Cu2ZnSnS4纳米晶的制备及其三阶非线性光学性能的研究

以乙酰丙酮铜、醋酸锌、二氯亚锡、油胺和硫粉为前驱体,采用one-pot法合成出了单分散的Cu2ZnSnS4(CZTS)纳米晶.所得样品采用X射线粉末衍射仪(XRD),能量色散谱仪(EDS),透射电子显微镜(TEM),高分辨透射电子显微镜(HRTEM),光电子能谱仪(XPS),紫外-可见光谱仪(UV-vis)和Z-扫描(Z-scan)技术对其结构组成、形貌、性能等进行了表征.结果表明:所获得的产物为四方相结构的六边形CZTS纳米颗粒,直径约为10 nm.计算出尺寸大小为10 nm,13 nm的纳米晶的三阶非线性光学折射率γ(-1.08×10-15,-9.08×10-17 m2·W-1),三阶非线性光学吸收系数β(6.5×10-9,3.69×10-11 m·W-1)以及三阶非线性光学极化率χ(3)(1.49×10-9,4.35×10-10 esu).并探讨了CZTS纳米晶可能的形成机理,及引起三阶光学非线性发生变化的原因。     

高分子载体材料对青霉素酰化酶的固定化作用

介绍了天然高分子材料和合成高分子材料对青霉素酰化酶的固定化作用,着重讨论了高分子材料的制备、性质及其表面修饰对固定化酶活性和使用稳定性的影响。     

基于半导体断路开关的8 MW,10 kHz脉冲发生器

 功率器件半导体断路开关具有高重复频率工作能力。采用高速绝缘栅双极晶体管组件作为初级充电回路的主开关,建立了一台工作频率为10 kHz的脉冲发生器。脉冲发生器采用磁饱和脉冲变压器、磁开关及高压脉冲电容器组等固态器件进行两级脉冲压缩,产生小于100 ns的电流脉冲,对半导体断路开关进行泵浦,半导体断路开关反向截断泵浦电流在负载上产生高压脉冲输出。实验装置在电阻负载上得到了脉冲输出功率约为8.6 MW,脉冲宽度约10 ns,重复频率10 kHz的高压脉冲输出。     

基于视觉容差与色调角相关性的色差公式评价

为了研究CIELAB颜色空间中明度、彩度和色调等视觉容差与色调角之间的相关性对基于CIELAB的典型色差公式(CIELAB、CMC、BFD、CIE94、LCD以及CIEDE2000)预测性能的影响,实验选取了具有不同明度和彩度冰平的5个色调环(L*=30,50,70和Cab*=10,20,30),并采用3个不同视觉尺度(△V=3.02,5.92和8.87CIELAB单位)进行视觉评估实验.8名色觉正常观察者根据心理物理学的恒常刺激法原理,在阴极射线管(CRT)显示器上获取了相应颜色中心的明度、彩度和色调视觉容差.对实验结果的详细分析表明,由于明度容差与色调角无明显相关性,6个色差公式的预测性能均较好,其中CIEDE2000略优于其它色差公式.对于彩度容差,LCD(Leeds color-difference formula)预测性能表现最优,而CIEDE2000和BFD的表现最差,其余色差公式则相差不多.CIEDE2000和LCD的色调权重函数的预测性能明显优于其它色差公式,而CMC预测性能则为最差.     

Photoluminescence and X-Ray Photoelectron Spectroscopy of p-Type Phosphorus-Doped ZnO Films Prepared by MOCVD

Reproducible p-type phosphorus-doped ZnO （p-ZnO：P） films are prepared on semi-insulating InP substrates by metal-organic chemical vapour deposition technology. The electrical properties of these films show a hole concentration of 9.02 × 10^17 cm ^-3, a mobifity of 1.05 cm^2 /Vs, and a resistivity of 6.6 Ω.cm. Obvious acceptorbound-exciton-related emission and P-induced zinc vacancy （Vzn） emission are observed by low-temperature photoluminescence spectra of the films, and the acceptor binding energy is estimated to be about 125meV. The local chemical bonding environments of the phosphorus atoms in the ZnO are also identified by x-ray photoelectron spectra. Our results show direct experimental evidence that Pzn-2Vzn shallow acceptor complex most likely contributes to the p-type conductivity of ZnO：P films.     

A robust photometric calibration framework for projector-camera display system

A novel photometric calibration framework is presented for a projector-camera （ProCam） display system, which is currently under booming development. Firstly, a piecewise bilinear model and five 5-ary color coding images are used to construct the homography between the image planes of a projector and a camera. Secondly, a photometric model is proposed to describe the data flow of the ProCam display system for displaying color images on colored surface in a general way. An efficient self-calibration algorithm is correspondingly put forward to recover the model parameters. Aiming to adapt this algorithm to different types of ProCam display system robustly, a 3× 7 masking coupling matrix and a patches image with 1024 color samples are adopted to fit the complex channel interference function of the display system. Finally, the experimental results demonstrate the validity and superiority of this calibration algorithm for the ProCam display system.     

Extended Measurement of the v2 (1- ←0+) Band of H3O+ by Mid-Infrared Diode Laser Spectroscopy

Twenty-five new R-branch lines of the v2（1^-← 0^＋） band of H3O^＋ are measured using diode laser velocity modulation spectroscopy between 1070 and 1230 cm^-1. The H3O^＋ ions are produced in a high voltage ac discharge with water diluted in helium. The observed lines together with all the previously published measurements are fit to the standard vibration-rotational Hamiltonian of an oblate symmetric top, yielding a set of improved molecular constants. All the sextic centrifugal distortion constants for both 0^＋ and 1^- states are determined precisely. The observed R（13, 0） transition is shifted about -0.129 cm^-1 from its calculated value, indicating that a near degeneracy exists between the （13, 0）^＋ and （13, 3）^- ground-state rotation-inversion levels.     

以混合模板剂合成TS-1分子筛及其性能研究

以四丁基溴化铵（ＴＢＡＢｒ）＋四乙基氢氧化铵（ＴＥＡＯＨ，ｎ（ＴＢＡ＋）／ｎ（ＴＥＡ＋）＝１）或以四丙基溴化铵（ＴＰＡＢｒ）＋ＴＥＡＯＨ为模板剂，钛酸四丁酯和正硅酸乙酯为原料，于１７０℃水热合成出ＴＳ１分子筛．对合成的ＴＳ１样品进行了ＸＲＤ，ＦＴＩＲ，ＳＥＭ和ＢＥＴ比表面积分析，证实了样品中钛已进入Ｓｉｌｉｃａｌｉｔｅ１骨架．选择戊烷氧化为探针反应，考察了ＴＳ１的催化活性．结果表明以ＴＥＡＯＨ为碱，合成的样品晶粒较大，达到４～１０μｍ，用氨水和ＴＥＡＯＨ调节反应液的碱度，对晶体的生长和形貌的影响各不相同．文中还就ＴＥＡＯＨ引入的作用进行了讨论．     

甲烷氧化偶联Ti-La-Li系混合氧化物催化剂

研究了Ti-La-Li三元氧化物的组成、结构及其对甲烷氧化偶联反应的催化性能；用XRD、IR、XPS和SEM等方法对催化剂进行表征，结果表明：在LiTi_xLa_(1-x)O_2系列催化剂中，随x值的不同，可生成LaTi_(1－y)Li_yO_(3-λ)、Li_2TiO_3、La_(0.66)TiO_(2.993)、La_2O_3和Li_(1.33)Ti_(1.66)O_4几种物相，其中，钙钛矿到三元复合氧化物LaTi_(1-y)Li_yO_(3-λ)是甲烷氧化偶联反应的主要活性相，活性位Li~＋-O~－-Ti~(3＋)的形成是活性提高的主要原因．Li_2TiO_3和La_(0.66)TiO_(2.993)是深度氧化活性相，而Li_(1.33)Ti_(1.66)O_4既无偶联活性，也无深度氧化活性．     

青霉素酰化酶在甲基丙烯酸缩水甘油酯共聚物上的固定化

 用共价键合法将青霉素酰化酶固定化在珠状多孔的甲基丙烯酸缩水甘油酯（GM）共聚物上，研究了固定化反应时间、温度、pH值和酶液用量对固定化青霉素酰化酶的表观活性、表观偶联效率、活性回收及稳定性的影响．将GM共聚物载体加入到磷酸缓冲液（0．1mol／L，pH10．8）与青霉素酰化酶液（每克干载体用酶液1ml）的混合溶液中，在30℃下反应72h，单位质量（干重）固定化酶的表观活性为348U／g，表观偶联效率为66．7％，活性回收为31．7％．