Li and Nb codoping in dielectric properties and phase transitions of KTaO3: Reentrant dipolar glass and long-range dipole ordering

Abstract

The highly polarizable perovskite-type oxide, KTaO₃ doped simultaneously with Li⁺ and Nb⁵⁺ (K_1?xLi_xTa_1?yNb_yO₃, KLTN), reveals unexpected properties and ordering effects. Studies of the dielectric permittivity ?'(T, f) (10—300K, 100Hz-1 MHz) for x = 0.0014 and y = 0.024 show collective dipolar ordering effects with a transition from paraelectric into a mixed phase (coexisting dipole-glass-like and long-range ordered ferroelectric phases) taking place near 39 K. At 15 K another phase transition into a reentrant dipolar glass-like state is observed. Such a sequence of transitions and the existence of a reentrant glass state are unknown for electrical dipolar systems.     

Dipole solitons in an optical lattice with longitudinal modulation

In this paper, we numerically demonstrate the (1+1)-dimensional dipole solitons can exist in a new Kerr-type optical lattice with longitudinal modulation that fades away and boosts up alternately. The solitons whose two dipoles simultaneously located at one lattice site and at two adjacent lattice sites are investigated, respectively. The results show that, in the two cases, the dipole solitons can be stably trapped in this kind of lattice by properly adjusting lattice parameters and soliton parameters when the repulsive force of dipoles balances the centripetal force resulting from the lattice potential effect on dipole solitons. In addition, the trapping of dipole solitons with an incident angle or the initial center position is discussed.     

Macroscopic far-field observation of the sub-wavelength near-field dipole vortex

The energy flow lines of the radiation emitted by a rotating electric dipole moment have a vortex structure near the source. The spatial extend of this vortex is well below an optical wavelength. This near-field vortex has a macroscopic effect which could be observed in the far field.     

光学偶极阱中铷原子5S_(1/2)及5P_(3/2)态的AC Stark频移

基于二能级模型和多能级模型,分析计算了由强聚焦高斯光束形成的光学偶极阱中87Rb原子5S1/2态和5P3/2态的AC Stark频移。基于多能级模型,针对在852 nm高斯激光束强聚焦所形成的87Rb原子远失谐光学偶极阱中进行偏振梯度冷却的情形,计算了冷却循环跃迁(5S1/2F=2-5P3/2F′=3)的频移量,结果显示频移对molasses冷却过程产生了重要的影响。同时,计算了5S1/2|F=2,mF=±2〉态和5P3/2|F′=3,mF=±3〉态的AC Stark频移随光学偶极阱激光波长的变化情况,发现在红失谐情况下,对于87Rb原子5S1/2-5P3/2态跃迁不存在魔数波长。     

FAIR收集环二极超导磁体外杜瓦泄放系统的概念设计

对FAIR(Facility for Antiproton and Ion Research)收集环-CR(Collector Ring)二极超导磁体外杜瓦的超压泄放系统进行了概念设计,给出了爆破片式的泄放系统结构,并基于ANSYS的结构分析初步确定了爆破片的结构参数;以及通过ANSYS对波纹管和外杜瓦进行了结构分析,分析结果表明波纹管和外杜瓦在超压状态下安全。文中的设计和分析研究,为外杜瓦的工程设计提供了有益的参考。     

Analysis and Verification on the Chain-like Model with Normal Distribution of Magnetorheological Elastomer

在磁流变弹性体链化模型的基础上,引入斜链夹角的正态分布,采用偶极子法从理论上分析了诸多因素对磁流变弹性体磁致剪切模量的影响,包括颗粒链的初始倾斜角、外加磁场强度、剪应变大小等,并进行了实验验证.     

边界层转捩区声辐射的预报方法研究

对Lighthill剪切应力脉动模型和Liepmann位移厚度脉动模型进行了讨论,在此基础上,本文提出利用Krane偶极子声源模型对Liepmann单极子声源模型进行改进。数值计算结果表明:作为偶极子声源的Lighthill理论剪切应力脉动模型,预报的噪声级偏低;而作为单极子声源的Liepmann模型,预报的噪声级又偏高;本文提出的两种改进模型预报的噪声级则与Lauchle实验值的一致性较好。     

强外电场作用下二甲基硅酮的分子结构和激发态

The ground states of dimethyl siloxane under different intense electric fields ranging from - 0. 04 to 0. 04 a. u. are optimized using density functional theory DFT / B3P86 at 6-311 ++ G（d,p）level. The excitation energies and oscillator strengths under the same intense applied electric fields are calculated employing the revised hybrid CIS-DFT method. The result shows that the electronic state,molecular geometry,total energy,dipole moment and excitation energy are strongly dependent on the field strength and behave asymmetry to the direction of the applied electric field. As the electric field changes from - 0. 04 to 0. 04 a. u. ,the bond length of Si-O increases whereas the bond length of Si-C decreases because of the charge transfer induced by the applied electric field. The dipole moment of the ground state decreases linearly with the applied field strength. However,the dipole moment of molecule changes from positive to negative as the inverse electric field increase to - 0. 03 a. u. Further increase of the inverse electric field results in an increase of the total energy of the molecule. The dependence of the calculated excitation energies on the applied electric field strength is fitting well to the relationship proposed by Grozema. The excitation energies of the first five excited states of dimethyl siloxane decrease as the applied electric filed increases because the energy gap between the HOMO and LUMO become close with the field,which shows that the molecule is easy to be excited under electric field and hence can be easily dissociated.     

外电场作用下三元环状水分子团簇的特性研究

The influence of an external field on the ground states energy and dipole moment of the cyclic water trimer is investigated. Employing the Hartree-Fork method with basis sets 3-21G. The field-induced H-F force including the internal and external forces and clusters equilibrium structures under balance of this force are analyzed. The external field is varied in the 0.001~0.01 a.u. range. It is shown that the magnitude of the external electric field has important effects on these characteristics of the cyclic water trimer. The energy was found to decrease and the dipole moment to increase with the increasing external field. The change of the electronic population of every atom leads the electrostatic field to vary accordingly.     

Dipole defects in BeO

Thermally Stimulated Depolarization Currents (TSDC) technique was applied to study the effects of thermal treatments and gamma irradiation in the formation, aggregation and destruction processes of dipole defects in beryllium oxide (BeO). In this work, a TSDC dipole peak was observed at 350 K that was assigned to impurity-vacancy complexes. The TSDC peak presents a linear dependence with the Polarization Voltage (V_P), typical behaviour of defects with dipole origin. Thermal treatments of 1 h were performed between 400 and 900 °C and a decay in the peak intensity was observed. After the gamma irradiation of the thermal treated samples a restoration tendency of the TSDC peak was observed.