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81.
82.
《Solid State Sciences》2012,14(5):650-654
Two new beryllium phosphites, H2en·Be3(HPO3)4 (1) and H2pda·Be3(HPO3)4 (2), have been synthesized under hydrothermal conditions. Single-crystal structural analyses reveal that both compounds have three-dimensional inorganic frameworks constructed from strictly alternating BeO4 tetrahedra and HPO3 pseudo pyramids. The structure of compound 1 can be described as a pillared layered structure with 12-ring channels. The structure of compound 2 has an interesting sqp topology if Be3(HPO3)4 clusters are regarded as 5-connected nodes in the network. 相似文献
83.
Heping Deng Wei Cao Rong Liu Yanhui Zhang Prof. Dr. Bo Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(21):5943-5946
Asymmetric total synthesis of the dimeric diterpenoid hispidanin A was accomplished by non-catalytic Diels–Alder cycloaddition at room temperature. The synthesis relies on iron-catalyzed coupling to construct a Z-configured trisubstituted alkene, an iron-catalyzed radical cascade to generate a labdane-type diene, and both Yamamoto cationic polyene cyclization and palladium-catalyzed Stille coupling to generate a totarane-type dienophile. 相似文献
84.
Numerical preference relations (NPRs) consisting of numerical judgments can be considered as a general form of the existing preference relations, such as multiplicative preference relations (MPRs), fuzzy preference relations (FPRs), interval MPRs (IV-MPRs) and interval FPRs (IV-FPRs). On the basis of NPRs, we develop a stochastic preference analysis (SPA) method to aid the decision makers (DMs) in decision making. The numerical judgments in NPRs can also be characterized by different probability distributions in accordance with practice. By exploring the judgment space of NPRs, SPA produces several outcomes including the rank acceptability index, the expected priority vector, the expected rank and the confidence factor. The outcomes are obtained by Monte Carlo simulation with at least 95% confidence degree. Based on the outcomes, the DMs can choose some of them which they find most useful to make reliable decisions. 相似文献
85.
In this note, we show that the blowing-up of a point on a locally conformally balanced manifold also admits a locally conformally Balanced manifold structure. 相似文献
86.
Flow segmentation based on similar motion patterns in crowded scenes remains an open problem in computer vision due to inherent complexity and vast diversity found in such scenes. To solve this problem, the streakline framework based on Lagrangian fluid dynamics had been proposed recently. However, this framework computed optical flow field using conventional optical flow method (Lucas Kanade method) which has poor anti-interference performance, and serious deviation would be brought to the computation of optical flow field. Moreover, our experimental results show that using the formulation of streak flow similarity in this framework can result in incorrect flow segmentation. Therefore, we combine this framework with a high accurate variational model, and modify the corresponding formulation of streak flow similarity after analyzing the streakline framework in detail. Finally, an improved method is proposed to solve flow segmentation in crowded scenes. Experiments are done to compare these two methods and results verify the validity and accuracy of our method. 相似文献
87.
An easily prepared tetraphosphine N,N,N′,N′‐tetra(diphenylphosphinomethyl)‐1,2‐ethylenediamine (1) combined with PdCl2 affords an efficient catalytic system for Suzuki cross‐coupling of aryl and heteroaryl bromides. A high turnover number of 750 000 is obtained with the catalyst loading as low as 1 ppm. This catalyst system exhibits good stability and longevity. In this study, a broad scope of substrates is investigated and satisfactory yields are obtained. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
88.
Dr. Peng Wu Ting Zhao Yunfei Tian Dr. Lan Wu Prof. Dr. Xiandeng Hou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(23):7473-7479
Proteins typically have nanoscale dimensions and multiple binding sites with inorganic ions, which facilitates the templated synthesis of nanoparticles to yield nanoparticle–protein hybrids with tailored functionality, water solubility, and tunable frameworks with well‐defined structure. In this work, we report a protein‐templated synthesis of Mn‐doped ZnS quantum dots (QDs) by exploring bovine serum albumin (BSA) as the template. The obtained Mn‐doped ZnS QDs give phosphorescence emission centered at 590 nm, with a decay time of about 1.9 ms. A dual‐channel sensing system for two different proteins was developed through integration of the optical responses (phosphorescence emission and resonant light scattering (RLS)) of Mn‐doped ZnS QDs and recognition of them by surface BSA phosphorescent sensing of trypsin and RLS sensing of lysozyme. Trypsin can digest BSA and remove BSA from the surface of Mn‐doped ZnS QDs, thus quenching the phosphorescence of QDs, whereas lysozyme can assemble with BSA to lead to aggregation of QDs and enhanced RLS intensity. The detection limits for trypsin and lysozyme were 40 and 3 nM , respectively. The selectivity of the respective channel for trypsin and lysozyme was evaluated with a series of other proteins. Unlike other protein sensors based on nanobioconjugates, the proposed dual‐channel sensor employs only one type of QDs but can detect two different proteins. Further, we found the RLS of QDs can also be useful for studying the BSA–lysozyme binding stoichiometry, which has not been reported in the literature. These successful biosensor applications clearly demonstrate that BSA not only serves as a template for growth of Mn‐doped ZnS QDs, but also impacts the QDs for selective recognition of analyte proteins. 相似文献
89.
Zhen Wang Zuliang Zhang Qian Yao Prof. Dr. Xiaohua Liu Yunfei Cai Dr. Lili Lin Prof. Dr. Xiaoming Feng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(26):8591-8596
The highly Z‐selective asymmetric conjugate addition of 3‐substituted oxindoles to alkynyl carbonyl compounds has been developed by using scandium complexes of chiral N,N′‐dioxides under mild conditions. The thermodynamically unstable Z‐olefin derivatives were obtained in excellent yields and high enantiomeric and geometric control. The catalyst was also found to be effective in the asymmetric acetylenic substitution reaction of 3‐substituted oxindoles, giving excellent enantioselectivities. 相似文献
90.
A novel functionalized α-zirconium phosphate (F-ZrP) modified with intumescent flame retardant was synthesized by co-precipitation method and characterized. Poly (lactic acid) (PLA)/F-ZrP nanocomposites were prepared by melt blending method. The thermal stability and combustion behavior of PLA/F-ZrP nanocomposites were investigated by thermogravimetric analysis (TGA), limiting oxygen index (LOI), vertical burning test (UL-94), scanning electronic microscopy (SEM), and cone calorimeter test (CCT). The results showed that the addition of flame retardant F-ZrP slightly affect PLA's thermal stability, but significantly improve the flame retardancy of PLA composites. In comparison with neat PLA, the LOI value of PLA/F-ZrP was increased from 19.0 to 26.5, and the UL-94 rating was enhanced to V-0 as the loading of F-ZrP at 10%. SEM results suggested the introduction of F-ZrP in the PLA system can form compact intumescent char layer during burning. All these results showed that the F-ZrP performed good flame retardancy for PLA. 相似文献