粒径可控球形TiO2的制备

在正丙醇与水的混合溶剂体系中以Ti(SO4)2为前驱物制备得到了粒径分布窄,分散性好的球形TiO2.对表面活性剂种类及用量,反应物浓度及焙烧温度和时间等影响因素进行了研究,结果表明,在正丙醇与水的体积比为1∶1的条件下,以聚乙烯吡咯烷酮(PVP)为表面活性剂,温度为70-90℃时可制得粒径分布窄、分散性好的高质量的球形TiO2颗粒.通过TG-DSC、SEM、XRD等分析表明,颗粒粒度大小及粒径分布受表面活性剂浓度和反应前驱物浓度影响大;物相间的转化主要由焙烧温度和时间来决定.并引入LaMer模型对颗粒形核、长大的过程进行理论说明.     

结合计算全息与混沌的彩色图像加密方法

针对现有彩色图像光学加密方法存在解密结果失真的问题,提出一种结合混沌运算与菲涅耳衍射全息的彩色图像单通道加密新方法.首次加密操作利用菲涅耳衍射将彩色图像RGB通道分量转换成一幅实值计算全息图;第二次加密操作是利用改造的Logistic混沌系统对计算全息图像素进行置换与扩散.结果 表明,本文方法除传统混沌系统密钥以外,菲涅耳衍射距离、参考光波长和入射角方向余弦作为关键密钥均可以增大密钥空间(约为10249),而且具有较小的密钥体积;解密图像的保真度高且相邻像素相关性、信息熵、像素数改变率和归一化改变强度等评价指标均接近理想值;密文图像的直方图平坦,灰度分布均匀,完全隐藏了原始彩色图像的灰度和色彩信息.     

High-humidity Sensor of a New Trinuclear Ti3-Oxo Cluster

Crystalline polyoxo-titanium clusters （PTCs）,as a molecular model of TiO₂ nanomaterials,have attracted unprecedented attention due to their designable structure,tunable band gap,catalysis,and photochromic properties.A new trinuclear Ti₃-oxo cluster,[Ti₃（μ₂-O）(μ₃-O)（abz）₆（OⁱPr）₂]·CH₃CN·H₂O （Ti3）,was synthesized by solvothermal method with a yield of 60%by using 4-aminobenzoic acid as liga...     

可调频高功率宽谱微波的产生和辐射

 设计了一种可调谐频率的高功率宽谱微波辐射装置,装置由可调谐长度的1/4波长低阻同轴谐振器、环形开关、电容耦合器和宽谱辐射天线组成,中心频率调谐为200～400 MHz。低阻传输线与环形开关构成1/4波长短路谐振器,它产生的宽谱微波振荡通过耦合器耦合到宽谱辐射天线上辐射,而耦合器由集中电容与分布电感组成,实现宽谱微波在频率调谐范围内以较为一致的耦合度提取微波能量。通过转动螺杆滑动安装在同轴谐振器内芯上的环形开关,达到改变谐振频率的目的。最后,将可调频宽谱辐射装置与输出电压为500 kV的Tesla变压器脉冲功率源联试,得到200～400 MHz宽谱微波辐射,辐射因子为95～130 kV,频谱百分比带宽为10%～30%。     

Low-overhead fault-tolerant error correction scheme based on quantum stabilizer codes

Fault-tolerant error-correction (FTEC) circuit is the foundation for achieving reliable quantum computation and remote communication. However, designing a fault-tolerant error correction scheme with a solid error-correction ability and low overhead remains a significant challenge. In this paper, a low-overhead fault-tolerant error correction scheme is proposed for quantum communication systems. Firstly, syndrome ancillas are prepared into Bell states to detect errors caused by channel noise. We propose a detection approach that reduces the propagation path of quantum gate fault and reduces the circuit depth by splitting the stabilizer generator into X-type and Z-type. Additionally, a syndrome extraction circuit is equipped with two flag qubits to detect quantum gate faults, which may also introduce errors into the code block during the error detection process. Finally, analytical results are provided to demonstrate the fault-tolerant performance of the proposed FTEC scheme with the lower overhead of the ancillary qubits and circuit depth.     

Quantum multicast communication over the butterfly network

We propose a scheme where one can exploit auxiliary resources to achieve quantum multicast communication with network coding over the butterfly network.In this paper,we propose the quantum 2-pair multicast communication scheme,and extend it to k-pair multicast communication over the extended butterfly network.Firstly,an EPR pair is shared between each adjacent node on the butterfly network,and make use of local operation and classical communication to generate entangled relationship between non-adjacent nodes.Secondly,each sender adds auxiliary particles according to the multicast number k,in which the CNOT operations are applied to form the multi-particle entangled state.Finally,combined with network coding and free classical communication,quantum multicast communication based on quantum measurements is completed over the extended butterfly network.Not only the bottleneck problem is solved,but also quantum multicast communication can be completed in our scheme.At the same time,regardless of multicast number k,the maximum capacity of classical channel is 2 bits,and quantum channel is used only once.     

铜(Ⅱ)-硫氰酸盐-乙基紫-微乳液分光光度法测定钢样中的微量铜

在非离子型微乳液(OP/n-C5H11OH/n-C7H16/H2O)存在下,Cu2+与硫氰酸盐形成络阴离子[Cu(SCN)4]2-,在pH 3.6乙酸盐缓冲溶液中,该络阴离子再与乙基紫(EV)形成吸附型离子络合物,该络合物的组成为[Cu(SCN)4]2-:EV=1:2,最大吸收波长为660nm,表观摩尔吸光系数ε660为1.08×l05L.mol-1.cm-1,Cu2+含量在1.7～18.0μg/50 mL范围内符合比尔定律,检出限为0.5μg/50 mL,用该方法测定了钢中的铜,相对标准偏差小于2%。     

制备条件对Cu2S光阴极性能的影响

制备了Cu2S纳米材料,研究了制备条件对Cu2S形貌及催化多硫离子还原性能的影响,并将最优条件下制备的Cu2S作为光阴极应用在量子点敏化太阳能电池上.在Cu2S的制作过程中,盐酸对铜片的预处理及铜片和多硫化钠溶液的反应是影响Cu2S性能的两个重要过程.研究结果表明:得到的Cu2S为纳米片组成的花瓣状结构,且随着盐酸浓度的增大和处理时间的延长,表面逐渐变得粗糙和多孔,这有利于增加其表面积,因此Cu2S和多硫电解质之间的界面电荷转移电阻逐渐减小.另外,铜和多硫化钠溶液反应生成Cu2S是一个非常快的过程,反应时间不宜过长,否则Cu2S膜会断裂.在保证Cu2S具有良好催化性能的前提下优化得到的最经济省时的制备条件是:盐酸的浓度为30%,预处理时间为40min,和多硫化钠反应的时间为10s.用此条件下制备的Cu2S作为光阴极组装成量子点敏化太阳能电池达到了4.01%高的光电转化效率.     

TixV1-xO2薄膜的光学及相变特性

采用射频磁控溅射方法,在c-Al2O3(0001)基底上制备了不同钒钛比例的TixV1-xO2(0≤x≤1)薄膜,利用X射线衍射(XRD)、拉曼(Raman)光谱、紫外-可见-近红外(UV-Vis-NIR)光谱对薄膜结构及光学性能进行测试分析,计算薄膜的太阳能智能调节率和光学带隙.实验结果及分析表明:随着Ti含量的增加,薄膜的红外调节特性和热滞特性逐渐减弱直至消失;薄膜样品的光学带隙随着Ti含量的增加而变宽,光响应范围发生蓝移;其光学带隙随着V含量的增加而变窄,光响应范围发生红移.     

高功率超宽谱双反射面天线优化设计与实验

对高功率超宽谱双反射面天线系统进行了优化改进设计,兼顾辐射性能、馈入反射和功率容量。采用沿能流线设计的粗胖实体结构代替板状TEM喇叭极板结构,增加低频电流的回流通道,从而改善天线馈入反射特性。将副反射面设计为尼龙箱体内、外两部分,使其与尼龙箱体之间的连接螺钉不再突出于高压电场中,优化后最大场强下降了约70%,功率容量达到59 GW,通过Taguchi优化算法对组合馈源喇叭结构进行整体优化,天线辐射因子rE(辐射场峰值与观测点距离乘积)提高了1.2倍。优化后的天线系统进行了高功率实验,实验结果表明:天线系统功率容量达到30 GW,辐射因子超过8 MV。