0.7视场在133 lp/mm处大于0.2,系统的最小后截距大于9 mm,满足装配要求。最后采用多点拟合绘制出此系统的变焦凸轮曲线。     

蓝宝石晶体生长过程中粘锅现象的实验研究

采用泡生法生长蓝宝石晶体的过程中,经常遇到粘锅问题.通过不同炉次的实验研究,分别分析了放肩阶段、等径生长阶段、收尾阶段等生长过程中产生粘锅的原因.指出温场的对称性是消除粘锅现象的最重要方式之一.同时,在放肩结束段及收尾阶段,为避免粘锅,可采用适当增大拉速及增加功率的措施.     

折反式微光夜视物镜的光学设计

介绍一种长焦距、大相对孔径微光夜视物镜的光学设计。设计参数为焦距100 mm,相对孔径1/1.4,视场10。为增大视距,减小物镜尺寸和质量,并且满足在宽光谱范围消色差的要求,选择均为球面的折反式物镜结构,在相同焦距和相对孔径的条件下折反式系统比折射系统尺寸更小,质量更轻。在设计过程中引入曼金反射镜,增加设计自由度。经优化设计达到较好的成像质量,空间频率在50 lp/mm时,轴上传递函数大于0.4,轴外传递函数大于0.2,与像增强器极限分辨率相匹配,全视场畸变小于2 %,物镜总长达到67 mm。