首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   205篇
  免费   37篇
  国内免费   36篇
化学   39篇
晶体学   2篇
力学   2篇
数学   127篇
物理学   108篇
  2022年   3篇
  2021年   3篇
  2020年   4篇
  2019年   4篇
  2018年   10篇
  2017年   7篇
  2016年   5篇
  2015年   3篇
  2014年   6篇
  2013年   26篇
  2012年   4篇
  2011年   13篇
  2010年   10篇
  2009年   14篇
  2008年   10篇
  2007年   19篇
  2006年   15篇
  2005年   12篇
  2004年   12篇
  2003年   17篇
  2002年   19篇
  2001年   11篇
  2000年   8篇
  1999年   9篇
  1998年   8篇
  1997年   4篇
  1996年   5篇
  1995年   3篇
  1994年   3篇
  1993年   1篇
  1992年   2篇
  1991年   2篇
  1989年   2篇
  1987年   1篇
  1981年   1篇
  1978年   1篇
  1977年   1篇
排序方式: 共有278条查询结果,搜索用时 15 毫秒
61.
62.
The concept of the time-independent correlators for the even- and odd-frequency pairing states that can be defined for both bosonic and fermionic quasiparticles is proposed. These correlators explicitly capture the existence of two distinct classes of pairing states and provide a direct probe of the hidden Berezinskii order. This concept is illustrated in the cases of pairings for Majorana fermions and quasiparticles in Dirac semimetals. It is shown that the time-independent correlator is able to effectively capture the energy scale relevant for pairing.  相似文献   
63.
A series of linear carboxylic acids containing diacetylenic units at different positions along the chain (C12H25(C≡C)2(CH2)nCOOH, n=7–11) were vacuum-deposited on clean silica substrates. The morphologies of the initial films after UV irradiation were studied. A clear odd–even effect on the morphology of the initial film was observed in that, depending on the spacer length between the diacetylenic unit and carboxyl head group, rings or dendrites of acid dimer layers were obtained. A molecular dynamic simulation of the aggregation process suggests that two competing intermolecular interactions and thus aggregation directions are involved and modulated by the odd or even carbon chain length. Further modulation of the interaction by substitution of a phenyl group at the terminus of the chain or by changing the carboxyl head group to an amidobenzoic acid head group led to a similar odd–even effect but with different dimensions or trends, which can be rationalized similarly. These results give the opportunity to create aligned conjugated polymer chains of different dimensions through self-assembly for applications in molecular/organic electronics.  相似文献   
64.
讨论 Weierstrass逼近定理的应用 .运用 Weierstrass逼近定理 ,我们对于连续偶函数和连续奇函数的性质进行了进一步的刻划 .  相似文献   
65.
于肇贤  张德兴 《光子学报》1995,24(3):246-248
研究结果表明,偶q相干态呈现振幅立方压缩性质;奇q相干态不呈现振幅立方压缩性质。  相似文献   
66.
不饱和链烃分子结构与沸点的关系   总被引:7,自引:0,他引:7  
曹晨忠  袁华 《有机化学》2002,22(5):354-363
在分子图的基本结构要素的基础上,提出了三个新的拓扑指数:顶点度-距离 指数(VDI),边度-距离指数(EDI)和奇偶指数(OEI),并用这些指数对C2- C20的150个不饱和链烃(包括烯烃、炔烃及烯炔)的沸点(bp)进行相关分析,得 到如下回归方程:ln(795-bp)=6.935044-0.373392EDI^1/5-3.900564×10^- 2OEI+6.396343×10^-3VDI(F=10539.14,r=0.9977,s=6.24),该回归模型对不饱和 链烃的沸点具有较好的估算和预测能力,表明本文所提出的三个拓扑指数具有良好 的结构-性质相关性。  相似文献   
67.
Biomimetic polyelectrolyte of Dopa modified poly(acrylic acid) (PAADopa) was synthesized taking advantage of Dopa, the major unit of marine adhesive proteins. Zinc crosslinked PAADopa (PAADopa‐Zn) were formed at acidic pH for more compact structure and assembled with the positively charged polyethylenimine (PEI) to build robust polyelectrolyte multilayers at high salt concentration. Effects of pH, crosslinking degree, and salt concentration on polymer structure, film building process, and morphology were investigated, respectively. An “odd‐even” effect was observed by quartz crystal microbalance with dissipation and AFM in the presence of zinc ion, which becomes more obvious with an optimum crosslinking degree (Zn/Dopa = 2.0) under high salt concentration (0.6 M NaCl). It indicates the different swollen properties of PEI chain and PAADopa‐Zn complexes during the layer‐by‐layer building process under optimum crosslinking degree of PAADopa‐Zn at high salt concentration. Such odd‐even phenomenon of the biocompatible system is of critical importance for understanding the mechanism of layer formation and film structures. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 245–255  相似文献   
68.
We determine the structure of -free graphs with n vertices and minimum degree larger than : such graphs are homomorphic to the graph obtained from a -cycle by adding all chords of length , for some k. This answers a question of Messuti and Schacht. We deduce that the homomorphism threshold of -free graphs is 1/5, thus answering a question of Oberkampf and Schacht.  相似文献   
69.
Eleven members of the homologous series of liquid crystal dimers, the α,ω-bis(4-cyanobiphenyl-4′-yl) alkanedioates, have been synthesised and their transitional properties characterised. These dimers consist of two cyanobiphenyl units connected by an alkyl spacer attached via ester linkages. All eleven members exhibit exclusively nematic behaviour. The nematic–isotropic transition temperatures, TNI, and associated entropy changes, ?SNI/R, exhibit pronounced alternations as the length and parity of the spacer is varied; this is characteristic behaviour of liquid crystal dimers. The transitional properties of the ester-linked dimers are compared with the corresponding materials having either ether, methylene or carbonate linkages between the spacer and mesogenic units. For short spacer lengths and both odd- and even-membered dimers, the ester-linked materials show the highest values of TNI and the methylene-linked the lowest. For longer spacer lengths, TNI of the carbonate-linked dimers fall between those of the corresponding ester- and ether-linked dimers. The ether-linked materials show the largest alternation in ?SNI/R on varying spacer length and the carbonate-linked dimers the lowest. This behaviour is interpreted in terms of the molecular geometry and it is suggested that the ether- and ester-linked odd-membered dimers have rather similar shapes. A phase diagram constructed using binary mixtures of the pentyl member of this ester-linked series and the known twist-bend nematogen, 1,7-bis(4-cyanobiphenyl-4′-yl)heptane (CB7CB), is presented. The twist-bend nematic–nematic transition temperature of the mixtures shows a striking convex curvature as the concentration of CB7CB is decreased, and so it is not possible to estimate a virtual twist-bend nematic–nematic transition temperature for the ester-linked material.  相似文献   
70.
The high-spin states in 128I have been studied by using in-beam γ-ray spectroscopy with the 124Sn(7Li,3n)128I reaction at beam energies of 25, 28 and 42 MeV. A new level scheme including 20 new levels and 27 new γ-transitions for 128I has been established preliminarily.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号