SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED PHENYLALANINE SCHIFF BASE COMPLEX OF Mn(Ⅱ) IN AEROBIC OXIDATION OF CYCLOHEXENE

1. INTRODUCTION The partial oxidation of alkenes (forming acids, aldehydes and alcohols) is of considerable interest to the chemical industry. In most cases, more than one oxygenated product is formed from a given starting material and all products are susceptible to complete oxidation to carbon dioxide and water [1]. As mimetic oxygen carrier or oxidation catalyst, metalloporphyrins have been widly studied [2~7]. Among the non-porphyrin systems, the manganese complexes of Schiff base are…     

A Theoretical Study on the Stereoisomerism in the Complex of Cucurbit[8]uril with 2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)naphthalene

Cucurbit[n]urils (CB [n]),macropolycyclic compounds self-assembled from an acid-catalyzed condensation of glycoluril and formaldehyde1, can form inclusion complexes with a number of organic substrates in water2. Usually, CB [6] is used in the studies because of its easy synthesis, and the driving forces for its binding are considered to be the hydrophobic effect and dipole-dipole interactions. CB[n] 1Very recently, Kim et al reported the synthesis of CB [5], CB [7], and CB [8]3. They fou…     

Hydrothermal Synthesis of Pb_(1-1.5x)La_xZr_(0.5)Ti_(0.5)O_3 (x = 0.01-0.06) Nanocrystallites

Lanthanum doped lead zirconate titanate (PLZT) ceramics display excellent electrooptic and photostriction properties because of the existence of cavities in the perovskite structure1-3. The PLZT powders are conventionally prepared by solid state reaction4-5, and the wet chemical methods such as sol-gel techniques are then introduced6-7. However, the homogeneity, morphology and size of the particles, which greatly affect the sinterability and the property of the resulting ceramics, are dif…     

Synthesis and Crystal Structure of N′-(4-fluorobenzylidene)-2-(1H-1,2,4-triazole-1-yl)acetohydrazide

IntroductionBoth triazole derivatives and Schiff base have beenreported to possess significant antifungal[1—3]and plantgrowth regulatory activities[4—6].Triazole drugs are alsovery common in the medical field,which has given animmense impetus to the res…     

Rayleigh and Hyper-Rayleigh Scatterings from the Nanometer SnO_2 Particle in Solution

Nano-materials have been extensively studied in the past[1]. The quantum effect makes the properties of nano-materials dif- ferent from that of bulk materials. A few of publications regard- ing the catalysis, electronic structure, and optics of the nanome…     

Flow Injection Analysis of Histidine with Enhanced Electrogenerated Chemiluminescence of Luminol

Histidine is one of the necessary basic amino acids in biological bases, which often controls the catalytic activity of enzymes and acts in holding the higher structure of proteins. Furthermore, it is also an important ingredient in pharmaceutical preparations used for treatment of hetpatosis and nephropathy. Therefore, the determination of histidine in biological fluids and pharmaceutical preparations is of great importance. Various methods have been proposed for the detection of histidine …     

联吡啶与铼、钌络合物的核磁共振谱分析

对2，2’—联吡啶—4，4’—二羧酸乙酯与过渡金属铼络合物(化合物1)和钌络合物(化合物2)的结构进行了核磁共振与电喷雾质谱(ESI—MS)的分析研究；利用^1H—^1H COSY、HSQC、HMBC等二维相关NMR谱淮确表征了化合物的结构，观测了远程偶合作用。     

The Electron Transfer Reaction between ρ-Nitrobenzoates and β-N, N-Dimethylaminonaphthalene

Photoinduced electron-transfer (PET) reactions are fundamentally important in biology and technology1,2. Because of the complexity of PET in biological systems, many simple compounds were synthesized to look into its detailed mechanism3. In previous papers, we reported the electron transfer reaction in the supramolecular systems assembled by mono-6-p-nitrobenzoyl-b-cyclodextrin 6 and naphthalene derivatives in aqueous solution4. In the present paper the intermolecular electron transfer from …     

New Thiophene Derivatives with Two-photon Excited Fluorescence

Organic molecules that can simultaneously absorb two or more photons in reaching theirexcited states have recently been the subject in various photon-electronic fields. Tomeet the criteria for various nonlinear optical applications, such as three-dimensionaloptical storage1 and up-converted lasing2, molecules with large two-photon absorption(TPA) cross-section σ are required and have been synthesized. These dyes generallybelong to the structural modes of D-π-D, A-π-A3 or D-π-A, where D…     

Exponential Synchronization of the Linearly Coupled Dynamical Networks with Delays

In this paper,the authors investigate the synchronization of an array of linearly coupled identical dynamical systems with a delayed coupling.Here the coupling matrix can be asymmetric and reducible.Some criteria ensuring delay-independent and delay- dependent global synchronization are derived respectively.It is shown that if the coupling delay is less than a positive threshold,then the coupled network will be synchronized.On the other hand,with the increase of coupling delay,the synchronization stability of the network will be restrained,even eventually de-synchronized.