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81.
The effects of 60Co (γ-ray) irradiation on the electrical and dielectric properties of Al-TiW-Pd2Si/n-Si Schottky diodes (SDs) have been investigated by using capacitance-voltage (C-V) and conductance-voltage (G/ω-V) measurements at room temperature and 500 KHz. The corrected capacitance and conductance values were obtained by eliminating the effect of series resistance (Rs) on the measured capacitance (Cm) and conductance (Gm) values. The high-low frequency capacitance (CHF-CLF) method given in [12] as Nss = (1/qA) [((1/CLF) − (1/Cox))−1 − ((1/CHF) − (1/Cox))−1] was successfully adapted to the before-after irradiation capacitance given in this report as Nss = (1/qA) [((1/Cbef) − (1/Cox))−1 − ((1/Cafter) − (1/Cox))−1] for the analyzing the density of interface states. The Nss-V plots give a distinct peak corresponding to localized interface states regions at metal and semiconductor interface. The experimental values of the ac electrical conductivity (σac), the real (M′) and imaginary (M″) parts of the electrical modulus were found to be strong functions of radiation and applied bias voltage, especially in the depletion and accumulation regions. The changes in the dielectric properties in the depletion and accumulation regions stem especially from the restructuring and reordering of the charges at interface states and surface polarization whereas those in the accumulation region are caused by series resistance effect. 相似文献
82.
Evgenia Minko Petr Sysel Michal Hauf Jiří Brus Libor Kobera 《Macromolecular Symposia》2010,295(1):88-93
Summary: The novel hyperbranched polyimide - silica hybrid materials containing theoretically 16 wt% of an inorganic phase were prepared via a sol-gel process. An amine terminated polyimide precursor (hyperbranched polyamic acid) was prepared from commercially available monomers 4,4′,4″-triaminotriphenylmethane and 4,4′-oxydiphthalic anhydride in molar ratio 1:1. Tetramethoxysilane and/or 3-glycidoxypropyltrimethoxysilane (also used as a coupling agent) were used as silica precursors. During thermal exposition the polyimide precursor was transformed to hyperbranched polyimide and hydrolyzed alkoxy groups reacted mutually to form silica. The final products were self-standing films, whose structure was characterized by using IR and 13C and 29Si solid state NMR spectroscopy. The influence of the amount of silica and/or coupling agent on their structure and thermal properties was described. 相似文献
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Experimental results on the current–voltage (I–V) characteristics of amorphous Si nanostructures reported by Irrera et al. [A. Irrera, F. Iacona, I. Crupil, C.D. Presti, G. Franzo, C. Bongiorno, D. Sanfilippo, G. Di Stefano, A. Piana, P.G. Fallica, A. Canino, F. Priolo, Nanotechnology 17 (2006) 1428] are reinterpreted in terms of a phonon-assisted tunneling model. It is shown that temperature dependence of current can be caused by the temperature dependence of electron tunneling rate from traps in the metal–semiconductor interface to the conduction band of the semiconductor. A good fit of experimental data with the theory is achieved in all measured temperature range from 30 to 290 K using for calculation the effective mass of 0.5me, and for the phonon energy the value of 12 meV. An advantage of this model over that of Irrera et al. used model is the possibility of describing the behavior of I–V data measured at both high and low temperatures with the same set of parameters characterizing this material. The temperature-dependent I–V data by Schricker et al. [A.D. Schricker, F.M. Davidson III, R.J. Wiacek, B.A. Korgel, Nanotechn. 17 (2006) 2681.] of GaAs nanowires, are also explained on the basis of this model. 相似文献
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An ultrahigh vacuum scanning Kelvin probe force microscope (UHV SKPM) based on the gradient of electrostatic force was developed using the technique of a UHV non-contact atomic force microscope (NC-AFM) capable of atomic level imaging, and used for simultaneous observation of contact potential difference (CPD) and NC-AFM images. The CPD images with a potential resolution of less than 10 meV were observed in the UHV SKPM, demonstrating an atomic level resolution. The change of potential corresponding to the charges on the insulated surface of polypropylene have been observed in UHV SKPM. We also demonstrated a reliable method to obtain the CPD from the bias voltage dependence curves of the frequency shift in all of the scanning area. The results are consistent with comparing the barrier height images in that the work functions of adatoms are greater than the work function of corner holes. 相似文献
88.
本文采用Hartree-Fock自洽场方法,从理论上计算出类锂硅离子1s~2nl(n=2~7,l=0~5)各能级能量,并给出在极紫外(波长小于400(?))范围内各跃迁谱线的光谱性质、波长、振子强度和跃迁几率.对实验中已实现软X射线激光的跃迁(5d-3p,5f-3d,6d-3p,6f-3d),计算所得的跃迁波长与实验值完全相符.与现有文献的波长比较,相对误差不超过1%. 相似文献
89.
Mourad Benlamri Kyle M. Bothe Alex M. Ma Gem Shoute Amir Afshar Himani Sharma Arash Mohammadpour Manisha Gupta Kenneth C. Cadien Ying Y. Tsui Karthik Shankar Douglas W. Barlage 《固体物理学:研究快报》2014,8(10):871-875
A high effective electron mobility of 33 cm2 V–1 s–1 was achieved in solution‐processed undoped zinc oxide (ZnO) thin films. The introduction of silicon nitride (Si3N4) as growth substrate resulted in a mobility improvement by a factor of 2.5 with respect to the commonly used silicon oxide (SiO2). The solution‐processed ZnO thin films grown on Si3N4, prepared by low‐pressure chemical vapor deposition, revealed bigger grain sizes, lower strain and better crystalline quality in comparison to the films grown on thermal SiO2. These results show that the nucleation and growth mechanisms of solution‐processed films are substrate dependent and affect the final film structure accordingly. The substantial difference in electron mobilities suggests that, in addition to the grain morphology and crystalline structure effects, defect chemistry is a contributing factor that also depends on the particular substrate. In this respect, interface trap densities measured in high‐κ HfO2/ZnO MOSCAPs were about ten times lower in those fabricated on Si3N4 substrates. (© 2014 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)
90.
Mechanical and thermodynamic properties of the monoclinic and orthorhombic phases of SiC_2N_4 under high pressure from first principles 下载免费PDF全文
First principles calculations are preformed to systematically investigate the electronic structures, elastic and thermodynamic properties of the monoclinic and orthorhombic phases of Si C2N4 under pressure. The calculated structural parameters and elastic moduli are in good agreement with the available theoretical values at zero pressure. The elastic constants of the two phases under pressure are calculated by stress–strain method. It is found that both phases satisfy the mechanical stability criteria within 60 GPa. With the increase of pressure, the degree of the anisotropy decreases rapidly in the monoclinic phase, whereas it remains almost constant in the orthorhombic phase. Furthermore, using the hybrid density-functional theory, the monoclinic and orthorhombic phases are found to be wide band-gap semiconductors with band gaps of about 2.85 e V and 3.21 e V, respectively. The elastic moduli, ductile or brittle behaviors, compressional and shear wave velocities as well as Debye temperatures as a function of pressure in both phases are also investigated in detail. 相似文献