以Nd改性CeO2-ZrO2固溶体助剂的研究

 用两种方法在贵金属三效催化剂的主要助剂CeO2－ZrO2固溶体中掺杂Nd进行改性,以提高催化剂的活性和热稳定性．方法1是采用硝酸钕溶胶浸渍CeO2－ZrO2固溶体的新方法,试图在固溶体粉体外层分别附上含Nd的物质．方法2为用改进的溶胶－凝胶法制备出均一相的含Ce,Zr和Nd的三组分超细固溶体．测定了样品的比表面积和储氧量,并对部分样品进行了XRD和H2－TPR表征．结果表明,用方法1制备的复合相超细粒子的热稳定性优于用方法2制备的均一相超细固溶体,且当Nd含量为7％时,储氧量最高、热稳定性最佳．将经方法1改性过的以及未经Nd改性的CeO2－ZrO2固溶体,分别用机械混合的方法加入γ－Al2O3粉体制成催化剂前体,并进一步制成含低含量Pt,Pd和Rh的贵金属催化剂．活性测试结果表明,对于新鲜催化剂,经Nd改性后CO,C3H6和NO起燃温度下降20～30℃．经850℃老化2h后,和未掺杂Nd的催化剂的起燃温度相比,NO的起燃温度稍有下降,C3H6的起燃温度相差不大,而CO的起燃温度有所升高．     

含铈、镧低贵金属含量三效催化剂的结构与性能

采用ＣｅＯ２和Ｌａ２Ｏ３的不同加入方式,制备了一系列以ＣｅＯ和Ｌａ２Ｏ３为助剂的低贵金属含量三效催化剂,用ＸＲＤ和ＸＰＳ对其结构进行了表征,并进行了孔结构测定。测试了样品上ＣＯ,Ｃ３Ｈ６和ＮＯｘ三效转化的温度－转化率曲线和Ｓ值－转化率曲线。结果表明：以机械混合加入ＣｅＯ２和Ｌａ２Ｏ３的样品抗烧结性能差,老化后在Ｓ≤１区的ＮＯｘ和Ｃ３Ｈ４转化率明显下降,但起燃温度并不高;     

Permanence and extinction analysis for a delayed periodic predator-prey system with Holling type II response function and diffusion

In this paper, it is studied that two species predator-prey Lotka-Volterra type dispersal system with delay and Holling type II response function, in which the prey species can disperse among n patches, while the density-independent predator species is confined to one of the patches and cannot disperse. Sufficient conditions of integrable form for the boundedness, permanence, extinction and the existence of positive periodic solution are established, respectively.     

Bounded traveling waves of the oceanic currents motion equations

The bifurcation methods of differential equations are employed to investigate traveling waves of the oceanic currents motion equations. The sufficient conditions to guarantee the existence of different kinds of bounded traveling wave solutions are rigorously determined. Further, due to the existence of a singular line in the corresponding traveling wave system, the smooth periodic traveling wave solutions gradually lose their smoothness and evolve to periodic cusp waves. The results of numerical simulation accord with theoretical analysis.     

Analysis of mathematics and dynamics in a food web system with impulsive perturbations and distributed time delay

In this paper, on the basis of the theories and methods of ecology and ordinary differential equation, a food web system with impulsive perturbations and distributed time delay is established. By using the theories of impulsive equation, small amplitude perturbation skills and comparison technique, we get the condition which guarantees the global asymptotical stability of the prey and intermediate predator eradication periodic solution. On this basis, we get that the food web system is permanent if some parameters are satisfied with certain conditions. In order to show that these conditions are effective, the influences of impulsive perturbations on the inherent oscillation and distributed time delay are studied numerically; these show rich dynamics, such as period-halving bifurcation, chaotic band, narrow or wide periodic window, chaotic crises. Moreover, the computation of the largest Lyapunov exponent shows the chaotic dynamic behavior of the model. Meanwhile, we investigate the qualitative nature of strange attractor by using Fourier spectra. All of these results may be useful in the study of the dynamic complexity of ecosystems.     

BaCeO3 钙钛矿型氧化物的储氮和抗硫性能研究

采用改进的溶胶 凝胶法制备了钙钛矿结构的BaCeO3 样品 ,在此基础上再用浸渍法制备了Pt/BaCeO3 、Rh/BaCeO3 、Pt Rh/BaCeO3 样品 ,并用机械混合γ Al2 O3 ,再浸渍贵金属的方法制备了Pt/BaCeO3 /γ Al2 O3 、Rh/BaCeO3 /γ Al2 O3 、Pt Rh/BaCeO3 /γ Al2 O3 样品 .储氮量 (NSC)结果表明 :对未加γ Al2 O3 的BaCeO3 来说 ,贵金属的加入反而使NSC减小 .加入贵金属催化剂的储氮量 (NSC)大小为 :Pt的最大 ,Rh的次之 ,Pt Rh的最小 .γ Al2 O3 的加入对BaCeO3 吸收NO和O2 没有影响 .而对于BaCeO3 /γ Al2 O3 样品 ,贵金属的加入使NSC值提高了 3倍以上 .讨论了贵金属加入到BaCeO3 /γ Al2 O3 样品中显著提高样品储氮能力的原因 .结合XRD结果表明 ,钙钛矿BaCeO3 相是Ba -Ce -O样品主要的NOx 储存活性中心 .NSC结果还表明 ,BaCeO3 和Pt/BaCeO3 催化剂在SO2 为≤ 0 .0 0 6 %时具有较好的抗硫性能 .而Pt/BaCeO3 /γ Al2 O3 催化剂不但具有较好的储氮能力而且具有更好的抗硫性能 .     

Preparation of orange-red fluorescent gold nanoclusters using denatured casein as a reductant and stabilizing agent,and their application to imaging of HeLa cells and for the quantitation of mercury(II)

We describe a method for the preparation of water-soluble gold nanoclusters (Au-NCs) from chloroauric acid using denatured-casein as both a reducing and stabilizing agent. The resulting Au-NCs were characterized by photoluminescence, UV–vis absorption, and X-ray photoelectron spectroscopies, and by transmission electron microscopy. The Au-NCs have an average diameter of 1.7 ± 0.2 nm and exhibit orange-red fluorescence emission peaking at 600 nm (with a Stokes’ shift as large as 237 nm), a quantum yield of 4.3 %, and good stability over the physiologically relevant range of pH values and ionic strength. Cytotoxicity studies showed the Au-NCs to display negligible effects in terms of altering cell proliferation or triggering apoptosis. Fluorescence imaging of HeLa cancer cells was accomplished by loading such cells with the Au-NCs. The fluorescence of the Au-NCs is found to be strongly quenched by Hg(II) ions, and thus the Au-NCs can be used for detecting and, possibly, imaging of Hg(II). An assay was worked out for the determination of Hg(II), and its limit of detection is 1.83 nM, which is 5.5 times lower than the maximum allowed concentration of Hg(II) in drinking water as defined by the US EPA.

Denatured-casein was firstly used as a reductant and stabilizing agent in facile preparation of orange-red fluorescent AuNCs for imaging of HeLa cells and for the quantitation of mercury(II)

     

Existence of Extremal Solutions for a Nonlinear Fractional <Emphasis Type="Italic">q</Emphasis>-Difference System

In this paper, we study the boundary value problem of a fractional q-difference system with nonlocal integral boundary conditions involving the fractional q-derivatives of the Riemann–Liouville type. Using the properties of the Green function, and monotone iterative method, the extremal solutions were obtained. Finally, an example is presented to illustrate our main results.     

硒化壳聚糖诱导NB4细胞凋亡及周期阻断作用

为研究硒化壳聚糖对NB4细胞的凋亡及周期阻断作用,用流式细胞法观察了药物对细胞的诱导凋亡及周期阻断作用。结果表明,硒化壳聚糖作用NB4细胞24 h,可剂量依赖性地诱导细胞凋亡并使G0—G1期细胞增多。提示硒化壳聚糖可诱导细胞凋亡,并对NB4细胞周期有特异性阻断作用。     

酱香型酒香气成分研究：1.珍酒,茅台酒空杯香分离及官能色谱探索

本文系统地研究了酱香型酒主体香的分离方法，摸索出“溶剂萃取－自然挥发－溶解”的酱香型酒空杯香的分离方法，首次从珍酒、茅台酒中分离出典型的空杯香。用在线色谱闻香系统研究了酱香型酒空杯香的化学成分，同时进行色谱测定及嗅闻。结果表明，空杯香是多种成分构成的复合香。