铑(Ⅱ)和锆(Ⅳ)共同催化的重氮乙酸酯,苄醇和醛的多组分反应

重氮乙酸酯和苄醇在铑(Ⅱ)催化下形成的氧叶立德中间体被锆(Ⅳ)活化的醛捕捉,以中等收率生成α,β-双羟基酸衍生物.     

非奇H矩阵的充分条件

文章通过引进一类具有非零元素链的矩阵,利用α对角占优矩阵性质,给出了一个新的非奇H矩阵的充分条件,扩大了非奇H矩阵的判定范围．     

磁场中轴向运动条形板强非线性超谐共振及混沌运动

针对磁场环境中周期外载作用下轴向运动导电条形板的非线性振动及混沌运动问题进行研究。应用改进多尺度法对横向磁场中条形板的强非线性振动问题进行求解,得到超谐波共振下系统的分岔响应方程。根据奇异性理论对非线性动力学系统的普适开折进行分析,求得含两个开折参数的转迁集及对应区域的拓扑结构分岔图。通过数值算例,分别得到以磁感应强度、轴向拉力、激励力幅值和激励频率为分岔控制参数的分岔图和最大李雅普诺夫指数图,以及反映不同运动行为区域的动力学响应图形,讨论分岔参数对系统呈现的倍周期和混沌运动的影响。结果表明,可通过相应参数的改变实现对系统复杂动力学行为的控制。     

Principal parametric resonance of axially accelerating rectangular thin plate in magnetic field

Nonlinear parametric vibration and stability is investigated for an axially accelerating rectangular thin plate subjected to parametric excitations resulting from the axial time-varying tension and axial time-varying speed in the magnetic field. Consid- ering geometric nonlinearity, based on the expressions of total kinetic energy, potential energy, and electromagnetic force, the nonlinear magneto-elastic vibration equations of axially moving rectangular thin plate are derived by using the Hamilton principle. Based on displacement mode hypothesis, by using the Galerkin method, the nonlinear para- metric oscillation equation of the axially moving rectangular thin plate with four simply supported edges in the transverse magnetic field is obtained. The nonlinear principal parametric resonance amplitude-frequency equation is further derived by means of the multiple-scale method. The stability of the steady-state solution is also discussed, and the critical condition of stability is determined. As numerical examples for an axially moving rectangular thin plate, the influences of the detuning parameter, axial speed, axial tension, and magnetic induction intensity on the principal parametric resonance behavior are investigated.     

次磷酸铝协同硼酸锌阻燃聚乙烯

以次磷酸铝(AHP)和硼酸锌(ZB)为复合阻燃剂,通过熔融共混法制备了阻燃聚乙烯(PE)材料,研究了AHP和ZB对PE的协同阻燃效应。 结果表明,AHP、ZB阻燃剂在PE基体中分散均匀;添加质量分数为25%AHP阻燃剂,PE材料的极限氧指数值(LOI)提升至25%,通过垂直燃烧测试(UL-94(3.2 mm))V-2级,显示出良好的阻燃效果;引入ZB后,材料LOI值呈先升高后下降趋势,在m(AHP):m(ZB)=21:4时,出现峰值,达到27.2%,并通过UL-94(3.2 mm)V-1级;热失重分析(TGA)结果显示,AHP、ZB阻燃剂能同时提高PE材料的热稳定性和成炭率,当m(AHP):m(ZB)=17:8时,残渣率达到25.7%。     

基于低相干干涉的透镜厚度测量及生物影像研究进展

低相干光干涉测量技术作为重要的非接触测量方法之一,由于具有结构简单、测量速度快及分辨率高的优点,在光学系统的非接触测量及生物医学影像等前沿领域具有广阔的应用前景。本文对透镜组的光学元件中心厚度及空气间隔的非接触测量技术进行了总结,简述了基于OCT的生物医学影像方面研究现状,重点论述基于低相干光干涉法测量原理和研究进展,对比分析相关研究方法的优缺点和创新之处,并从系统结构和应用范围的角度对低相干干涉测量技术的发展趋势作了展望。     

Universal order-parameter and quantum phase transition for two-dimensional q-state quantum Potts model

We investigate quantum phase transitions for q-state quantum Potts models (q=2,3,4) on a square lattice and for the Ising model on a honeycomb lattice by using the infinite projected entangled-pair state algorithm with a simplified updating scheme. We extend the universal order parameter to a two-dimensional lattice system, which allows us to explore quantum phase transitions with symmetry-broken order for any translation-invariant quantum lattice system of the symmetry group G. The universal order parameter is zero in the symmetric phase, and it ranges from zero to unity in the symmetry-broken phase. The ground-state fidelity per lattice site is computed, and a pinch point is identified on the fidelity surface near the critical point. The results offer another example highlighting the connection between (i) critical points for a quantum many-body system undergoing a quantum phase-transition and (ii) pinch points on a fidelity surface. In addition, we discuss three quantum coherence measures: the quantum Jensen-Shannon divergence, the relative entropy of coherence, and the l₁ norm of coherence, which are singular at the critical point, thereby identifying quantum phase transitions.     

Iterative filtered ghost imaging

It is generally believed that, in ghost imaging, there has to be a compromise between resolution and visibility. Here we propose and demonstrate an iterative filtered ghost imaging scheme whereby a super-resolution image of a grayscale object is achieved, while at the same time the signal-to-noise ratio (SNR) and visibility are greatly improved, without adding complexity. The dependence of the SNR, visibility, and resolution on the number of iterations is also investigated and discussed. Moreover, with the use of compressed sensing the sampling number can be reduced to less than 1% of the Nyquist limit, while maintaining image quality with a resolution that can exceed the Rayleigh diffraction bound by more than a factor of 10.     

A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage

Li dendrites and electrolyte leakage are common causes of Li-ion battery failure. H₂, generated by Li dendrites, and electrolyte vapors have been regarded as gas markers of the early safety warning of Li-ion batteries. SnO₂-based gas sensors, widely used for a variety of applications, are promising for the early safety detection of Li-ion batteries, which are necessary and urgently required for the development of Li-ion battery systems. However, the traditional SnO₂ sensor, with a single signal, cannot demonstrate intelligent multi-gas recognition. Here, a single dual-mode (direct and alternating current modes) SnO₂ sensor demonstrates clear discrimination of electrolyte vapors and H₂, released in different states of Li-ion batteries, together with principal component analysis (PCA) analysis. This work provides insight into the intelligent technology of single gas sensors.     

Switching plasticity in compensated ferrimagnetic multilayers for neuromorphic computing

Current-induced multilevel magnetization switching in ferrimagnetic spintronic devices is highly pursued for the application in neuromorphic computing. In this work, we demonstrate the switching plasticity in Co/Gd ferrimagnetic multilayers where the binary states magnetization switching induced by spin-orbit toque can be tuned into a multistate one as decreasing the domain nucleation barrier. Therefore, the switching plasticity can be tuned by the perpendicular magnetic anisotropy of the multilayers and the in-plane magnetic field. Moreover, we used the switching plasticity of Co/Gd multilayers for demonstrating spike timing-dependent plasticity and sigmoid-like activation behavior. This work gives useful guidance to design multilevel spintronic devices which could be applied in high-performance neuromorphic computing.