化学蒸气发生-多通道原子荧光光谱法同时测定化探样品中的砷、锑、铋、汞

采用氢化物发生-四通道原子荧光光谱仪同时测定化探样品中砷、锑、铋和汞的含量。试样溶于盐酸-硝酸-水(3+1+4)的混合酸中,分取适量试液在盐酸(1+4)溶液和含硫脲10g·L-1的介质中预还原30min。用纯氩气作载气和屏蔽气,流量依次为300,900mL·min-1。仪器采用间歇流动进样方式,硼氢化钾溶液的质量浓度为15g·L-1。上述4种元素的质量浓度在一定范围内呈线性,检出限(3S/N)为0.031μg·L-1(砷)、0.028μg·L-1(锑)、0.024μg·L-1(铋)和0.004 8μg·L-1(汞)。应用此方法分析了化探样品,并用标准加入法对上述4种元素进行回收试验,测得回收率在95.4%~101%之间。     

2-甲基环戊酮离子前6个激发态的解离

用量子化学原理,CIS/6-31+G(d,p)方法研究了2-甲基环戊酮离子前6个激发态的解离过程,通过虚频的振动分析,计算其可能产物,寻求2-甲基环戊酮离子的解离通道和解离产物.     

Fe(100)表面Cu单层膜上CO的吸附,解离以及C-C偶合反应

采用密度泛函方法研究了Fe(100)表面Cu单层膜上CO的吸附,直接解离,氢助解离以及C-C偶合反应.相比洁净的Fe(100)表面,在Fe(100)的单层Cu膜上,CO的吸附和活化都减弱了.特别是,相比Fe(100)上CO的解离能垒1.08 eV,铜单层膜上CO解离能垒高达2.4 eV.在H原子共吸附的情况下,Fe(1...     

微管内气液两相流中液膜厚度的实验测量

微通道内气液两相流中气柱(plug bubble)与通道壁之间液膜厚度的实验测量,是微热管、微流动、微电子冷却以及气泡雾化等研究中普遍关注的问题.本文利用基于光学干涉和快速傅立叶变换的空间频谱分析方法,实验测量获取了含表面活性剂水中气柱在750μm 通道内运动时其与通道壁面之间的液膜厚度.实验结果表明:表面活性剂对液膜厚度的影响比较明显,即当表面活性剂浓度在一定范围内增大时,液膜厚度会减小;此外,当气柱运动速度在一定范围内增大时,液膜厚度也会减小.     

Study on resistance coefficient in compound channels

This paper presents a further study of the Manning and Darcy-Weisbach resistance coefficients, as they play a significant role in assessing the cross-sectional mean velocity, conveyance capacity and determining the lateral distribution of depth mean velocity and local boundary shear stress in compound channels. The relationships between the local, zonal and overall resistance coefficients, and a wide range of geometries and different roughness between the main channel and the flood plain are established by analyzing a vast amount of experimental data from a British Science and Engineering Research Council Flood Channel Facility (SERC-FCF). And the experimental results also show that the overall Darcy-Weisbach resistance coefficient for a compound channel is the function of Reynolds number, but the function relationship is different from that for a single channel. By comparing and analyzing the conventional methods with the experimental data to predict composite roughness in compound channels, it is found that these methods are not suitable for compound channels. Moreover, the reason why the conventional methods can not assess correctly the conveyance capacity of compound channels is also analyzed in this paper.The project supported by the National Natural Science Foundation of China (50279024), the National Key Basic Research and Development Program of China (973 Program) (2003CB415202) and the Specialized Research Fund for the Doctoral Program of Higher Education (20030610039)The English text was polished by Ron Marshall     

微通道换热器复合翅片的传热特性研究

研究了管径对微通道换热器传热性能的影响,并在百叶窗翅片的基础上开发了两种复合翅片。计算结果表明:在同一迎面风速下,1mm管径的百叶窗翅片Nu数分别比1.5mm和1.8mm管径的大4.8%~10.5%和24.6%~25.8%。JF值增加11%~15%和26%~28%,说明管径为1mm时微通道换热器的综合性能更好。与百叶窗翅片相比,百叶窗-三角翼复合翅片的换热系数减小1.9%~5.4%,但压降降低7.8%~12.7%,表明复合翅片是一种高效低阻翅片。     

循环风冷却式电抗器散热结构优化与分析

基于某密闭式大型电力电子设备中电抗器的散热需求,采用了蒸发冷却式的循环风冷散热系统;同时为电抗器设计了一种散热结构,用于提高电抗器的散热性能;并运用计算流体力学软件Ansys/icepak,对该结构进行了仿真优化;分析了循环风量以及该散热结构中的散热器通道宽度,导热片的数量、厚度、排列规律对电抗器散热性能的影响。研究结果表明,在散热器通道宽度为5mm、循环风量为800m3/h,采用不等间距的方式排列5块5mm的铜导热片时,该结构散热条件最佳;电抗器温升可以得到有效的控制,且温度分布均匀,满足系统的使用要求;同时也为该类电抗器的热设计提供了理论依据。     

纳米孔分析化学

源于自然界,服务于人类社会的纳米尺度装置包括生物及人工制备的纳米孔与纳米通道等。基于这些纳米尺度装置的分析化学简称纳米孔分析化学。本文对纳米孔分析化学的发展,特别是近年来在DNA测序、蛋白质分析的进展进行了综述,对于纳米孔分析化学发展的历史、基本分类、原理和应用作了介绍与展望。     

一种改进的汽车尾气检测装置的过滤清洁阀

公开号:CN202691221U公开日:2013.01.23申请人:骆旭山,陶元本实用新型公开了一种改进的汽车尾气检测装置的过滤清洁阀,包括连接于一体的内接口、阀体和外接口,     

Expression and Emmprin Regulated Function of Aquaporinl in SMMC7221 Cells

<正>Herein lie the crosstalk and regulation between AQP1 and Emmprin in SMMC7221 cells by means of siRNA technology and deglycosylation method.Firstly,HAQP1,rather than hAQP3,was selectively upregulated in SMMC7221 cells by FBS,flollowed by the upregulated expression of Emmprin.Emmprin gene silencing caused a remarkable change in the expression of AQP1 gene,just like its downstream gene,MMP9,meanwhile the water permeability and cell migration were also descended prominently.Furthermore,when treated with tunicamycin, Emmprin was deglycosylated,which made the expression of AQP1 significantly declined,followed by remarkably decreased cell membrane water permeability and cell migration.Taken together,all the data indicates the expression level and the modification of Emmprin by glycosylation are the key factors in regulating the expression of AQP1.