一种红光发射的粘度荧光探针

以三苯胺和苯并噻唑盐为原料,设计合成了一种具有红光发射特性的D-π-A型荧光粘度探针N-乙酸乙酯基-2-(4-甲酸甲酯基三苯胺-4'-乙烯基)苯并噻唑六氟磷酸盐(L),运用现代分析测试手段进行了系统地表征。 研究结果表明,探针L的最大发射波长为630 nm,能有效地降低生物背景,提高生物成像的信噪比。 该探针对粘度有很好的荧光响应,其荧光强度比值(I/I₀)的对数与粘度的对数呈现很好的线性关系(R²=0.9934)。 此外,探针L对极性的敏感性小,且荧光信号不受生物分子的干扰。 生物学研究结果表明,探针L具有低的细胞毒性,可应用于细胞内微环境粘度的荧光成像。     

四卤化锰(Ⅱ)配合物的结构调控及力致发光性能

力致发光是一种力刺激诱导的发光现象。由于其独特的发光方式,使得力致发光材料在结构损伤检测、压力传感、显示和安全标记等方面展现出了巨大的应用价值。目前已报道的力致发光材料大多基于无机材料体系,而有机力致发光材料体系相对较少,并且人们对其发光机理的认识仍不清晰。在本文中,我们发现锰(Ⅱ)配合物[BPP]2[Mn Br4]具有力致发光特性,并在此基础上设计合成了一系列具有力致发光性质的四卤化锰(Ⅱ)配合物。改变有机阳离子配体或者卤素阴离子可对其光物理性质进行有效调控。固态下,这些锰(Ⅱ)配合物均显示出了较强的光致发光现象,同时表现出了明显的力致发光特性。晶体结构分析表明,分子内/分子间强的C―H…X (X=Br或Cl)相互作用对锰(Ⅱ)配合物的力致发光起到了至关重要的作用,它可在较大程度上降低由分子振动和旋转造成的能量损失。本工作将为力刺激响应型材料体系的拓展提供一定的参考价值。     

A1/Ti/4H-SiC Schottky barrier diodes with inhomogeneous barrier heights

This paper investigates the current-voltage （I-V） characteristics of Al/Ti/4H-SiC Schottky barrier diodes （SBDs） in the temperature range of 77 K-500 K, which shows that Al/Ti/4H SiC SBDs have good rectifying behaviour. An abnormal behaviour, in which the zero bias barrier height decreases while the ideality factor increases with decreasing temperature （T）, has been successfully interpreted by using thermionic emission theory with Gaussian distribution of the barrier heights due to the inhomogeneous barrier height at the A1/Ti/4H-SiC interface. The effective Richardson constant A＊ = 154 A/cm2 . K2 is determined by means of a modified Richardson plot In（I0/T2） - （qσ）2/2（κT）2 versus q/kT, which is very close to the theoretical value 146 A/cm2 · K2.     

Theoretical study of photon emission from single quantum dot emitter coupled to surface plasmons

Motivated by the recent pioneering advances on nanoscale plasmonics and also nanophotonics technology based on the surface plasmons (SPs), in this work, we give a master equation model in the Lindblad form and investigate the quantum optical properties of single quantum dot (QD) emitter coupled to the SPs of a metallic nanowire. Our main results demonstrate the QD luminescence results of photon emission show three distinctive regimes depending on the distance between QD and metallic nanowire, which elucidates a crossover passing from being metallic dissipative for much smaller emitter-nanowire distances to surface plasmon (SP) emission for larger separations at the vicinity of plasmonic metallic nanowire. Besides, our results also indicate that, for both the resonant case and the detuning case, through measuring QD emitter luminescence spectra and second-order correlation functions, the information about the QD emitter coupling to the SPs of the dissipative metallic nanowire can be extracted. This theoretical study will serve as an introduction to understanding the nanoplasmonic imaging spectroscopy and pave a new way to realize the quantum information devices.     

Above-threshold detachment of negative ions by circularly polarized few-cycle laser fields

In accordance with nonperturbative quantum scattering theory,we investigate photoelectron angular distributions(PADs) from above-threshold detachment(ATD) of negative ions irradiated by circularly polarized few-cycle laser fields.Electrons ejected on the polarization plane demonstrate distinct anisotropies in angular distributions which distinctly vary with the carrier-envelope(CE) phase.The anisotropy is caused by interference between transition channels;it also depends strongly on laser frequency,pulse duration,and kinetic energy of photoelectrons.Optimal emission of photoelectrons,which varies with CE phase,makes it possible to control photoelectron motion.     

Transmission-mode GaN photocathode based on graded Al_xGa_(1-x)N buffer layer

We create a GaN photocathode based on graded Alx Ga1-x N buffer layers to overcome the influence of buffer-emission layer interface on the photoemission of transmission-mode GaN photocathodes.A gateshaped spectral response with a 260-nm starting wavelength and a 375-nm cut-off wavelength is obtained.Average quantum efficiency is 15% and short wavelength responses are almost equivalent to long wavelength ones.The fitted interface recombination velocity is 5×104 cm/s,with negligible magnitude,proving that the design of the graded buffer layers is efficient in obtaining good interface quality between the buffer and the emission layer.     

爆炸复合1Cr13Mo/45钢连铸辊工艺

鉴于目前连铸辊制造工艺存在的不足,以爆炸复合法制造1Cr13Mo/45钢复合轧辊,并以爆炸复合工艺为研究对象,采用超声波探伤和金相观察等方法,研究药厚和间隙大小对复合界面波形的影响.结果表明:药厚一定的情况下,间隙对复合轧辊界面波形的影响较大;而在间隙一定的情况下,药厚对复合轧辊界面波形的影响不明显.通过实验,获得了该...     

应用声发射技术的钢筋与混凝土粘结滑移特性研究

为研究钢筋与混凝土间的粘结滑移特性,分别对不同粘结长度的钢筋混凝土试件进行了拉拔试验,同时对粘结长度相同而钢筋外形不同的试件进行了比较试验.利用声发射技术采集相应波形信号,并对采集信号进行了小波去噪和Gabor小波时频分析.结果显示,各试件受力全过程均可分为完全粘结、局部脱粘、非线性滑移及残余粘结四个阶段;不同粘结长度...     

等离子喷涂铁基涂层的疲劳磨损裂纹行为

采用等离子喷涂制备了铁基涂层,使用球盘式疲劳磨损试验机进行涂层的疲劳磨损试验,利用声发射技术在线判断涂层开裂,并通用透射电子显微镜（TEM）分析了试验前后涂层内部微观结构,研究了喷涂层疲劳磨损裂纹的扩展行为。结果表明：制备的涂层致密,结合状态良好,主要相为铁素体,同时存在大量的非晶-纳米晶相,利用声发射技术能够表征涂层的临界失效状态,其内部疲劳磨损裂纹主要以韧性穿晶断裂的形式扩展。