生物高分子-氧化石墨烯三维多功能复合凝胶的制备及其血液净化性能

以生物高分子(壳聚糖、白蛋白、脱氧核糖核酸)为交联剂与氧化石墨烯片层进行三维自组装,冻干后得到生物高分子-氧化石墨烯复合凝胶。通过扫描电镜、原子力显微镜、纳米粒度分析仪等分析其物化性能。结果表明:生物高分子成功组装到氧化石墨烯片层上,并形成三维多孔结构,制备的凝胶显示出极好的血液相容性,有效抑制了红细胞的溶血现象,对阳离子毒性分子及重金属离子有较高的吸附量。     

A Note on Nonclassical Symmetries of a Class of Nonlinear Partial Differential Equations and Compatibility

The nonclassical symmetries of a class of nonlinear partial differential equations obtained by the compatibility method is investigated. We show the nonclassicaJ symmetries obtained in [J. Math. Anal. Appl. 289 （2004） 55, J. Math. Anal. Appl. 311 （2005） 479] are not all the nonclassical symmetries. Based on a new assume on the form of invariant surface condition, all the nonclassical symmetries for a class of nonlinear partial differential equations can be obtained through the compatibility method. The nonlinear Klein-Gordon equation and the Cahn-Hilliard equations all serve as examples showing the compatibility method leads quickly and easily to the determining equations for their all nonclassical symmetries for two equations.     

一个解决声纳系统同频干扰的新思路

多平台联合作战将是未来海上作战的重要形式之一,多部主动声纳的同时存在使声兼容问题十分突出。由于友舰直达波经历的是单程传播,其强度往往比经历了双程传播的目标回波大的多。通过波形设计可以获得相关系数小的声纳波形,虽然可以从一定程度上缓解声兼容问题,但由于获得的增益有限,并不能从根本上解决这一问题。本文通过对常规检测器的修正,引入能量归一化的概念,有效地消除了能量对检测器的影响,从而解决了这一问题。同时本文还提出了与现有声纳信号处理体系相兼容的频域实现方法,使该算法在工程上的实现成为可能。计算机仿真证明,这一方法是正确有效的。     

Engineering of the Filler/Polymer Interface in Metal–Organic Framework‐Based Mixed‐Matrix Membranes to Enhance Gas Separation

Traditional films cannot fully adapt to industrial applications and to intensified processes. Advanced mixed‐matrix membranes comprising metal–organic frameworks (MOF) embedded in a polymer matrix have been developed with the goal of breaking the trade‐off effect of traditional polymer membranes and achieving separation performance beyond Robeson's upper limit. The key challenges in the fabrication of MOF‐based mixed‐matrix membranes are an enhancement in compatibility between the inorganic filler and the polymer matrix, elimination of the irregular morphology and non‐selective interfacial defects, and further improvement in the gas‐separation performance. This review summarizes the recent advances in protocols and strategies in terms of designing interfacial interactions to enhance the MOF/polymer interface compatibility. This review aims at providing some meaningful insights into preparing MOF‐based mixed‐matrix membranes targeting ideal interfacial morphology and leading to excellent gas‐separation performance.     

机载多天线系统电磁兼容性研究

为了在有限计算机资源条件下快速解决机载平台中多天线系统的电磁兼容(EMC)问题,基于电场积分方程(EFIE),实现自动分层的多层快速多极子方法(MLFMA).针对天线问的近场耦合特性,采用任意天线间的隔离度代替传统隔离度,使得隔离度计算结果更加合理.同时采用BiCGStab(l)结合近场预条件方法进行求解,进一步提高MLFMA的综合效率.最后实例计算并分析波音747飞机模型上多根超短波天线的辐射方向图和宽频带内天线间的隔离度.数值结果表明方法准确有效.     

换热器与相变材料的兼容性研究进展

相变材料是一类以潜热实现能量存储释放的储能材料,由于其在相变温度附近具有很大的储热密度,相变材料可以被用于建筑控温、太阳能热发电和高温传热蓄热等应用中。 换热器是相变储能设备的重要组成部分,可以将热量在供需两端进行传递和转移,保障需求一方的使用,随着相变材料研究的不断深入及其工程应用的广泛普及,换热器已在众多相变储能项目中发挥了重要的枢纽作用。 为了保证换热器的使用性能,需要对换热器在相变材料中的防腐蚀性进行全面的分析。 本文总结了大量国内外的文献,分析不同成分的相变材料对换热器材料的腐蚀性,为换热器材料的选择提供了参考。     

聚(ε-己内酯-L-丙交酯)无规共聚物与聚乳酸共混材料的制备与性能

通过开环聚合,合成不同比例的ε-己内酯(ε-CL)与L-丙交酯(L-LA)的无规共聚物P(CL/LLA)。 将上述共聚物P(CL/LLA)与聚乳酸(PLLA)共混,制备了PLA/P(CL/LLA)共混材料。 并对其相容性、热性能、力学性能进行了研究。 结果表明,共聚物P(CL/LLA)与PLA相容性与共聚物中LA单元含量和链段的平均长度有密切关系,P(CL/LLA)中LA链段平均长度达到3.4以上时,可以与PLA很好的相互作用。 同时共聚物P(CL/LLA)中-CL-链段有很好的柔性,可以很好的改善PLLA的韧性,使PLLA材料的断裂伸长率达到500%以上。     

Effect of the degree of crosslinking on the interfacial layer structure of poly(vinyl chloride) dispersed with crosslinked poly(n-butyl methacrylate) particles

The interfacial layer structure of a model incompatible polymer blend system was analyzed using ¹H pulse nuclear magnetic resonance (pulse NMR) spectroscopy. Non-crosslinked and crosslinked poly(n-butyl methacrylate) particles with a mean size of ca. 0.9 μm were prepared by seeded emulsion polymerization, and the degree of crosslinking was varied. The particles were powdered using a freeze-dry method and dispersed in poly(vinyl chloride) by melt blending. Dynamic mechanical analysis indicated that the non-crosslinked particles were completely compatible. In contrast, mutual diffusion of the polymer chains in the crosslinked particles was restricted within the particle/matrix interfacial layer. As a result, an incompatible phase structure in which the crosslinked particles were dispersed in the continuous phase was formed. Pulse NMR analysis indicated that the interfacial layer thickness was in the range of 17–98 nm. The thickness decreased with an increase in the degree of crosslinking in the particles. The interfacial layer thickness in the particles was approximately 10 times larger than that for the incompatible polymer pair. Tensile test results indicated that the elongation at break was dependent on the thickness of the interfacial layer. The yield stress was developed for the particles with high hardness that was independent of the interfacial thickness.     

Effect of Unplasticized Poly Vinyl Chloride (UPVC) Molecular Weight and Graft-Acrylonitrile-Butadiene-Styrene (g-ABS) Content on Compatibility and Izod Impact Strength of UPVC/g-ABS Blends

In this study three grades of rigid poly vinyl chloride (PVC) having different molar masses were melt blended with graft-acrylonitrile-butadiene-styrene (g-ABS) in different compositions. The effect of PVC molecular weight and g-ABS composition on the compatibility and Izod impact strength of the blends were investigated. Differential scanning calorimetry (DSC) results showed a single glass transition temperature (T_g) for all the blends, representative of miscibility between the PVC phase and the styrene-acrylonitrile copolymer (SAN) phase of g-ABS which, in turn, led to compatibility of the PVC/g-ABS blends. It was observed that in all the PVC grades the blends Izod impact strength increased with increasing g-ABS content. Also, at a given composition of g-ABS, by increasing the molecular weight of the PVC phase the impact strength of the blends increased. The morphology of the fracture surfaces from the impact tests were analyzed using scanning electron microscopy (SEM) micrographs and the results showed that with increasing g-ABS content in the blend, cloudy regions increased and eventually begin to overlap each other, and the deformed material on the fracture surfaces increased. This was attributed to the blend compatibility causing greater energy dissipation in the fracture process.     

复杂飞行器电气系统抗干扰设计技术研究

结合现代飞行器因其功能复杂,设备种类和数量众多,电气系统规模庞大,设备间连接关系复杂,接口信号类型多的特点,针对其较高的抗干扰性能和可靠性要求,系统分析了复杂飞行器电气系统辐射、电源串扰、浪涌串扰等干扰源类型、特性及影响。针对影响电路的传导、辐射、差模、共模干扰四种干扰模式,提出了可以从源头抑制提高复杂飞行器电气系统抗干扰性能的四个方面的设计方法和注意事项,分别是接地设计、屏蔽设计、隔离设计和滤波设计。最后,结合典型案例,分析了某飞行器电气系统因设计缺陷存在地信号干扰问题,通过增加隔离措施解决了该干扰问题,并通过了试验验证。