208Hg β－ 衰变γ纲图

以¹⁸O重离子束轰击厚天然铅靶,通过多核子转移反应生成²⁰⁸Hg核.辐照铅片放入离线熔化铅靶气相热色谱装置中处理,分离并收集汞元素产物.完成了4πΔE_βγ-γ,γX(γ)关联事件谱及γ射线时序单谱测量.建议了21条γ射线,以及能量为1365,1727keV的两条²⁰⁸Tl新能级的²⁰⁸Hg β^－ 衰变部分γ纲图.     

无机盐对聚乙二醇(PEG)水溶液浊点温度的影响

<正> 聚乙二醇(Polyethylenylycol,PEG)是一种线型水溶性大分子,广泛用于造纸工业的粘着剂,纤维工业的上浆材料,它在生物体内的原生质融合过程中起着重要作用。因其分子结构简单,且不荷电,所以它对研究大分子水溶液中的结构效应是很有益的,无机盐的加入可以改变PEG溶液体系的相转移温度。Baily和Callard,曾研究过无机盐对PEG水溶液浊点温度的影响。本研究除进一步系统考察这种影响外,还讨论了它们之间的规律性,并且确定了PEG+H_2O体系的下临界共溶温度。     

用纸上层析分离分光光度法测定含金(铊)矿石中的锑

目前,测定含金(铊)矿石中的锑,无论是碱性染料法或是碘化钾-罗丹明B(6G)-聚乙烯醇法,都相当程度的受金、铊的干扰,即使加入大量的掩蔽剂也无法消除。本文是藉助于纸层析法将金、铊分离,然后用孔雀绿显色分光光度法测定含金(铊)矿石中的锑。经实验表明,在此条件下,金80μg、铊100μg不干扰测定,方法回收率在90％以上,变动系数为5.5％左右,测定范围为0.0x-x.0％。 (一)分析手续称取0.5000g试样于100ml的烧杯中,用水润湿后加盐酸和磷酸混酸(4:1)15Ml,加热煮沸溶解后定     

Development of Monoclonal Antibody-based Enzyme-linked Immunosorbent Assay to the Estrogen Diethylstilbestrol

Diethylstilbestrol （DES） is a synthetic estrogen that has ever been used worldwide. Polyclonal antibodies （PAbs） were used in immunoassay for detection of DES residues in environmental and agricultural samples in previous paper. In this paper, an indirect competitive enzyme-linked immunosorbent assay （icELISA） was developed based on monoclonal antibody （MAb） for the determination of diethylstilbestrol. Mono-o-carboxypropyldiethylstilbestrol （DES-CP） and mono-o-carboxymethyldiethylstilbestrol （DES-CME） were synthesized to be haptens. DES-CP was coupled to bovine serum albumin （BSA） to be an immunogen in BALB/c female mouse for MAb production. The MAb was characterized for specificity and affinity to DES in icELISA. Under the optimum condition, the icELISA showed an ICs0 of 9.8 ng/mL, the limit of detection （IC20） of 2.3 ng/mL and a working range of 2-42 ng/mL. Hexestrol and dienestrol exhibited cross-reactivity values were 44% and 27%, respectively. Cross-reactivity of natural estrogen 17β-estradiol was less than 0.1%. The influences of some factors such as salt concentration, pH and organic solvent concentration on the assay were evaluated. The concentrations of DES in the fortified water samples determined by the assay were correlated well with the fortification levels. The results were conf＇m＇ned with analysis by HPLC.     

COMPREHENSIVE MATHEMATICAL MODEL OF MICROCIRCULATORY DYNAMICS (Ⅰ)——BASIC THEORY

Under the basis of physiological data, a nonlinear and unsteady comprehensive mathematical model of microcirculatory dynamics with distributed parameters is developed. Hemodynamics, interstitium dynamics, lymph dynamics, dynamics of protein transport, oxygen dynamics, dynamics of heat transfer, and myogenic and metabolic regulation procedures are included. The interactions between these factors were comprehensively exhibited. The influences of arteriolar vasomotion and nonlinear viscoelasticity of blood in arteriole are considered. A simplified vessel network consisting of arteriole, open and reserved capillaries, venule, initial lymphatics and arteriole-venule anastomose is adopted as the geometrical model. This kind of comprehensive mathematical model is helpful in analyzing clinical data and developing a “numerical experiment method” in microcirculation research.     

DNA改性聚砜多孔微球选择性清除环境激素

将DNA视为生物大分子材料,制成DNA改性聚砜微球,在生物体外考察改性微球对环境激素,包括重金属离子的选择性清除.制备了2种改性聚砜微球:DNA共混微球(将DNA共混入聚砜溶液,当混合溶液滴入水中时,发生相分离而沉淀)和DNA表面改性聚砜微球(先制备聚砜多孔微球,再通过紫外线照射的方法将DNA接枝到聚砜微球表面).两种DNA改性聚砜微球在水中比较稳定,在酸或碱性条件下,由于DNA水解而不稳定.对环境激素的清除结果表明,DNA改性聚砜微球可以选择性清除包括联苯、苯酚和二恶荚类环境荷尔蒙物质;同时选择性吸附锌、铜、银、铅和铬等重金属离子.     

电场作用下向列相液晶指向矢与流动的耦合机理

作为开发液晶流动驱动的第一步,运用宏观ELP模型及Frank弹性理论对电场作用下液晶盒内向列相液晶的指向矢旋转与所引起的液晶流动之间的耦合机理进行了理论与实验研究。通过对液晶盒进行施加及撤销电场的操作,得到了液晶盒内瞬间液晶指向矢的旋转及所引起的液晶流动的变化情况。电场施加瞬间指向矢的旋转控制着流动的变化,二者同时达到最大值:指向矢旋转为350(°)/s,引流速度为30μm/s;而电场撤销的瞬间流动的变化控制着指向矢的旋转,流动特征与电场施加瞬间很相似,但持续时间很短。实验验证采用最直接的观察法,用显微镜自带CCD拍摄液晶盒在电场施加和解除过程中内部液晶引流发生的过程,通过图像分析得到实验数据,每个数据点分别通过取10次实验的平均值得到,实验结果与理论计算结果吻合。     

COMPREHENSIVE MATHEMATICAL MODEL OF MICROCIRCULATORY DYNAMICS (Ⅰ)——BASIC THEORY

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Sm原子的偶宇称高激发态的光谱研究

采用双色三步激发和光电离过程,对Sm原子的偶宇称高激发态的光谱进行了研究.先采用两条激发路线分别将Sm原子两步共振激发至待测的高激发态,然后利用光电离技术对其进行探测.分别将第一束激光的波长固定在627.50nm和624.41nm上,以便将Sm原子从亚稳态共振激发到由4f⁶6s6p电子组态所构成的两个原子状态上.第二束激光在440-700nm的波段范围内扫描,不仅使Sm原子在30040-38065cm^-1能域内的偶宇称高激发态上布居,将其进一步光电离,测量了其光谱.通过光谱定标和选择定则等分析手段,本工作不仅精确获得了136个态的能级位置,而且也唯一确定了其总角动量,并且给出了相关跃迁的相对谱线强度.     

Measurement of Mg Content in Zn1-xMgxO Films by Electron Probe Microanalysis

Zn1-xMgxO films are grown on A-sapphire substrates by molecular beam epitaxy, and Mg content in the Zn1-xMgxO films is measured by electron probe microanalysis （EPMA） when the acceleration voltage, the emission current, and the magnification are set to be 1 k V, 30 μA and 1000, respectively. The dead time is controlled within 17%-20% during the measurement with the receive angle of characteristic x-ray of 45°. The Mg content of the ZnMgO film is calculated by the low energy calibration and the ZAF calibration. By comparing the measurement result with the theoretical analysis and the EPMA result with the inductively coupled plasma （ICP）, one can obtain that the measured value of Mg content of the samples is in good agreement with the theoretical analysis no matter whether the phase separation exists or not, and the correctness of ICP and EPMA is valid when Mg content in the samples is less than 0.5.