EFFECTS OF FINELY DISPERSED METALLIC PALLADIUM ON MICROSTRUCTURE AND PROPERTIES OF NANOCOMPOSITES PRODUCED BY SOL-GEL TECHNIQUE

Nanosized palladium particles were incorporated into mesoporous silica matrix to obtain nanocomposites using the sol-gel technique. Effects of the finely dispersed metallic palladium on the microstructure and properties of the nanocomposites were investigated. By means of X-ray diffraction and optical absorption, it was found that palladium particles were 5-9 nm in diameter and their uniform dispersion in the mesoporous silica depended on both the content of the palladium and the structural features of the silica matrix. The results showed that the mixing method of preparation led to wider size distribution of the nanosized particles as compared to the immersion method, but dispersed degree was reduced. Although the incorporation of nanosized palladium particles could not substantially induce significant structural changes of the matrix, the apparent red-shifted optical absorptions for the nanocomposites were observed as compared to the parent monolithic silica, particularly with increase in palladium loading and calcination temperature.     

Oblique Perforation of Thick Metallic Plates by Rigid Projectiles

Oblique perforation of thick metallic plates by rigid projectiles with various nose shapes is studied in this paper. Two perforation mechanisms, i.e., the hole enlargement for a sharp projectile nose and the plugging formation for a blunt projectile nose, are considered in the proposed analytical model. It is shown that the perforation of a thick plate is dominated by several non-dimensional numbers, i.e., the impact function, the geometry function of projectile, the non-dimensional thickness of target and the impact obliquity. Explicit formulae are obtained to predict the ballistic limit, residual velocity and directional change for the oblique perforation of thick metallic plates. The proposed model is able to predict the critical condition for the occurrence of ricochet. The proposed model is validated by comparing the predictions with other existing models and independent experimental data.The English text was polished by Keren Wang     

砼受压全过程发射b值与分形维数的研究

声发射ｂ值反映了材料内部微裂缝发展，本文在ＭＴＳ试验系统进行了砼受压全过程实验同时，检测了砼声发射的幅值和事件数变化，并根据实验结果对ｂ值进行了研究。研究表明：在应力－应变全曲线峰值处ｂ值最小。此外，还根据分形理论对砼受压全过程分形维数进行了研究。     

PBX颗粒力学性质对其撞击感度影响的初步研究

利用自行研制的应力测试系统研究了在机械撞击作用下粉状塑料粘结炸药(PBX)的表现。结果表明,由不同的聚氨酯(PU)溶液处理黑索今(RDX)得到的混和炸药PU-RDX,在机械撞击作用下给出的应力-时间曲线是多样的。而且PU-RDX的机械撞击感度随出现第二个应力峰的时间比(指不同的PU-RDX第二应力峰出现时间和仪器在空打时相应时间比)的增大,有下降的趋势。该时间比在一定程度上代表了粉状PU-RDX的塑性。研究在机械撞击作用下PBX的应力-时间特性有助于理解钝感炸药的机理、改进有关的工艺。     

运动参数惯性测量模拟弹设计与实验

在研制弹射式发射架的过程中,为了确保在高速飞行器上发射导弹的安全,需要预先在实验室内对发射架的弹射运动参数进行测试研究。而弹射分离过程时间短(仅为30～40 ms)、测量参数多(共18个运动和姿态参数),如何对其参数进行测量就成为一个研究重点。设计完成的弹射实验用模拟导弹是一种专用测试设备,它完全模拟真实导弹的机械特性,内部设计装有微型惯性测量系统(MIMS),可以在弹射过程中完全自主地对所有运动参数和姿态变化进行惯性测量,实验表明测量精度达到3%以内。其中应用的MIMS是惯性测量技术在该领域的创新型应用,具有测量范围大(±500(°)/s)、动态性能好(最高可达4 kHz)、操作简便等优势。     

高温高压下Zr2AlC的结构及热学性质的第一性原理

利用密度泛函理论研究了高温高压下Zr₂AlC的结构和热力学性质,计算得到Zr₂AlC的晶格参数与实验值符合较好．研究了Zr₂AlC的弹性常数、体模量、剪切模量和杨氏模量等力学性质随压力变化的趋势．同时研究了维氏硬度随压力的变化趋势．通过计算得到的杨氏模量预测了Zr₂AlC的弹性各向异性．最后,基于准简谐德拜模型,成功预测了Zr₂AlC的德拜温度、热容、热膨胀系数和Grüneisen参数随着压强和温度的变化关系.     

外区域上的抛物型Monge-Ampère方程

研究外区域上的抛物型Monge-Ampere方程-u_t det(D~2u)=f解的存在性.利用Perron方法得到了该方程的外问题具有渐近性质解的存在性与唯一性.     

变系数拟自回归模型下的测量误差分析

本文对雷达测量误差影响较大的因素进行了分析研究,并将其和雷达测量数据一起建立了变系数拟自回归的统计模型以实现对雷达测量值的纠偏,利用剖面最小二乘法估计模型参数,在一定条件下证明了模型的大样本性质,并结合残差的峰度和偏度构建了区间估计。实际数据的拟合和预测结果显示,我们提出的纠偏方法可将误差减少90%。     

巧用三点共线几何性质解题

<正>中学生数学2014年2月(上)第483期(高中)的《关于c→=xa→+yb→的几种常见转化方法》笔者阅读后感觉如果巧用c→=xa→+yb→的三点共线几何性质来解题,则会收到意想不到的效果.具体如下.例1已知平面内不共线的四点O、A、B、     

以函数为载体的新定义试题

<正>新定义题目为近年中考热点问题,既能考查同学们的基础知识,又能考查同学们的阅读理解能力、抽象概括能力和思维创新能力,体现出"考查能力"的主旨.求解时应从所给的新定义出发,化"新"为"旧",也就是把新定义内容转化为所学过知识,从而达到化"未知"为"已知"的目的,再运用相应"旧知"的基本概念和性质定理,层层递进,进而解决这类问题.现举例加以说明,供参考.