毛细管区带电泳—前沿分析法测定苯甲酸钠与牛血清白蛋白的相互作用

将毛细管区带电泳-前沿分析技术(CZE-FA)用于测定苯甲酸钠与牛血清白蛋白(BSA)平衡体系中结合参数的研究.通过压力进样将苯甲酸钠和白蛋白混合液引入石英毛细管电泳柱,在20 mmol/L硼砂缓冲液(pH=9.2)及20kV运行电压条件下,未结合苯甲酸钠的浓度可通过电泳平台峰的高度定量,两者具有良好的线性关系(相关系...     

气相色谱-负离子化学源-质谱法分析禽蛋食品中10种多溴联苯和多溴联苯醚残留

建立了气相色谱-负离子化学源-质谱法(GC-NCI-MS)同时分析禽蛋食品中10种多溴联苯(PBBs)和多溴联苯醚(PBDEs)残留的分析方法。禽蛋食品用正己烷超声提取、浓硫酸酸化、中性和酸性硅胶层析柱净化和正己烷洗脱后,以PCB209为内标物,采用GC-NCI-MS的选择离子监测方式(SIM)分析;同时探讨了目标物PBDE100 NCI-MS特征离子的断裂机理。当禽蛋食品空白的加标质量浓度为5(3.5)和50(35)μg/kg时,加标回收率为75.2%～107%,相对标准偏差为2.3%～8.8%,方法检测限为0.14～0.39μg/kg,线性范围为1～250μg/kg,相关系数皆大于0.9991,方法已用于禽蛋食品中10种痕量PPBs和PBDEs残留的同时分析。     

火焰原子吸收光谱法测定厚朴花中金属元素含量

采用浓硝酸-高氯酸(5+1)消解处理样品,火焰原子吸收光谱法测定厚朴花中Ca、Mg、Fe、Zn、Cu和Mn6种金属元素含量。测定结果显示,厚朴花中含有丰富的金属元素。实验为探讨厚朴花中金属元素含量与药理关系提供了有用的数据。采用火焰原子吸收光谱法测定厚朴花中金属元素含量,操作简便、快速,结果准确。     

Highly sensitive giant magnetoimpedance in a solenoid containing FeCo-based ribbon

The highly sensitive giant magneto-impedance effect in a solenoid containing a magnetic core of Fe₃₆Co₃₆Nb₄Si_4.8B_19.2 (FeCo-based) ribbon under a weak magnetic field (WMF) is presented in this paper. The FeCo-based amorphous ribbon is prepared by single roller quenching and annealed with Joule heat in a flowing nitrogen atmosphere. The giant magnetoimpedance effect in solenoid (GMIES) profiles are measured with an HP4294A impedance analyzer. The result shows that the GMIES responds to the WMF sensitively (as high as 1580 %/A穖^-1). The high sensitivity can be obtained in a moderate narrow range of annealing current density (30-34 A/mm²) and closely depends on the driven current frequency. The highest sensitivity (1580 %/A穖^-1) is obtained when the FeCo-based amorphous ribbon is annealed at 32 A/mm² for 10 min and then driven with an alterning current (AC) at the frequency of 350 kHz. The highly sensitive GMIES under the WMF may result from the multiple magnetic-anisotropic structure, which is induced by the temperature gradient produced during Joule-heating the ribbon.     

Highly sensitive giant magnetoimpedance in a solenoid containing FeCo-based ribbon

The highly sensitive giant magneto-impedance effect in a solenoid containing a magnetic core of Fe36Co36Nb4Si4.8B19.2(FeCo-based) ribbon under a weak magnetic field(WMF) is presented in this paper.The FeCo-based amorphous ribbon is prepared by single roller quenching and annealed with Joule heat in a flowing nitrogen atmosphere.The giant magnetoimpedance effect in solenoid(GMIES) profiles are measured with an HP4294A impedance analyzer.The result shows that the GMIES responds to the WMF sensitively(as high as 1580 %/A·m 1).The high sensitivity can be obtained in a moderate narrow range of annealing current density(30-34 A/mm 2) and closely depends on the driven current frequency.The highest sensitivity(1580 %/A·m 1) is obtained when the FeCobased amorphous ribbon is annealed at 32 A/mm 2 for 10 min and then driven with an alterning current(AC) at the frequency of 350 kHz.The highly sensitive GMIES under the WMF may result from the multiple magnetic-anisotropic structure,which is induced by the temperature gradient produced during Joule-heating the ribbon.     

整系数多项式因式分解的一种新方法

利用整系数多项式与正有理数的对应 ,将多项式因式分解通过对真分数序列筛选的办法求得因式 ,给出了整系数多项式因式分解的一种新方法 .     

大学物理实验教学内容与方法改革探索

面对科学技术的飞速发展和现代社会对人才的要求,针对现阶段大学物理实验教学中普遍存在的问题,结合我校在大学物理实验教学改革的实际情况,提供了一系列大学物理实验教学改革的新思路和新方法。     

油酸包裹对不同尺寸纳米α-Fe2O3晶体Morin相变影响的Mssbauer研究

用Mossbauer方法研究了冻油酸中的35nm与60nm均匀α－Fe2O3微晶的Morin相变温度，发现它比未包裹样品分别高了50K和24K。     

关于子式矩阵的行列式

讨论子式阵及伴随阵的行列式,得到了高阶伴随阵行列式的一般公式.我们的结果改进了文献中的相应结果.