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71.
研究q-玻色湮没算符高次幂(k≥3)的正交归一本征态的数学结构,在此基础上讨论了它们的数学性质及其q-压缩和振幅N次方压缩特性.发现它们能组成一个完备的希尔伯特(Hilbert)空间;且当k为偶数时,这些本征态均可存在振幅N次方压缩. 相似文献
72.
脉冲激光在有机分子材料中的共振传播 总被引:3,自引:3,他引:0
利用麦克斯韦-布洛赫耦合方程,研究了激光脉冲在4,4′-二甲氨基二苯乙烯分子材料中的共振传播,探讨了激光脉冲在传播中的时空演化情况.在数值计算中考虑了各种阻尼效应. 相似文献
73.
THE AMPLITUDE-N-TH POWERED SQUEEZING OF AN ELECTROMAGNETIC FIELD IN THE MULTIPHOTON JAYNES-CUMMINGS MODEL INTERACTING WITH THE SUPERPOSITION STATE 下载免费PDF全文
We have studied the properties of the amplitude-N-th powered squeezing of an elec-tromagnetic field in the k-photon Jaynes-Cummings model of an atom initially being in the ground state and coupling with the superposition state. The results show that, under the condition of n≥k, where n is the photon number of the superposition state, the field exhibits not only the amplitude-N = n-th powered squeezing but also the amplitude-N = (n/2)-th powered squeezing for even n. The variations of the amplitude-N-th powered squeezing of the field with the powers N and k are discussed. 相似文献
74.
从第一性原理出发利用密度泛函理论计算了共扼分子2氨基5硝基1,4二乙炔基4′苯硫醇基苯(2amino5nitro1,4diethyny4′benzenethiolbenzene)的电子结构,并利用前线轨道理论和微扰理论定量地确定了该分子与金表面的相互作用能常数.然后,利用弹性散射格林函数方法研究了该分子与金表面形成的分子线的伏安特性.计算结果表明,分子通过硫氢官能团可以很强地吸附于金表面上,形成以共价键为主的混合键,从而为电子的转移提供了通道.当外加偏压很低时,分子线的电流存在禁区,禁区的宽度约08eV.
关键词:
化学吸附
分子线
分子电子学 相似文献
75.
Time-dependent hybrid density functional theory in combination with Onsager reaction field model and super-molecular model has been applied to study solvent effects on the geometrical and electronic structures, as well as one/two-photon absorption properties, of 4-(N-(2-hydroxyethyl)-N-methyl)-amino-4'-nitroazobenzene. It is found that the short-range interaction has a large effect on the electronic structure of the solute molecule, namely, large red-shift of the maximum one-photon absorption is induced by hydrogen bonding. The solute molecule has a large two-photon absorption cross section, which is enhanced by the solvent effect. The computational results are in good agreement with measurements.[第一段] 相似文献
76.
以1,8-辛二硫醇分子为研究对象,在第一性原理基础上,利用弹性散射格林函数方法,研究了1,8-辛二硫醇分子在金原子团簇上不同取向对该分子结电输运特性的影响.计算结果表明,分子与金原子团簇表面之间方位角的不同会导致分子结构、电子结构的改变,从而影响分子体系的电输运特性.当1,8-辛二硫醇分子S-S轴线与金(111)面的法线成25°夹角时,所得到的电流-电压曲线与实验值符合较好. 相似文献
77.
78.
从第一性原理出发,采用杂化的密度泛函理论和弹性散射格林函数法,计算有机分子4,4'-二巯基二苯醚分子的电子结构并研究其电子输运性质.计算结果表明,电场对分子系统电子结构有明显的影响,电流、电导表现为非线性变化,与不考虑电场作用时相比,更为接近实验结果. 相似文献
79.
Theoretical Studies on One-photon and Two-photon Absorption Properties of Pyrene-core Derivatives 下载免费PDF全文
The analytic response theory at density functional theory level is applied to investigate one-photon and two-photon absorption properties of a series of recently synthesized pyrene-core derivatives. The theoretical results show that there are a few charge-transfer states for each compound in the lower energy region. The one-photon absorption properties of the five investigated compounds are highly consistent with those given by experimental measure-ments. The two-photon absorption intensities of the compounds are greatly enhanced with the increments of the molecular sizes, in which the two-photon absorption cross section of the four-branched compound is about 5.6 times of that of the mono-branched molecule. Further-more, it is shown that the two-photon absorption properties are sensitive to the geometrical arrangements. 相似文献
80.
The aggregation effects on the two-photon absorption properties of para-nitroaniline polymers by hydrogen-bond interactions 下载免费PDF全文
This paper has theoretically designed a series of
aggregate polymers on the basis of several para-nitroaniline
monomers by hydrogen-bond interactions. At the level of
time-dependent hybrid density functional theory, it has optimized
their geometrical structures and studied their two-photon absorption
(TPA) properties by using analytical response theory. The calculated
results exhibit that the aggregation effects not only bring out the
considerable red shift of the excited energies but also greatly
enhance the TPA intensities of the aggregate polymers in comparison
with the para-nitroaniline monomer. The aggregate configurations
also have an important influence on the TPA abilities of the
polymers; the trimer has the largest TPA cross section. The electron
transitions between the molecular orbits involving the strong TPA
excitations of the trimer are depicted to illuminate the
relationship between the intermolecular charge transfer and the TPA
property. 相似文献