Impedance Characterization of Adsorption Process of Calmodulin on Au Substrate and its Combination with Ca~(2+)

Recently, the adsorption behavior of protein on solid substrate has attracted much attention for the reason that adsorption on a substrate is the first key step for other further electrochemical investigation1. Meanwhile the free adsorption could provide a relative well-ordered structure, with which some fundamental study could be carried out conveniently2. As we know, the electrochemical impedance spectroscopy (EIS) method has become one of the powerful techniques to detect the change of i…     

Synthesis and Electrochemical Property of Calcium Doped LiNi0.8Co0.2O2 Solid Solution

Today, batteries with high capacity, good cyclability, long life and environmental goodness are much required to meet some pressing demands of our modern society. In principle, lithium ion cells can satisfy these requirements1. But the properties of the cathode materials have limited the further development of the lithium ion cells. The studied cathode materials before were mainly LiCoO2, LiMn2O4, LiNiO2. The LiCoO2 has disadvantages including cost and environmental risk although it is…     

中国滇西腾冲新生代火山岩的成因

腾冲上新—全新世火山岩属高钾的钙碱性岩系,以强亏损高场强元素、富集大离子亲石元素和轻稀土为特征,明显具岛弧或活动陆缘属性。其形成与新特提斯演化有关,即:印度微大陆与东南亚微大陆间的洋盆于晚白垩—古新世向东消减,伴以岛弧形成,始新世开始印度板块与该岛弧碰撞;作为弧后盆地的安达曼海及内缅甸盆地于中新世晚期扩张。腾冲的独特之处是岛弧型火山活动迟后于消减作用。     

中国东南部新生代火山岩系——Ⅱ.微量元素地球化学

本文详细地讨论了新生代火山岩的微量元素地球化学特征。研究表明,中国东南部之下的上地幔,相对球粒陨石质地幔,富集强HYG元素,以及从沿海向内陆玄武岩浆源的深度变大。新生代玄武岩质火山作用发生于张裂的大陆边缘构造环境中。相反,以长英质为主的中生代火山岩喷发于活动大陆边缘的构造环境中。由超镁铁质岩包体推导的地温分布表明,中国东部新生代张裂作用主要受热地幔底辟作用所控制。     

Binding Affinity of Novel Cyclodextrin Dimers to Ethyl Orange

The interaction between ethyl orange (Eto, guest) and β-cyclodextrin dimers (1a～d, host) bridged with 2-t-butoxycarbonyl(Boc)-amino diacid was investigated. A remarkable synergic complexation of two cavities in host molecule was observed.     

Efficient Debromination of Vicinal a, b-Dibromo Carboxylic Acid Derivatives with the Sm/HOAc System

The chemistry of samarium (II) iodide (SmI2) is of current interest in organic synthesis. SmI2 has been developed as a powerful, versatile and ether-soluble single-electron reductant and many examples have been reported of its use in the reduction of various functional groups1. Though SmI2 is a useful reagent, storage is difficult because it is very sensitive to air oxidation. On the other hand, metallic samarium is stable in air and has strong reducing power (Sm3+/Sm=-2.41 V). These pr…     

Chemical Components of Helicia nilagirica Beed.I.Structure of Three New Flavonol Glycosides

Helicia nilagirica Beed. belongs to the plant of Proteaceae family. The seeds of the plant is for treatment of insomnia and neurasthenia in Jingpo nationality in Yunnan Province1. Helicid and helicidol were isolated from the seeds of the plant2,3, and the helicid was recorded in the Yunnan Pharmacopoea at the 1987 edition. The chemical constituents of the leaves of this plant has not been reported yet in the literature. This paper is concerning the study of the chemical component of the…     

Spherical foam growth in Al alloy melt

The ultra light metal structure, realizing the light-ness and multifunction of structural material, has a bright future in high-tech and civil fields and is be-coming one of the hotspots in developed countries in 21 century[1―8]. Preparing Al foam by mel…     

SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED PHENYLALANINE SCHIFF BASE COMPLEX OF Mn(Ⅱ) IN AEROBIC OXIDATION OF CYCLOHEXENE

1. INTRODUCTION The partial oxidation of alkenes (forming acids, aldehydes and alcohols) is of considerable interest to the chemical industry. In most cases, more than one oxygenated product is formed from a given starting material and all products are susceptible to complete oxidation to carbon dioxide and water [1]. As mimetic oxygen carrier or oxidation catalyst, metalloporphyrins have been widly studied [2~7]. Among the non-porphyrin systems, the manganese complexes of Schiff base are…